MiMeDB: Showing metabocard for Fumonisin b6 (MMDBc0017696)

Record Information

Version

2.0

Status

Detected and Quantified

Creation Date

2021-05-15 08:00:29 UTC

Update Date

2025-10-07 16:06:43 UTC

Metabolite ID

MMDBc0017696

Metabolite Identification

Common Name

Fumonisin b6

Description

Fumonisin B6 is a member of the fumonisin chemical class, which consists of a group of mycotoxins produced by certain fungi, notably Aspergillus and Fusarium species. Its chemical structure features a long-chain fatty acid backbone with a unique arrangement of hydroxyl and amino functional groups, which contributes to its biological activity. Fumonisin B6 is structurally related to fumonisin B2, differing primarily in the presence of a hydroxyl group at the C-6 position. This compound is involved in various biochemical pathways, particularly in the inhibition of ceramide synthase, leading to the disruption of sphingolipid metabolism. Such interference can result in altered cell signaling and apoptosis, which are critical processes in cellular health and disease. The isolation and characterization of fumonisin B6 from Aspergillus niger have been documented in the literature, highlighting its significance as a metabolite of interest (PMID:20028011 ). Understanding the chemical properties and biological interactions of fumonisin B6 is essential for assessing its potential impacts on health and the environment.

Structure

MOL SDF PDB SMILES InChI


  Mrv1533004241508362D          

 50 49  0  0  0  0            999 V2000
   17.5677    7.6677    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   16.8533    8.0802    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   16.1388    7.6677    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   15.4243    8.0802    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   14.7099    7.6677    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   13.9954    8.0802    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   14.7099    6.8427    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   13.9954    6.4302    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   13.2809    6.8427    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   13.2809    7.6677    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   12.5664    6.4302    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   11.8520    6.8427    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   11.1375    6.4302    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   10.4230    6.8427    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   10.4230    7.6677    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    9.7086    6.4302    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   11.8520    7.6677    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   11.1375    8.0802    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   12.5664    8.0802    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   15.4243    6.4302    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   16.1388    6.8427    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   16.8533    6.4302    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   16.8533    5.6052    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   17.5677    6.8427    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   18.2822    6.4302    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   18.9967    6.8427    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   19.7112    6.4302    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   20.4256    6.8427    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   21.1401    6.4302    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   21.8546    6.8427    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   21.8546    7.6677    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   22.5690    6.4302    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   22.5690    5.6052    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   23.2835    6.8427    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   23.2835    7.6677    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   23.9980    6.4302    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   24.7124    6.8427    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   23.9980    5.6052    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
   15.4243    5.6052    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   14.7099    5.1927    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   14.7099    4.3677    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   13.9954    5.6052    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   13.2809    5.1927    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   12.5664    5.6052    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   11.8520    5.1927    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   11.8520    4.3677    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   11.1375    5.6052    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   13.2809    4.3677    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   12.5664    3.9552    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   13.9954    3.9552    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  1  0  0  0  0
  3  4  1  0  0  0  0
  4  5  1  0  0  0  0
  5  6  1  0  0  0  0
  5  7  1  0  0  0  0
  7  8  1  0  0  0  0
  8  9  1  0  0  0  0
  9 10  2  0  0  0  0
  9 11  1  0  0  0  0
 11 12  1  0  0  0  0
 12 13  1  0  0  0  0
 13 14  1  0  0  0  0
 14 15  2  0  0  0  0
 14 16  1  0  0  0  0
 12 17  1  0  0  0  0
 17 18  2  0  0  0  0
 17 19  1  0  0  0  0
  7 20  1  0  0  0  0
 20 21  1  0  0  0  0
 21 22  1  0  0  0  0
 22 23  1  0  0  0  0
 22 24  1  0  0  0  0
 24 25  1  0  0  0  0
 25 26  1  0  0  0  0
 26 27  1  0  0  0  0
 27 28  1  0  0  0  0
 28 29  1  0  0  0  0
 29 30  1  0  0  0  0
 30 31  1  0  0  0  0
 30 32  1  0  0  0  0
 32 33  1  0  0  0  0
 32 34  1  0  0  0  0
 34 35  1  0  0  0  0
 34 36  1  0  0  0  0
 36 37  1  0  0  0  0
 36 38  1  0  0  0  0
 20 39  1  0  0  0  0
 39 40  1  0  0  0  0
 40 41  2  0  0  0  0
 40 42  1  0  0  0  0
 42 43  1  0  0  0  0
 43 44  1  0  0  0  0
 44 45  1  0  0  0  0
 45 46  2  0  0  0  0
 45 47  1  0  0  0  0
 43 48  1  0  0  0  0
 48 49  2  0  0  0  0
 48 50  1  0  0  0  0
M  END


  Mrv1533004241508362D          

 50 49  0  0  0  0            999 V2000
   17.5677    7.6677    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   16.8533    8.0802    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   16.1388    7.6677    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   15.4243    8.0802    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   14.7099    7.6677    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   13.9954    8.0802    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   14.7099    6.8427    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   13.9954    6.4302    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   13.2809    6.8427    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   13.2809    7.6677    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   12.5664    6.4302    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   11.8520    6.8427    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   11.1375    6.4302    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   10.4230    6.8427    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   10.4230    7.6677    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    9.7086    6.4302    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   11.8520    7.6677    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   11.1375    8.0802    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   12.5664    8.0802    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   15.4243    6.4302    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   16.1388    6.8427    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   16.8533    6.4302    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   16.8533    5.6052    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   17.5677    6.8427    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   18.2822    6.4302    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   18.9967    6.8427    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   19.7112    6.4302    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   20.4256    6.8427    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   21.1401    6.4302    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   21.8546    6.8427    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   21.8546    7.6677    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   22.5690    6.4302    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   22.5690    5.6052    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   23.2835    6.8427    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   23.2835    7.6677    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   23.9980    6.4302    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   24.7124    6.8427    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   23.9980    5.6052    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
   15.4243    5.6052    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   14.7099    5.1927    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   14.7099    4.3677    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   13.9954    5.6052    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   13.2809    5.1927    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   12.5664    5.6052    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   11.8520    5.1927    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   11.8520    4.3677    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   11.1375    5.6052    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   13.2809    4.3677    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   12.5664    3.9552    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   13.9954    3.9552    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  1  0  0  0  0
  3  4  1  0  0  0  0
  4  5  1  0  0  0  0
  5  6  1  0  0  0  0
  5  7  1  0  0  0  0
  7  8  1  0  0  0  0
  8  9  1  0  0  0  0
  9 10  2  0  0  0  0
  9 11  1  0  0  0  0
 11 12  1  0  0  0  0
 12 13  1  0  0  0  0
 13 14  1  0  0  0  0
 14 15  2  0  0  0  0
 14 16  1  0  0  0  0
 12 17  1  0  0  0  0
 17 18  2  0  0  0  0
 17 19  1  0  0  0  0
  7 20  1  0  0  0  0
 20 21  1  0  0  0  0
 21 22  1  0  0  0  0
 22 23  1  0  0  0  0
 22 24  1  0  0  0  0
 24 25  1  0  0  0  0
 25 26  1  0  0  0  0
 26 27  1  0  0  0  0
 27 28  1  0  0  0  0
 28 29  1  0  0  0  0
 29 30  1  0  0  0  0
 30 31  1  0  0  0  0
 30 32  1  0  0  0  0
 32 33  1  0  0  0  0
 32 34  1  0  0  0  0
 34 35  1  0  0  0  0
 34 36  1  0  0  0  0
 36 37  1  0  0  0  0
 36 38  1  0  0  0  0
 20 39  1  0  0  0  0
 39 40  1  0  0  0  0
 40 41  2  0  0  0  0
 40 42  1  0  0  0  0
 42 43  1  0  0  0  0
 43 44  1  0  0  0  0
 44 45  1  0  0  0  0
 45 46  2  0  0  0  0
 45 47  1  0  0  0  0
 43 48  1  0  0  0  0
 48 49  2  0  0  0  0
 48 50  1  0  0  0  0
M  END
> <DATABASE_ID>
MMDBc0017696

> <DATABASE_NAME>
MIME

> <SMILES>
CCCCC(C)C(OC(=O)CC(CC(O)=O)C(O)=O)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N)OC(=O)CC(CC(O)=O)C(O)=O

> <INCHI_IDENTIFIER>
InChI=1S/C34H59NO15/c1-5-6-12-20(3)32(50-29(42)18-23(34(47)48)16-27(39)40)25(49-28(41)17-22(33(45)46)15-26(37)38)14-19(2)11-9-7-8-10-13-24(36)31(44)30(43)21(4)35/h19-25,30-32,36,43-44H,5-18,35H2,1-4H3,(H,37,38)(H,39,40)(H,45,46)(H,47,48)

> <INCHI_KEY>
WQXBMSIHHKRGPX-UHFFFAOYSA-N

> <FORMULA>
C34H59NO15

> <MOLECULAR_WEIGHT>
721.838

> <EXACT_MASS>
721.388470204

> <JCHEM_ACCEPTOR_COUNT>
14

> <JCHEM_ATOM_COUNT>
109

> <JCHEM_AVERAGE_POLARIZABILITY>
77.13870619701608

> <JCHEM_BIOAVAILABILITY>
0

> <JCHEM_DONOR_COUNT>
8

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
2-[2-({19-amino-6-[(3,4-dicarboxybutanoyl)oxy]-16,17,18-trihydroxy-5,9-dimethylicosan-7-yl}oxy)-2-oxoethyl]butanedioic acid

> <ALOGPS_LOGP>
-0.58

> <JCHEM_LOGP>
0.029341928788774438

> <ALOGPS_LOGS>
-4.17

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
0

> <JCHEM_PHYSIOLOGICAL_CHARGE>
-3

> <JCHEM_PKA>
3.7459173747253973

> <JCHEM_PKA_STRONGEST_ACIDIC>
3.1587620031276766

> <JCHEM_PKA_STRONGEST_BASIC>
9.150006568012664

> <JCHEM_POLAR_SURFACE_AREA>
288.51

> <JCHEM_REFRACTIVITY>
175.13330000000013

> <JCHEM_ROTATABLE_BOND_COUNT>
31

> <JCHEM_RULE_OF_FIVE>
0

> <ALOGPS_SOLUBILITY>
4.88e-02 g/l

> <JCHEM_TRADITIONAL_IUPAC>
2-[2-({19-amino-6-[(3,4-dicarboxybutanoyl)oxy]-16,17,18-trihydroxy-5,9-dimethylicosan-7-yl}oxy)-2-oxoethyl]butanedioic acid

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 24-APR-15   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   24-APR-15         0                                  
HETATM    1  C   UNK     0      32.793  14.313   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0      31.459  15.083   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0      30.126  14.313   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0      28.792  15.083   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0      27.458  14.313   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0      26.125  15.083   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0      27.458  12.773   0.000  0.00  0.00           C+0
HETATM    8  O   UNK     0      26.125  12.003   0.000  0.00  0.00           O+0
HETATM    9  C   UNK     0      24.791  12.773   0.000  0.00  0.00           C+0
HETATM   10  O   UNK     0      24.791  14.313   0.000  0.00  0.00           O+0
HETATM   11  C   UNK     0      23.457  12.003   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0      22.124  12.773   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0      20.790  12.003   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0      19.456  12.773   0.000  0.00  0.00           C+0
HETATM   15  O   UNK     0      19.456  14.313   0.000  0.00  0.00           O+0
HETATM   16  O   UNK     0      18.123  12.003   0.000  0.00  0.00           O+0
HETATM   17  C   UNK     0      22.124  14.313   0.000  0.00  0.00           C+0
HETATM   18  O   UNK     0      20.790  15.083   0.000  0.00  0.00           O+0
HETATM   19  O   UNK     0      23.457  15.083   0.000  0.00  0.00           O+0
HETATM   20  C   UNK     0      28.792  12.003   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0      30.126  12.773   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0      31.459  12.003   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0      31.459  10.463   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0      32.793  12.773   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0      34.127  12.003   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0      35.460  12.773   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0      36.794  12.003   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0      38.128  12.773   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0      39.462  12.003   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0      40.795  12.773   0.000  0.00  0.00           C+0
HETATM   31  O   UNK     0      40.795  14.313   0.000  0.00  0.00           O+0
HETATM   32  C   UNK     0      42.129  12.003   0.000  0.00  0.00           C+0
HETATM   33  O   UNK     0      42.129  10.463   0.000  0.00  0.00           O+0
HETATM   34  C   UNK     0      43.463  12.773   0.000  0.00  0.00           C+0
HETATM   35  O   UNK     0      43.463  14.313   0.000  0.00  0.00           O+0
HETATM   36  C   UNK     0      44.796  12.003   0.000  0.00  0.00           C+0
HETATM   37  C   UNK     0      46.130  12.773   0.000  0.00  0.00           C+0
HETATM   38  N   UNK     0      44.796  10.463   0.000  0.00  0.00           N+0
HETATM   39  O   UNK     0      28.792  10.463   0.000  0.00  0.00           O+0
HETATM   40  C   UNK     0      27.458   9.693   0.000  0.00  0.00           C+0
HETATM   41  O   UNK     0      27.458   8.153   0.000  0.00  0.00           O+0
HETATM   42  C   UNK     0      26.125  10.463   0.000  0.00  0.00           C+0
HETATM   43  C   UNK     0      24.791   9.693   0.000  0.00  0.00           C+0
HETATM   44  C   UNK     0      23.457  10.463   0.000  0.00  0.00           C+0
HETATM   45  C   UNK     0      22.124   9.693   0.000  0.00  0.00           C+0
HETATM   46  O   UNK     0      22.124   8.153   0.000  0.00  0.00           O+0
HETATM   47  O   UNK     0      20.790  10.463   0.000  0.00  0.00           O+0
HETATM   48  C   UNK     0      24.791   8.153   0.000  0.00  0.00           C+0
HETATM   49  O   UNK     0      23.457   7.383   0.000  0.00  0.00           O+0
HETATM   50  O   UNK     0      26.125   7.383   0.000  0.00  0.00           O+0
CONECT    1    2                                                            
CONECT    2    1    3                                                       
CONECT    3    2    4                                                       
CONECT    4    3    5                                                       
CONECT    5    4    6    7                                                  
CONECT    6    5                                                            
CONECT    7    5    8   20                                                  
CONECT    8    7    9                                                       
CONECT    9    8   10   11                                                  
CONECT   10    9                                                            
CONECT   11    9   12                                                       
CONECT   12   11   13   17                                                  
CONECT   13   12   14                                                       
CONECT   14   13   15   16                                                  
CONECT   15   14                                                            
CONECT   16   14                                                            
CONECT   17   12   18   19                                                  
CONECT   18   17                                                            
CONECT   19   17                                                            
CONECT   20    7   21   39                                                  
CONECT   21   20   22                                                       
CONECT   22   21   23   24                                                  
CONECT   23   22                                                            
CONECT   24   22   25                                                       
CONECT   25   24   26                                                       
CONECT   26   25   27                                                       
CONECT   27   26   28                                                       
CONECT   28   27   29                                                       
CONECT   29   28   30                                                       
CONECT   30   29   31   32                                                  
CONECT   31   30                                                            
CONECT   32   30   33   34                                                  
CONECT   33   32                                                            
CONECT   34   32   35   36                                                  
CONECT   35   34                                                            
CONECT   36   34   37   38                                                  
CONECT   37   36                                                            
CONECT   38   36                                                            
CONECT   39   20   40                                                       
CONECT   40   39   41   42                                                  
CONECT   41   40                                                            
CONECT   42   40   43                                                       
CONECT   43   42   44   48                                                  
CONECT   44   43   45                                                       
CONECT   45   44   46   47                                                  
CONECT   46   45                                                            
CONECT   47   45                                                            
CONECT   48   43   49   50                                                  
CONECT   49   48                                                            
CONECT   50   48                                                            
MASTER        0    0    0    0    0    0    0    0   50    0   98    0
END

Synonyms

Value	Source
2-[2-({19-amino-6-[(3,4-dicarboxybutanoyl)oxy]-16,17,18-trihydroxy-5,9-dimethylicosan-7-yl}oxy)-2-oxoethyl]butanedioate	Generator
2-Amino-12,16-dimethyl-3,4,5,14,15-icosanepentaol 14,15-bis[3,4-bis(hydroxycarbonyl)butyric acid]	Generator

Molecular Formula

C₃₄H₅₉NO₁₅

Average Mass

721.838

Monoisotopic Mass

721.388470204

IUPAC Name

2-[2-({19-amino-6-[(3,4-dicarboxybutanoyl)oxy]-16,17,18-trihydroxy-5,9-dimethylicosan-7-yl}oxy)-2-oxoethyl]butanedioic acid

Traditional Name

2-[2-({19-amino-6-[(3,4-dicarboxybutanoyl)oxy]-16,17,18-trihydroxy-5,9-dimethylicosan-7-yl}oxy)-2-oxoethyl]butanedioic acid

CAS Registry Number

Not Available

SMILES

CCCCC(C)C(OC(=O)CC(CC(O)=O)C(O)=O)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N)OC(=O)CC(CC(O)=O)C(O)=O

InChI Identifier

InChI=1S/C34H59NO15/c1-5-6-12-20(3)32(50-29(42)18-23(34(47)48)16-27(39)40)25(49-28(41)17-22(33(45)46)15-26(37)38)14-19(2)11-9-7-8-10-13-24(36)31(44)30(43)21(4)35/h19-25,30-32,36,43-44H,5-18,35H2,1-4H3,(H,37,38)(H,39,40)(H,45,46)(H,47,48)

InChI Key

WQXBMSIHHKRGPX-UHFFFAOYSA-N

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as fumonisins. These are diesters of propane-1,2,3-tricarboxylic acid (TCA) and similar long-chain aminopolyol backbones (for FB1: 2S-amino-12S,16R-dimethyl-3S,5R,10R,14S,15R-pentahydroxyeicosane). Structurally, fumonisins resemble the sphingoid bases sphinganine (SA) and sphingosine (SO) to which TCA groups have been added at the C-14 and C-15 positions.

Kingdom

Organic compounds

Super Class

Organic acids and derivatives

Class

Carboxylic acids and derivatives

Sub Class

Fumonisins

Direct Parent

Fumonisins

Alternative Parents

Substituents

Fumonisin-skeleton
Fumonisin skeleton
Hexacarboxylic acid or derivatives
Fatty acid ester
Fatty acyl
1,3-aminoalcohol
1,2-aminoalcohol
1,2-diol
Amino acid or derivatives
Carboxylic acid ester
Amino acid
Secondary alcohol
Carboxylic acid
Polyol
Primary aliphatic amine
Organic oxide
Organic oxygen compound
Alcohol
Carbonyl group
Organic nitrogen compound
Organonitrogen compound
Organooxygen compound
Primary amine
Amine
Hydrocarbon derivative
Aliphatic acyclic compound

Molecular Framework

Aliphatic acyclic compounds

External Descriptors

Not Available

Functional Ontology

Not Available

Physical Properties

State

Expected Solid

Predicted Properties

Property	Value	Source
Water Solubility	0.049 g/L	ALOGPS
logP	-0.58	ALOGPS
logP	0.029	ChemAxon
logS	-4.2	ALOGPS
pKa (Strongest Acidic)	3.16	ChemAxon
pKa (Strongest Basic)	9.15	ChemAxon
Physiological Charge	-3	ChemAxon
Hydrogen Acceptor Count	14	ChemAxon
Hydrogen Donor Count	8	ChemAxon
Polar Surface Area	288.51 Å²	ChemAxon
Rotatable Bond Count	31	ChemAxon
Refractivity	175.13 m³·mol⁻¹	ChemAxon
Polarizability	77.14 Å³	ChemAxon
Number of Rings	0	ChemAxon
Bioavailability	No	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

Spectra

Spectrum Type	Description	Splash Key	Deposition Date	View
Predicted GC-MS	Predicted GC-MS Spectrum - GC-MS (TMS_2_2) - 70eV, Positive	Not Available	2022-08-08	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 10V, Positive	Not Available	2022-08-09	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 20V, Positive	Not Available	2022-08-09	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 40V, Positive	Not Available	2022-08-09	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 10V, Negative	Not Available	2022-08-09	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 20V, Negative	Not Available	2022-08-09	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 40V, Negative	Not Available	2022-08-09	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 100 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 1000 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 200 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 300 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 400 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 500 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 600 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 700 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 800 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 900 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)		2022-08-20	View Spectrum

Chromatographic Retention Times and Retention Indices

Retention Times

Chromatography Type	Technique	Column	Deposition Date	Retention Time (s)
Liquid Chromatography	HILIC	Waters Acquity UPLC-BEH Amide column (eluted)	2025-10-23	493.4
Liquid Chromatography	HILIC	Accucore 150 Amide HILIC (eluted)	2025-10-23	224.7
Liquid Chromatography	Reversed-phase	Hypersil Gold 1.9 µm C18 (eluted)	2025-10-23	622.6
Liquid Chromatography	Reversed-phase	Agilent Zorbax Eclipse Plus C18 (2.1 mm x 150 mm, 3.5 um) (eluted)	2025-10-23	589.9
Liquid Chromatography	Reversed-phase	XBridge C18 3.5u 2.1x50 mm (eluted)	2025-10-23	568.6
Liquid Chromatography	Reversed-phase	Ascentis Express C18 (eluted)	2025-10-23	139.7
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC HSS T3 C18 (eluted)	2025-10-23	2498.3
Liquid Chromatography	HILIC	Merck SeQuant ZIC-HILIC (eluted)	2025-10-23	446.7
Liquid Chromatography	HILIC	Merck SeQuant ZIC-pHILIC (eluted)	2025-10-23	345.7
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC HSS T3 C18 (eluted)	2025-10-23	261.7
Liquid Chromatography	HILIC	Merck SeQuant ZIC-HILIC (eluted)	2025-10-23	86.9
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC HSS T3 C18 (eluted)	2025-10-23	156.6
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC BEH C18 (void)	2025-10-23	181.1
Liquid Chromatography	HILIC	Merck SeQuant ZIC-pHILIC column (eluted)	2025-10-23	247.6
Liquid Chromatography	HILIC	Merck SeQuant ZIC-pHILIC column (eluted)	2025-10-23	239.4
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC BEH C18 (eluted)	2025-10-23	198.4
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC BEH C18 (eluted)	2025-10-23	452.6
Liquid Chromatography	Reversed-phase	Kinetex Core-Shell C18 2.6 um, 3.0 x 100 mm, Phenomenex (eluted)	2025-10-23	1467.6
Liquid Chromatography	Reversed-phase	Waters Atlantis T3 (2.1 x 150 mm, 5 um) (eluted)	2025-10-23	1030.5

Retention Indices

Chromatography Type	Peak Label	SMILES	Stationary Phase	Deposition Date	Retention Index
Gas Chromatography	Fumonisin b6_TMS_1	CCCCC(C)C(OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard non polar	2025-10-23	1609.12
Gas Chromatography	Fumonisin b6_TMS_2	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O[Si](C)(C)C)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard non polar	2025-10-23	1415.15
Gas Chromatography	Fumonisin b6_TMS_3	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O[Si](C)(C)C)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard non polar	2025-10-23	1375.51
Gas Chromatography	Fumonisin b6_TMS_4	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O[Si](C)(C)C)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard non polar	2025-10-23	1812.46
Gas Chromatography	Fumonisin b6_TMS_5	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O[Si](C)(C)C)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard non polar	2025-10-23	1246.23
Gas Chromatography	Fumonisin b6_TMS_6	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O	standard non polar	2025-10-23	2079.32
Gas Chromatography	Fumonisin b6_TMS_7	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O[Si](C)(C)C	standard non polar	2025-10-23	3313.93
Gas Chromatography	Fumonisin b6_TMS_8	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N[Si](C)(C)C)OC(=O)CC(CC(=O)O)C(=O)O	standard non polar	2025-10-23	2142.38
Gas Chromatography	Fumonisin b6_TMS_9	CCCCC(C)C(OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard non polar	2025-10-23	2271.19
Gas Chromatography	Fumonisin b6_TMS_10	CCCCC(C)C(OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O)C(CC(C)CCCCCCC(O[Si](C)(C)C)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard non polar	2025-10-23	2136.57
Gas Chromatography	Fumonisin b6_TMS_11	CCCCC(C)C(OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O)C(CC(C)CCCCCCC(O)C(O[Si](C)(C)C)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard non polar	2025-10-23	2289.74
Gas Chromatography	Fumonisin b6_TMS_12	CCCCC(C)C(OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O[Si](C)(C)C)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard non polar	2025-10-23	1031.7
Gas Chromatography	Fumonisin b6_TMS_13	CCCCC(C)C(OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O	standard non polar	2025-10-23	2911.55
Gas Chromatography	Fumonisin b6_TMS_14	CCCCC(C)C(OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O[Si](C)(C)C	standard non polar	2025-10-23	1207.57
Gas Chromatography	Fumonisin b6_TMS_15	CCCCC(C)C(OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N[Si](C)(C)C)OC(=O)CC(CC(=O)O)C(=O)O	standard non polar	2025-10-23	1601.54
Gas Chromatography	Fumonisin b6_TMS_16	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O[Si](C)(C)C)C(CC(C)CCCCCCC(O[Si](C)(C)C)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard non polar	2025-10-23	4081.83
Gas Chromatography	Fumonisin b6_TMS_17	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O[Si](C)(C)C)C(CC(C)CCCCCCC(O)C(O[Si](C)(C)C)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard non polar	2025-10-23	2759.98
Gas Chromatography	Fumonisin b6_TMS_18	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O[Si](C)(C)C)C(CC(C)CCCCCCC(O)C(O)C(O[Si](C)(C)C)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard non polar	2025-10-23	3153.5
Gas Chromatography	Fumonisin b6_TMS_19	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O[Si](C)(C)C)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O	standard non polar	2025-10-23	3381.64
Gas Chromatography	Fumonisin b6_TMS_20	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O[Si](C)(C)C)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O[Si](C)(C)C	standard non polar	2025-10-23	2169.14
Gas Chromatography	Fumonisin b6_TMS_21	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O[Si](C)(C)C)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N[Si](C)(C)C)OC(=O)CC(CC(=O)O)C(=O)O	standard non polar	2025-10-23	2862.84
Gas Chromatography	Fumonisin b6_TMS_22	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O[Si](C)(C)C)C(O[Si](C)(C)C)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard non polar	2025-10-23	2273.44
Gas Chromatography	Fumonisin b6_TMS_23	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O[Si](C)(C)C)C(O)C(O[Si](C)(C)C)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard non polar	2025-10-23	1207.37
Gas Chromatography	Fumonisin b6_TMS_24	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O[Si](C)(C)C)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O	standard non polar	2025-10-23	1808.69
Gas Chromatography	Fumonisin b6_TMS_25	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O[Si](C)(C)C)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O[Si](C)(C)C	standard non polar	2025-10-23	2552.49
Gas Chromatography	Fumonisin b6_TMS_26	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O[Si](C)(C)C)C(O)C(O)C(C)N[Si](C)(C)C)OC(=O)CC(CC(=O)O)C(=O)O	standard non polar	2025-10-23	1625.7
Gas Chromatography	Fumonisin b6_TMS_27	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O[Si](C)(C)C)C(O[Si](C)(C)C)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard non polar	2025-10-23	3080.92
Gas Chromatography	Fumonisin b6_TMS_28	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O[Si](C)(C)C)C(O)C(C)N)OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O	standard non polar	2025-10-23	2827.28
Gas Chromatography	Fumonisin b6_TMS_29	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O[Si](C)(C)C)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O[Si](C)(C)C	standard non polar	2025-10-23	1854.41
Gas Chromatography	Fumonisin b6_TMS_30	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O[Si](C)(C)C)C(O)C(C)N[Si](C)(C)C)OC(=O)CC(CC(=O)O)C(=O)O	standard non polar	2025-10-23	3317.14
Gas Chromatography	Fumonisin b6_TMS_31	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O[Si](C)(C)C)C(C)N)OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O	standard non polar	2025-10-23	1780.33
Gas Chromatography	Fumonisin b6_TMS_32	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O[Si](C)(C)C)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O[Si](C)(C)C	standard non polar	2025-10-23	1553.15
Gas Chromatography	Fumonisin b6_TMS_33	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O[Si](C)(C)C)C(C)N[Si](C)(C)C)OC(=O)CC(CC(=O)O)C(=O)O	standard non polar	2025-10-23	1995.9
Gas Chromatography	Fumonisin b6_TMS_34	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard non polar	2025-10-23	2807.75
Gas Chromatography	Fumonisin b6_TMS_35	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N[Si](C)(C)C)OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O	standard non polar	2025-10-23	1119.15
Gas Chromatography	Fumonisin b6_TMS_36	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N[Si](C)(C)C)OC(=O)CC(CC(=O)O)C(=O)O[Si](C)(C)C	standard non polar	2025-10-23	2318.5
Gas Chromatography	Fumonisin b6_TMS_37	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N([Si](C)(C)C)[Si](C)(C)C)OC(=O)CC(CC(=O)O)C(=O)O	standard non polar	2025-10-23	1526.62
Gas Chromatography	Fumonisin b6_TMS_1	CCCCC(C)C(OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard polar	2025-10-23	3929.53
Gas Chromatography	Fumonisin b6_TMS_2	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O[Si](C)(C)C)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard polar	2025-10-23	2327.73
Gas Chromatography	Fumonisin b6_TMS_3	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O[Si](C)(C)C)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard polar	2025-10-23	2124.77
Gas Chromatography	Fumonisin b6_TMS_4	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O[Si](C)(C)C)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard polar	2025-10-23	1969.13
Gas Chromatography	Fumonisin b6_TMS_5	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O[Si](C)(C)C)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard polar	2025-10-23	970.821
Gas Chromatography	Fumonisin b6_TMS_6	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O	standard polar	2025-10-23	2531.74
Gas Chromatography	Fumonisin b6_TMS_7	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O[Si](C)(C)C	standard polar	2025-10-23	2286.25
Gas Chromatography	Fumonisin b6_TMS_8	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N[Si](C)(C)C)OC(=O)CC(CC(=O)O)C(=O)O	standard polar	2025-10-23	1299.23
Gas Chromatography	Fumonisin b6_TMS_9	CCCCC(C)C(OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard polar	2025-10-23	2609.09
Gas Chromatography	Fumonisin b6_TMS_10	CCCCC(C)C(OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O)C(CC(C)CCCCCCC(O[Si](C)(C)C)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard polar	2025-10-23	3434.44
Gas Chromatography	Fumonisin b6_TMS_11	CCCCC(C)C(OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O)C(CC(C)CCCCCCC(O)C(O[Si](C)(C)C)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard polar	2025-10-23	399.005
Gas Chromatography	Fumonisin b6_TMS_12	CCCCC(C)C(OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O[Si](C)(C)C)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard polar	2025-10-23	2400.79
Gas Chromatography	Fumonisin b6_TMS_13	CCCCC(C)C(OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O	standard polar	2025-10-23	3011.35
Gas Chromatography	Fumonisin b6_TMS_14	CCCCC(C)C(OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O[Si](C)(C)C	standard polar	2025-10-23	1366.52
Gas Chromatography	Fumonisin b6_TMS_15	CCCCC(C)C(OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N[Si](C)(C)C)OC(=O)CC(CC(=O)O)C(=O)O	standard polar	2025-10-23	2424.65
Gas Chromatography	Fumonisin b6_TMS_16	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O[Si](C)(C)C)C(CC(C)CCCCCCC(O[Si](C)(C)C)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard polar	2025-10-23	1739.09
Gas Chromatography	Fumonisin b6_TMS_17	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O[Si](C)(C)C)C(CC(C)CCCCCCC(O)C(O[Si](C)(C)C)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard polar	2025-10-23	1052.51
Gas Chromatography	Fumonisin b6_TMS_18	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O[Si](C)(C)C)C(CC(C)CCCCCCC(O)C(O)C(O[Si](C)(C)C)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard polar	2025-10-23	-515.458
Gas Chromatography	Fumonisin b6_TMS_19	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O[Si](C)(C)C)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O	standard polar	2025-10-23	1981.34
Gas Chromatography	Fumonisin b6_TMS_20	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O[Si](C)(C)C)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O[Si](C)(C)C	standard polar	2025-10-23	1858.1
Gas Chromatography	Fumonisin b6_TMS_21	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O[Si](C)(C)C)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N[Si](C)(C)C)OC(=O)CC(CC(=O)O)C(=O)O	standard polar	2025-10-23	3834.88
Gas Chromatography	Fumonisin b6_TMS_22	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O[Si](C)(C)C)C(O[Si](C)(C)C)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard polar	2025-10-23	438.377
Gas Chromatography	Fumonisin b6_TMS_23	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O[Si](C)(C)C)C(O)C(O[Si](C)(C)C)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard polar	2025-10-23	2610.7
Gas Chromatography	Fumonisin b6_TMS_24	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O[Si](C)(C)C)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O	standard polar	2025-10-23	1479.34
Gas Chromatography	Fumonisin b6_TMS_25	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O[Si](C)(C)C)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O[Si](C)(C)C	standard polar	2025-10-23	1603.4
Gas Chromatography	Fumonisin b6_TMS_26	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O[Si](C)(C)C)C(O)C(O)C(C)N[Si](C)(C)C)OC(=O)CC(CC(=O)O)C(=O)O	standard polar	2025-10-23	2720.32
Gas Chromatography	Fumonisin b6_TMS_27	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O[Si](C)(C)C)C(O[Si](C)(C)C)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O	standard polar	2025-10-23	1494.11
Gas Chromatography	Fumonisin b6_TMS_28	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O[Si](C)(C)C)C(O)C(C)N)OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O	standard polar	2025-10-23	573.279
Gas Chromatography	Fumonisin b6_TMS_29	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O[Si](C)(C)C)C(O)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O[Si](C)(C)C	standard polar	2025-10-23	3103.61
Gas Chromatography	Fumonisin b6_TMS_30	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O[Si](C)(C)C)C(O)C(C)N[Si](C)(C)C)OC(=O)CC(CC(=O)O)C(=O)O	standard polar	2025-10-23	1491.6
Gas Chromatography	Fumonisin b6_TMS_31	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O[Si](C)(C)C)C(C)N)OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O	standard polar	2025-10-23	1797.79
Gas Chromatography	Fumonisin b6_TMS_32	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O[Si](C)(C)C)C(C)N)OC(=O)CC(CC(=O)O)C(=O)O[Si](C)(C)C	standard polar	2025-10-23	1048.04
Gas Chromatography	Fumonisin b6_TMS_33	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O[Si](C)(C)C)C(C)N[Si](C)(C)C)OC(=O)CC(CC(=O)O)C(=O)O	standard polar	2025-10-23	2039.11
Gas Chromatography	Fumonisin b6_TMS_34	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N)OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard polar	2025-10-23	2789.87
Gas Chromatography	Fumonisin b6_TMS_35	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N[Si](C)(C)C)OC(=O)CC(CC(=O)O[Si](C)(C)C)C(=O)O	standard polar	2025-10-23	2090.82
Gas Chromatography	Fumonisin b6_TMS_36	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N[Si](C)(C)C)OC(=O)CC(CC(=O)O)C(=O)O[Si](C)(C)C	standard polar	2025-10-23	2738.58
Gas Chromatography	Fumonisin b6_TMS_37	CCCCC(C)C(OC(=O)CC(CC(=O)O)C(=O)O)C(CC(C)CCCCCCC(O)C(O)C(O)C(C)N([Si](C)(C)C)[Si](C)(C)C)OC(=O)CC(CC(=O)O)C(=O)O	standard polar	2025-10-23	1522.08

Biological Properties

Cellular Locations

Not Available

Biospecimen Locations

Not Available

Tissue Locations

Not Available

Associated OMIM IDs

114500 (Colorectal cancer)
610247 (Eosinophilic esophagitis)

Human Proteins and Enzymes

Protein ID	Protein Name	Protein Type	Uniprot ID	Species

Human Pathways

Pathways

Name	SMPDB/PathBank

Microbial Pathways

Pathways

Not Available

Metabolic Reactions

Reactions

This table shows at most 20 reactions. For the full list of associated reactions:

See All Associated Reactions

Reaction ID	Precursor	Product	Enzyme	Reaction Type	Data Source	Reference

Health Effects and Bioactivity

Health Outcome/Bioactivity	Metabolite Response/Effect	Evidence Type	Host and Biospecimen	Data Source	Reference

Microbial Sources

Superkingdom/Kingdom	Phylum	Total species	Hosts and Body Sites	Microbial Links
Eukaryota/Fungi	Ascomycota	1	Human feces	Metabolic reconstruction

Exposure Sources

Other Exposures

Source Type	Data Source	Reference

Host Biospecimen and Location

Host and Biospecimen	Status	Mean	Std	Min	Max	Units	Age	Sex	Health Condition	Data Source	Reference

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FooDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

101505417

PDB ID

Not Available

ChEBI ID

Not Available

Food Biomarker Ontology

Not Available

CMMC Knowledgebase

Not Available

General References

van Santen JA, Poynton EF, Iskakova D, McMann E, Alsup TA, Clark TN, Fergusson CH, Fewer DP, Hughes AH, McCadden CA, Parra J, Soldatou S, Rudolf JD, Janssen EM, Duncan KR, Linington RG: The Natural Products Atlas 2.0: a database of microbially-derived natural products. Nucleic Acids Res. 2022 Jan 7;50(D1):D1317-D1323. doi: 10.1093/nar/gkab941. [PubMed:34718710 ]

Showing metabocard for Fumonisin b6 (MMDBc0017696)

MOL for #<Metabolite:0x00007f9accb98a98>

3D MOL for #<Metabolite:0x00007f9accb98a98>

3D SDF for #<Metabolite:0x00007f9accb98a98>

3D-SDF for #<Metabolite:0x00007f9accb98a98>

PDB for #<Metabolite:0x00007f9accb98a98>

3D PDB for #<Metabolite:0x00007f9accb98a98>

SMILES for #<Metabolite:0x00007f9accb98a98>

INCHI for #<Metabolite:0x00007f9accb98a98>

Structure for #<Metabolite:0x00007f9accb98a98>

3D Structure for #<Metabolite:0x00007f9accb98a98>