MiMeDB: Showing metabocard for Isopentenyl-AMP (MMDBc0053381)

Record Information

Version

2.0

Status

Detected and Quantified

Creation Date

2022-05-16 21:22:43 UTC

Update Date

2025-10-07 16:08:18 UTC

Metabolite ID

MMDBc0053381

Metabolite Identification

Common Name

Isopentenyl-AMP

Description

Isopentenyl-AMP is a nucleoside derivative belonging to the class of adenine nucleotides. Its chemical structure features an isopentenyl group attached to the ribose moiety of adenosine monophosphate (AMP), making it a key intermediate in various metabolic pathways. Isopentenyl-AMP is synthesized through the action of the enzyme AMP isopentenyl transferase, which catalyzes the transfer of the isopentenyl group from delta 2-isopentenylpyrophosphate to AMP, resulting in the formation of isopentenyl-AMP (PMID:12972655 ). This compound plays a crucial role in the biosynthesis of cytokinins, a class of plant hormones that regulate various aspects of plant growth and development. The enzyme responsible for this conversion, delta 2-isopentenylpyrophosphate:5'AMP delta 2-isopentenyltransferase, has been purified from the fruiting body of the cellular slime mold Dictyostelium discoideum, demonstrating its significance in eukaryotic metabolism (PMID:6712260 ). Overall, isopentenyl-AMP serves as an important metabolite linking isoprenoid biosynthesis and nucleotide metabolism, contributing to cellular signaling and regulatory processes.

Structure

MOL 3D MOL SDF 3D SDF PDB 3D PDB SMILES InChI


  Mrv1652304202018272D          

 28 30  0  0  0  0            999 V2000
 9987.5047 9984.4219    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
 9989.2953 9984.4116    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
 9989.8027 9986.2738    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 9990.5185 9985.8621    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
 9991.2323 9986.2738    0.0000 P   0  0  0  0  0  0  0  0  0  0  0  0
 9990.8217 9986.9888    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
 9991.9480 9985.8621    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
 9991.6468 9986.9888    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
 9988.4166 9986.3548    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
 9987.7500 9985.8705    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
 9988.0046 9985.0869    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
 9988.8285 9985.0869    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
 9989.0831 9985.8705    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
 9987.0333 9986.2754    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
 9987.0333 9987.0993    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 9985.6062 9986.2754    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 9985.6062 9987.0993    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 9986.3197 9987.5112    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
 9984.8901 9985.8630    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
 9984.1767 9986.2749    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 9984.1767 9987.0990    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
 9984.8901 9987.5109    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 9982.7450 9989.5765    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 9982.0301 9988.3389    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 9982.7450 9988.7514    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 9983.4600 9988.3389    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 9984.1752 9988.7514    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 9984.8901 9988.3389    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
  3  4  1  0  0  0  0
  4  5  1  0  0  0  0
  5  6  2  0  0  0  0
  5  7  1  0  0  0  0
  5  8  1  0  0  0  0
 10 11  1  0  0  0  0
 11 12  1  0  0  0  0
 12 13  1  0  0  0  0
  9 10  1  0  0  0  0
  9 13  1  0  0  0  0
 11  1  1  1  0  0  0
 12  2  1  1  0  0  0
 13  3  1  6  0  0  0
 10 14  1  6  0  0  0
 14 15  1  0  0  0  0
 17 22  1  0  0  0  0
 19 16  1  0  0  0  0
 16 14  1  0  0  0  0
 18 15  2  0  0  0  0
 18 17  1  0  0  0  0
 17 16  2  0  0  0  0
 22 28  1  0  0  0  0
 20 19  2  0  0  0  0
 21 20  1  0  0  0  0
 22 21  2  0  0  0  0
 25 23  1  0  0  0  0
 25 24  1  0  0  0  0
 26 25  2  0  0  0  0
 27 26  1  0  0  0  0
 28 27  1  0  0  0  0
M  END

HMDB0304433
     RDKit          3D
N6-(delta2-isopentenyl)-adenosine 5'-monophosphate
 50 52  0  0  0  0  0  0  0  0999 V2000
    7.1678    0.8727    1.2580 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.5533   -0.2363    0.4712 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.0921   -1.6149    0.5776 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.5252    0.0464   -0.3143 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.9092   -1.0486   -1.0987 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.5191   -1.1577   -0.6994 N   0  0  0  0  0  0  0  0  0  0  0  0
    2.6386   -0.0616   -0.8830 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.0015    1.1101   -1.4194 N   0  0  0  0  0  0  0  0  0  0  0  0
    2.1900    2.1631   -1.6065 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.9069    2.0543   -1.2327 N   0  0  0  0  0  0  0  0  0  0  0  0
    0.4610    0.9175   -0.6879 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.3140   -0.1707   -0.4983 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.6237   -1.1635    0.0555 N   0  0  0  0  0  0  0  0  0  0  0  0
   -0.6410   -0.7307    0.2201 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7643    0.5326   -0.2248 N   0  0  0  0  0  0  0  0  0  0  0  0
   -1.9504    1.3706   -0.2334 C   0  0  2  0  0  0  0  0  0  0  0  0
   -2.7677    0.9824    0.7934 O   0  0  0  0  0  0  0  0  0  0  0  0
   -4.0447    0.8161    0.3244 C   0  0  2  0  0  0  0  0  0  0  0  0
   -4.8375   -0.1926    1.0879 C   0  0  0  0  0  0  0  0  0  0  0  0
   -6.1087   -0.3154    0.5718 O   0  0  0  0  0  0  0  0  0  0  0  0
   -7.0268   -1.4556    1.4230 P   0  0  0  0  0  5  0  0  0  0  0  0
   -8.2472   -1.8678    0.6583 O   0  0  0  0  0  0  0  0  0  0  0  0
   -7.4969   -0.8907    2.9372 O   0  0  0  0  0  0  0  0  0  0  0  0
   -6.0440   -2.8454    1.5726 O   0  0  0  0  0  0  0  0  0  0  0  0
   -3.8942    0.4343   -1.1444 C   0  0  1  0  0  0  0  0  0  0  0  0
   -5.0208    0.7089   -1.8793 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.7118    1.3052   -1.5172 C   0  0  1  0  0  0  0  0  0  0  0  0
   -3.1862    2.5509   -1.9160 O   0  0  0  0  0  0  0  0  0  0  0  0
    7.4646    1.6479    0.5038 H   0  0  0  0  0  0  0  0  0  0  0  0
    8.0474    0.4894    1.8021 H   0  0  0  0  0  0  0  0  0  0  0  0
    6.4406    1.3031    1.9923 H   0  0  0  0  0  0  0  0  0  0  0  0
    7.8348   -1.6497    1.3880 H   0  0  0  0  0  0  0  0  0  0  0  0
    7.5697   -1.9578   -0.3503 H   0  0  0  0  0  0  0  0  0  0  0  0
    6.2631   -2.3066    0.9007 H   0  0  0  0  0  0  0  0  0  0  0  0
    5.1350    1.0490   -0.3910 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.9357   -0.8326   -2.1975 H   0  0  0  0  0  0  0  0  0  0  0  0
    5.4640   -1.9849   -0.9510 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.2105   -2.0423   -0.2884 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.5724    3.0981   -2.0586 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4987   -1.2661    0.6446 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.6364    2.4181   -0.0506 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.6067    1.7958    0.3119 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.2850   -1.1703    1.0190 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.8694    0.1265    2.1430 H   0  0  0  0  0  0  0  0  0  0  0  0
   -8.3724   -0.4279    2.9175 H   0  0  0  0  0  0  0  0  0  0  0  0
   -6.4661   -3.6411    1.2096 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.6536   -0.6482   -1.2569 H   0  0  0  0  0  0  0  0  0  0  0  0
   -5.2293   -0.0431   -2.5108 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.0730    0.8399   -2.2938 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.4072    3.0893   -1.1066 H   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0
  2  3  1  0
  2  4  2  3
  4  5  1  0
  5  6  1  0
  6  7  1  0
  7  8  2  0
  8  9  1  0
  9 10  2  0
 10 11  1  0
 11 12  2  0
 12 13  1  0
 13 14  2  0
 14 15  1  0
 15 16  1  0
 16 17  1  0
 17 18  1  0
 18 19  1  0
 19 20  1  0
 20 21  1  0
 21 22  2  0
 21 23  1  0
 21 24  1  0
 18 25  1  0
 25 26  1  0
 25 27  1  0
 27 28  1  0
 12  7  1  0
 27 16  1  0
 15 11  1  0
  1 29  1  0
  1 30  1  0
  1 31  1  0
  3 32  1  0
  3 33  1  0
  3 34  1  0
  4 35  1  0
  5 36  1  0
  5 37  1  0
  6 38  1  0
  9 39  1  0
 14 40  1  0
 16 41  1  1
 18 42  1  6
 19 43  1  0
 19 44  1  0
 23 45  1  0
 24 46  1  0
 25 47  1  1
 26 48  1  0
 27 49  1  6
 28 50  1  0
M  END


  Mrv1652304202018272D          

 28 30  0  0  0  0            999 V2000
 9987.5047 9984.4219    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
 9989.2953 9984.4116    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
 9989.8027 9986.2738    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 9990.5185 9985.8621    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
 9991.2323 9986.2738    0.0000 P   0  0  0  0  0  0  0  0  0  0  0  0
 9990.8217 9986.9888    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
 9991.9480 9985.8621    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
 9991.6468 9986.9888    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
 9988.4166 9986.3548    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
 9987.7500 9985.8705    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
 9988.0046 9985.0869    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
 9988.8285 9985.0869    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
 9989.0831 9985.8705    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
 9987.0333 9986.2754    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
 9987.0333 9987.0993    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 9985.6062 9986.2754    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 9985.6062 9987.0993    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 9986.3197 9987.5112    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
 9984.8901 9985.8630    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
 9984.1767 9986.2749    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 9984.1767 9987.0990    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
 9984.8901 9987.5109    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 9982.7450 9989.5765    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 9982.0301 9988.3389    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 9982.7450 9988.7514    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 9983.4600 9988.3389    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 9984.1752 9988.7514    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 9984.8901 9988.3389    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
  3  4  1  0  0  0  0
  4  5  1  0  0  0  0
  5  6  2  0  0  0  0
  5  7  1  0  0  0  0
  5  8  1  0  0  0  0
 10 11  1  0  0  0  0
 11 12  1  0  0  0  0
 12 13  1  0  0  0  0
  9 10  1  0  0  0  0
  9 13  1  0  0  0  0
 11  1  1  1  0  0  0
 12  2  1  1  0  0  0
 13  3  1  6  0  0  0
 10 14  1  6  0  0  0
 14 15  1  0  0  0  0
 17 22  1  0  0  0  0
 19 16  1  0  0  0  0
 16 14  1  0  0  0  0
 18 15  2  0  0  0  0
 18 17  1  0  0  0  0
 17 16  2  0  0  0  0
 22 28  1  0  0  0  0
 20 19  2  0  0  0  0
 21 20  1  0  0  0  0
 22 21  2  0  0  0  0
 25 23  1  0  0  0  0
 25 24  1  0  0  0  0
 26 25  2  0  0  0  0
 27 26  1  0  0  0  0
 28 27  1  0  0  0  0
M  END
> <DATABASE_ID>
MMDBc0053381

> <DATABASE_NAME>
MIME

> <SMILES>
CC(C)=CCNC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(O)(O)=O)[C@@H](O)[C@H]1O

> <INCHI_IDENTIFIER>
InChI=1S/C15H22N5O7P/c1-8(2)3-4-16-13-10-14(18-6-17-13)20(7-19-10)15-12(22)11(21)9(27-15)5-26-28(23,24)25/h3,6-7,9,11-12,15,21-22H,4-5H2,1-2H3,(H,16,17,18)(H2,23,24,25)/t9-,11-,12-,15-/m1/s1

> <INCHI_KEY>
DUISZFLWBAPRBR-SDBHATRESA-N

> <FORMULA>
C15H22N5O7P

> <MOLECULAR_WEIGHT>
415.343

> <EXACT_MASS>
415.125685066

> <JCHEM_ACCEPTOR_COUNT>
10

> <JCHEM_ATOM_COUNT>
50

> <JCHEM_AVERAGE_POLARIZABILITY>
39.73754594865307

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
5

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
{[(2R,3S,4R,5R)-3,4-dihydroxy-5-{6-[(3-methylbut-2-en-1-yl)amino]-9H-purin-9-yl}oxolan-2-yl]methoxy}phosphonic acid

> <ALOGPS_LOGP>
-0.32

> <JCHEM_LOGP>
-2.857238207207811

> <ALOGPS_LOGS>
-2.36

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
3

> <JCHEM_PHYSIOLOGICAL_CHARGE>
-2

> <JCHEM_PKA>
6.251748329837749

> <JCHEM_PKA_STRONGEST_ACIDIC>
1.2234660390076773

> <JCHEM_PKA_STRONGEST_BASIC>
3.7017886982986403

> <JCHEM_POLAR_SURFACE_AREA>
172.07999999999996

> <JCHEM_REFRACTIVITY>
98.6801

> <JCHEM_ROTATABLE_BOND_COUNT>
7

> <JCHEM_RULE_OF_FIVE>
1

> <ALOGPS_SOLUBILITY>
1.83e+00 g/l

> <JCHEM_TRADITIONAL_IUPAC>
Isopentenyl-AMP

> <JCHEM_VEBER_RULE>
0

$$$$

HMDB0304433
     RDKit          3D
N6-(delta2-isopentenyl)-adenosine 5'-monophosphate
 50 52  0  0  0  0  0  0  0  0999 V2000
    7.1678    0.8727    1.2580 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.5533   -0.2363    0.4712 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.0921   -1.6149    0.5776 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.5252    0.0464   -0.3143 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.9092   -1.0486   -1.0987 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.5191   -1.1577   -0.6994 N   0  0  0  0  0  0  0  0  0  0  0  0
    2.6386   -0.0616   -0.8830 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.0015    1.1101   -1.4194 N   0  0  0  0  0  0  0  0  0  0  0  0
    2.1900    2.1631   -1.6065 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.9069    2.0543   -1.2327 N   0  0  0  0  0  0  0  0  0  0  0  0
    0.4610    0.9175   -0.6879 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.3140   -0.1707   -0.4983 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.6237   -1.1635    0.0555 N   0  0  0  0  0  0  0  0  0  0  0  0
   -0.6410   -0.7307    0.2201 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7643    0.5326   -0.2248 N   0  0  0  0  0  0  0  0  0  0  0  0
   -1.9504    1.3706   -0.2334 C   0  0  2  0  0  0  0  0  0  0  0  0
   -2.7677    0.9824    0.7934 O   0  0  0  0  0  0  0  0  0  0  0  0
   -4.0447    0.8161    0.3244 C   0  0  2  0  0  0  0  0  0  0  0  0
   -4.8375   -0.1926    1.0879 C   0  0  0  0  0  0  0  0  0  0  0  0
   -6.1087   -0.3154    0.5718 O   0  0  0  0  0  0  0  0  0  0  0  0
   -7.0268   -1.4556    1.4230 P   0  0  0  0  0  5  0  0  0  0  0  0
   -8.2472   -1.8678    0.6583 O   0  0  0  0  0  0  0  0  0  0  0  0
   -7.4969   -0.8907    2.9372 O   0  0  0  0  0  0  0  0  0  0  0  0
   -6.0440   -2.8454    1.5726 O   0  0  0  0  0  0  0  0  0  0  0  0
   -3.8942    0.4343   -1.1444 C   0  0  1  0  0  0  0  0  0  0  0  0
   -5.0208    0.7089   -1.8793 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.7118    1.3052   -1.5172 C   0  0  1  0  0  0  0  0  0  0  0  0
   -3.1862    2.5509   -1.9160 O   0  0  0  0  0  0  0  0  0  0  0  0
    7.4646    1.6479    0.5038 H   0  0  0  0  0  0  0  0  0  0  0  0
    8.0474    0.4894    1.8021 H   0  0  0  0  0  0  0  0  0  0  0  0
    6.4406    1.3031    1.9923 H   0  0  0  0  0  0  0  0  0  0  0  0
    7.8348   -1.6497    1.3880 H   0  0  0  0  0  0  0  0  0  0  0  0
    7.5697   -1.9578   -0.3503 H   0  0  0  0  0  0  0  0  0  0  0  0
    6.2631   -2.3066    0.9007 H   0  0  0  0  0  0  0  0  0  0  0  0
    5.1350    1.0490   -0.3910 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.9357   -0.8326   -2.1975 H   0  0  0  0  0  0  0  0  0  0  0  0
    5.4640   -1.9849   -0.9510 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.2105   -2.0423   -0.2884 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.5724    3.0981   -2.0586 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4987   -1.2661    0.6446 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.6364    2.4181   -0.0506 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.6067    1.7958    0.3119 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.2850   -1.1703    1.0190 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.8694    0.1265    2.1430 H   0  0  0  0  0  0  0  0  0  0  0  0
   -8.3724   -0.4279    2.9175 H   0  0  0  0  0  0  0  0  0  0  0  0
   -6.4661   -3.6411    1.2096 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.6536   -0.6482   -1.2569 H   0  0  0  0  0  0  0  0  0  0  0  0
   -5.2293   -0.0431   -2.5108 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.0730    0.8399   -2.2938 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.4072    3.0893   -1.1066 H   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0
  2  3  1  0
  2  4  2  3
  4  5  1  0
  5  6  1  0
  6  7  1  0
  7  8  2  0
  8  9  1  0
  9 10  2  0
 10 11  1  0
 11 12  2  0
 12 13  1  0
 13 14  2  0
 14 15  1  0
 15 16  1  0
 16 17  1  0
 17 18  1  0
 18 19  1  0
 19 20  1  0
 20 21  1  0
 21 22  2  0
 21 23  1  0
 21 24  1  0
 18 25  1  0
 25 26  1  0
 25 27  1  0
 27 28  1  0
 12  7  1  0
 27 16  1  0
 15 11  1  0
  1 29  1  0
  1 30  1  0
  1 31  1  0
  3 32  1  0
  3 33  1  0
  3 34  1  0
  4 35  1  0
  5 36  1  0
  5 37  1  0
  6 38  1  0
  9 39  1  0
 14 40  1  0
 16 41  1  1
 18 42  1  6
 19 43  1  0
 19 44  1  0
 23 45  1  0
 24 46  1  0
 25 47  1  1
 26 48  1  0
 27 49  1  6
 28 50  1  0
M  END

HEADER    PROTEIN                                 20-APR-20   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   20-APR-20         0                                  
HETATM    1  O   UNK     0    8643.3428637.587   0.000  0.00  0.00           O+0
HETATM    2  O   UNK     0    8646.6858637.568   0.000  0.00  0.00           O+0
HETATM    3  C   UNK     0    8647.6328641.045   0.000  0.00  0.00           C+0
HETATM    4  O   UNK     0    8648.9688640.276   0.000  0.00  0.00           O+0
HETATM    5  P   UNK     0    8650.3008641.045   0.000  0.00  0.00           P+0
HETATM    6  O   UNK     0    8649.5348642.379   0.000  0.00  0.00           O+0
HETATM    7  O   UNK     0    8651.6368640.276   0.000  0.00  0.00           O+0
HETATM    8  O   UNK     0    8651.0748642.379   0.000  0.00  0.00           O+0
HETATM    9  O   UNK     0    8645.0448641.196   0.000  0.00  0.00           O+0
HETATM   10  C   UNK     0    8643.8008640.292   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0    8644.2758638.829   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0    8645.8138638.829   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0    8646.2888640.292   0.000  0.00  0.00           C+0
HETATM   14  N   UNK     0    8642.4628641.047   0.000  0.00  0.00           N+0
HETATM   15  C   UNK     0    8642.4628642.585   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0    8639.7988641.047   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0    8639.7988642.585   0.000  0.00  0.00           C+0
HETATM   18  N   UNK     0    8641.1308643.354   0.000  0.00  0.00           N+0
HETATM   19  N   UNK     0    8638.4628640.278   0.000  0.00  0.00           N+0
HETATM   20  C   UNK     0    8637.1308641.047   0.000  0.00  0.00           C+0
HETATM   21  N   UNK     0    8637.1308642.585   0.000  0.00  0.00           N+0
HETATM   22  C   UNK     0    8638.4628643.354   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0    8634.4578647.210   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0    8633.1238644.899   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0    8634.4578645.669   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0    8635.7928644.899   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0    8637.1278645.669   0.000  0.00  0.00           C+0
HETATM   28  N   UNK     0    8638.4628644.899   0.000  0.00  0.00           N+0
CONECT    1   11                                                            
CONECT    2   12                                                            
CONECT    3    4   13                                                       
CONECT    4    3    5                                                       
CONECT    5    4    6    7    8                                             
CONECT    6    5                                                            
CONECT    7    5                                                            
CONECT    8    5                                                            
CONECT    9   10   13                                                       
CONECT   10   11    9   14                                                  
CONECT   11   10   12    1                                                  
CONECT   12   11   13    2                                                  
CONECT   13   12    9    3                                                  
CONECT   14   10   15   16                                                  
CONECT   15   14   18                                                       
CONECT   16   19   14   17                                                  
CONECT   17   22   18   16                                                  
CONECT   18   15   17                                                       
CONECT   19   16   20                                                       
CONECT   20   19   21                                                       
CONECT   21   20   22                                                       
CONECT   22   17   28   21                                                  
CONECT   23   25                                                            
CONECT   24   25                                                            
CONECT   25   23   24   26                                                  
CONECT   26   25   27                                                       
CONECT   27   26   28                                                       
CONECT   28   22   27                                                       
MASTER        0    0    0    0    0    0    0    0   28    0   60    0
END

COMPND    HMDB0304433
HETATM    1  C1  UNL     1       7.168   0.873   1.258  1.00  0.00           C  
HETATM    2  C2  UNL     1       6.553  -0.236   0.471  1.00  0.00           C  
HETATM    3  C3  UNL     1       7.092  -1.615   0.578  1.00  0.00           C  
HETATM    4  C4  UNL     1       5.525   0.046  -0.314  1.00  0.00           C  
HETATM    5  C5  UNL     1       4.909  -1.049  -1.099  1.00  0.00           C  
HETATM    6  N1  UNL     1       3.519  -1.158  -0.699  1.00  0.00           N  
HETATM    7  C6  UNL     1       2.639  -0.062  -0.883  1.00  0.00           C  
HETATM    8  N2  UNL     1       3.001   1.110  -1.419  1.00  0.00           N  
HETATM    9  C7  UNL     1       2.190   2.163  -1.606  1.00  0.00           C  
HETATM   10  N3  UNL     1       0.907   2.054  -1.233  1.00  0.00           N  
HETATM   11  C8  UNL     1       0.461   0.917  -0.688  1.00  0.00           C  
HETATM   12  C9  UNL     1       1.314  -0.171  -0.498  1.00  0.00           C  
HETATM   13  N4  UNL     1       0.624  -1.164   0.055  1.00  0.00           N  
HETATM   14  C10 UNL     1      -0.641  -0.731   0.220  1.00  0.00           C  
HETATM   15  N5  UNL     1      -0.764   0.533  -0.225  1.00  0.00           N  
HETATM   16  C11 UNL     1      -1.950   1.371  -0.233  1.00  0.00           C  
HETATM   17  O1  UNL     1      -2.768   0.982   0.793  1.00  0.00           O  
HETATM   18  C12 UNL     1      -4.045   0.816   0.324  1.00  0.00           C  
HETATM   19  C13 UNL     1      -4.838  -0.193   1.088  1.00  0.00           C  
HETATM   20  O2  UNL     1      -6.109  -0.315   0.572  1.00  0.00           O  
HETATM   21  P1  UNL     1      -7.027  -1.456   1.423  1.00  0.00           P  
HETATM   22  O3  UNL     1      -8.247  -1.868   0.658  1.00  0.00           O  
HETATM   23  O4  UNL     1      -7.497  -0.891   2.937  1.00  0.00           O  
HETATM   24  O5  UNL     1      -6.044  -2.845   1.573  1.00  0.00           O  
HETATM   25  C14 UNL     1      -3.894   0.434  -1.144  1.00  0.00           C  
HETATM   26  O6  UNL     1      -5.021   0.709  -1.879  1.00  0.00           O  
HETATM   27  C15 UNL     1      -2.712   1.305  -1.517  1.00  0.00           C  
HETATM   28  O7  UNL     1      -3.186   2.551  -1.916  1.00  0.00           O  
HETATM   29  H1  UNL     1       7.465   1.648   0.504  1.00  0.00           H  
HETATM   30  H2  UNL     1       8.047   0.489   1.802  1.00  0.00           H  
HETATM   31  H3  UNL     1       6.441   1.303   1.992  1.00  0.00           H  
HETATM   32  H4  UNL     1       7.835  -1.650   1.388  1.00  0.00           H  
HETATM   33  H5  UNL     1       7.570  -1.958  -0.350  1.00  0.00           H  
HETATM   34  H6  UNL     1       6.263  -2.307   0.901  1.00  0.00           H  
HETATM   35  H7  UNL     1       5.135   1.049  -0.391  1.00  0.00           H  
HETATM   36  H8  UNL     1       4.936  -0.833  -2.197  1.00  0.00           H  
HETATM   37  H9  UNL     1       5.464  -1.985  -0.951  1.00  0.00           H  
HETATM   38  H10 UNL     1       3.211  -2.042  -0.288  1.00  0.00           H  
HETATM   39  H11 UNL     1       2.572   3.098  -2.059  1.00  0.00           H  
HETATM   40  H12 UNL     1      -1.499  -1.266   0.645  1.00  0.00           H  
HETATM   41  H13 UNL     1      -1.636   2.418  -0.051  1.00  0.00           H  
HETATM   42  H14 UNL     1      -4.607   1.796   0.312  1.00  0.00           H  
HETATM   43  H15 UNL     1      -4.285  -1.170   1.019  1.00  0.00           H  
HETATM   44  H16 UNL     1      -4.869   0.126   2.143  1.00  0.00           H  
HETATM   45  H17 UNL     1      -8.372  -0.428   2.918  1.00  0.00           H  
HETATM   46  H18 UNL     1      -6.466  -3.641   1.210  1.00  0.00           H  
HETATM   47  H19 UNL     1      -3.654  -0.648  -1.257  1.00  0.00           H  
HETATM   48  H20 UNL     1      -5.229  -0.043  -2.511  1.00  0.00           H  
HETATM   49  H21 UNL     1      -2.073   0.840  -2.294  1.00  0.00           H  
HETATM   50  H22 UNL     1      -3.407   3.089  -1.107  1.00  0.00           H  
CONECT    1    2   29   30   31
CONECT    2    3    4    4
CONECT    3   32   33   34
CONECT    4    5   35
CONECT    5    6   36   37
CONECT    6    7   38
CONECT    7    8    8   12
CONECT    8    9
CONECT    9   10   10   39
CONECT   10   11
CONECT   11   12   12   15
CONECT   12   13
CONECT   13   14   14
CONECT   14   15   40
CONECT   15   16
CONECT   16   17   27   41
CONECT   17   18
CONECT   18   19   25   42
CONECT   19   20   43   44
CONECT   20   21
CONECT   21   22   22   23   24
CONECT   23   45
CONECT   24   46
CONECT   25   26   27   47
CONECT   26   48
CONECT   27   28   49
CONECT   28   50
END

HMDB0304433
     RDKit          3D
N6-(delta2-isopentenyl)-adenosine 5'-monophosphate
 50 52  0  0  0  0  0  0  0  0999 V2000
    7.1678    0.8727    1.2580 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.5533   -0.2363    0.4712 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.0921   -1.6149    0.5776 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.5252    0.0464   -0.3143 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.9092   -1.0486   -1.0987 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.5191   -1.1577   -0.6994 N   0  0  0  0  0  0  0  0  0  0  0  0
    2.6386   -0.0616   -0.8830 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.0015    1.1101   -1.4194 N   0  0  0  0  0  0  0  0  0  0  0  0
    2.1900    2.1631   -1.6065 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.9069    2.0543   -1.2327 N   0  0  0  0  0  0  0  0  0  0  0  0
    0.4610    0.9175   -0.6879 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.3140   -0.1707   -0.4983 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.6237   -1.1635    0.0555 N   0  0  0  0  0  0  0  0  0  0  0  0
   -0.6410   -0.7307    0.2201 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7643    0.5326   -0.2248 N   0  0  0  0  0  0  0  0  0  0  0  0
   -1.9504    1.3706   -0.2334 C   0  0  2  0  0  0  0  0  0  0  0  0
   -2.7677    0.9824    0.7934 O   0  0  0  0  0  0  0  0  0  0  0  0
   -4.0447    0.8161    0.3244 C   0  0  2  0  0  0  0  0  0  0  0  0
   -4.8375   -0.1926    1.0879 C   0  0  0  0  0  0  0  0  0  0  0  0
   -6.1087   -0.3154    0.5718 O   0  0  0  0  0  0  0  0  0  0  0  0
   -7.0268   -1.4556    1.4230 P   0  0  0  0  0  5  0  0  0  0  0  0
   -8.2472   -1.8678    0.6583 O   0  0  0  0  0  0  0  0  0  0  0  0
   -7.4969   -0.8907    2.9372 O   0  0  0  0  0  0  0  0  0  0  0  0
   -6.0440   -2.8454    1.5726 O   0  0  0  0  0  0  0  0  0  0  0  0
   -3.8942    0.4343   -1.1444 C   0  0  1  0  0  0  0  0  0  0  0  0
   -5.0208    0.7089   -1.8793 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.7118    1.3052   -1.5172 C   0  0  1  0  0  0  0  0  0  0  0  0
   -3.1862    2.5509   -1.9160 O   0  0  0  0  0  0  0  0  0  0  0  0
    7.4646    1.6479    0.5038 H   0  0  0  0  0  0  0  0  0  0  0  0
    8.0474    0.4894    1.8021 H   0  0  0  0  0  0  0  0  0  0  0  0
    6.4406    1.3031    1.9923 H   0  0  0  0  0  0  0  0  0  0  0  0
    7.8348   -1.6497    1.3880 H   0  0  0  0  0  0  0  0  0  0  0  0
    7.5697   -1.9578   -0.3503 H   0  0  0  0  0  0  0  0  0  0  0  0
    6.2631   -2.3066    0.9007 H   0  0  0  0  0  0  0  0  0  0  0  0
    5.1350    1.0490   -0.3910 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.9357   -0.8326   -2.1975 H   0  0  0  0  0  0  0  0  0  0  0  0
    5.4640   -1.9849   -0.9510 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.2105   -2.0423   -0.2884 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.5724    3.0981   -2.0586 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4987   -1.2661    0.6446 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.6364    2.4181   -0.0506 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.6067    1.7958    0.3119 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.2850   -1.1703    1.0190 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.8694    0.1265    2.1430 H   0  0  0  0  0  0  0  0  0  0  0  0
   -8.3724   -0.4279    2.9175 H   0  0  0  0  0  0  0  0  0  0  0  0
   -6.4661   -3.6411    1.2096 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.6536   -0.6482   -1.2569 H   0  0  0  0  0  0  0  0  0  0  0  0
   -5.2293   -0.0431   -2.5108 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.0730    0.8399   -2.2938 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.4072    3.0893   -1.1066 H   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0
  2  3  1  0
  2  4  2  3
  4  5  1  0
  5  6  1  0
  6  7  1  0
  7  8  2  0
  8  9  1  0
  9 10  2  0
 10 11  1  0
 11 12  2  0
 12 13  1  0
 13 14  2  0
 14 15  1  0
 15 16  1  0
 16 17  1  0
 17 18  1  0
 18 19  1  0
 19 20  1  0
 20 21  1  0
 21 22  2  0
 21 23  1  0
 21 24  1  0
 18 25  1  0
 25 26  1  0
 25 27  1  0
 27 28  1  0
 12  7  1  0
 27 16  1  0
 15 11  1  0
  1 29  1  0
  1 30  1  0
  1 31  1  0
  3 32  1  0
  3 33  1  0
  3 34  1  0
  4 35  1  0
  5 36  1  0
  5 37  1  0
  6 38  1  0
  9 39  1  0
 14 40  1  0
 16 41  1  1
 18 42  1  6
 19 43  1  0
 19 44  1  0
 23 45  1  0
 24 46  1  0
 25 47  1  1
 26 48  1  0
 27 49  1  6
 28 50  1  0
M  END

Synonyms

Value	Source
Isopentenyl-AMP	ChEBI
Isopentenyladenosine riboside-5'-monophosphate	ChEBI
Isopentenyladenosine-5'-monophosphate	ChEBI
N-(3-Methyl-2-butenyl)-5'-adenylic acid	ChEBI
N6-(delta(2)-Isopentenyl)adenosine 5'-monophosphate	ChEBI
N6-(delta2-Isopentenyl)-adenosine 5'-monophosphate	ChEBI
N(6)-(Delta(2)-Isopentenyl)adenosine 5'-monophosphate	ChEBI
N(6)-(Dimethylallyl)adenosine 5'-(dihydrogen phosphate)	ChEBI
N6-(Dimethylallyl)adenosine 5'-phosphate	ChEBI
N(6)-(Dimethylallyl)adenosine 5'-phosphate	ChEBI
N(6)-Dimethylallyl-5'-adenylic acid	ChEBI
N(6)-Dimethylallyl-AMP	ChEBI
N(6)-Isopentenyladenosine-5'-monophosphate	ChEBI
Isopentenyladenosine riboside-5'-monophosphoric acid	Generator
Isopentenyladenosine-5'-monophosphoric acid	Generator
N-(3-Methyl-2-butenyl)-5'-adenylate	Generator
N6-(delta(2)-Isopentenyl)adenosine 5'-monophosphoric acid	Generator
N6-(Δ(2)-isopentenyl)adenosine 5'-monophosphate	Generator
N6-(Δ(2)-isopentenyl)adenosine 5'-monophosphoric acid	Generator
N6-(delta2-Isopentenyl)-adenosine 5'-monophosphoric acid	Generator
N6-(Δ2-isopentenyl)-adenosine 5'-monophosphate	Generator
N6-(Δ2-isopentenyl)-adenosine 5'-monophosphoric acid	Generator
N(6)-(delta(2)-Isopentenyl)adenosine 5'-monophosphoric acid	Generator
N(6)-(Δ(2)-isopentenyl)adenosine 5'-monophosphate	Generator
N(6)-(Δ(2)-isopentenyl)adenosine 5'-monophosphoric acid	Generator
N(6)-(Dimethylallyl)adenosine 5'-(dihydrogen phosphoric acid)	Generator
N6-(Dimethylallyl)adenosine 5'-phosphoric acid	Generator
N(6)-(Dimethylallyl)adenosine 5'-phosphoric acid	Generator
N(6)-Dimethylallyl-5'-adenylate	Generator
N(6)-Isopentenyladenosine-5'-monophosphoric acid	Generator
N(6)-(Dimethylallyl)adenosine 5'-monophosphoric acid	Generator

Molecular Formula

C₁₅H₂₂N₅O₇P

Average Mass

415.343

Monoisotopic Mass

415.125685066

IUPAC Name

{[(2R,3S,4R,5R)-3,4-dihydroxy-5-{6-[(3-methylbut-2-en-1-yl)amino]-9H-purin-9-yl}oxolan-2-yl]methoxy}phosphonic acid

Traditional Name

Isopentenyl-AMP

CAS Registry Number

Not Available

SMILES

CC(C)=CCNC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(O)(O)=O)[C@@H](O)[C@H]1O

InChI Identifier

InChI=1S/C15H22N5O7P/c1-8(2)3-4-16-13-10-14(18-6-17-13)20(7-19-10)15-12(22)11(21)9(27-15)5-26-28(23,24)25/h3,6-7,9,11-12,15,21-22H,4-5H2,1-2H3,(H,16,17,18)(H2,23,24,25)/t9-,11-,12-,15-/m1/s1

InChI Key

DUISZFLWBAPRBR-SDBHATRESA-N

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as nicotinamide nucleotides. These are pyridine nucleotides, in which the pyridine base is nicotinamide or a derivative thereof.

Kingdom

Organic compounds

Super Class

Nucleosides, nucleotides, and analogues

Class

Pyridine nucleotides

Sub Class

Nicotinamide nucleotides

Direct Parent

Nicotinamide nucleotides

Alternative Parents

Substituents

Nicotinamide-nucleotide
Pentose phosphate
Pentose-5-phosphate
Glycosyl compound
N-glycosyl compound
Monosaccharide phosphate
N-substituted nicotinamide
Pentose monosaccharide
Dihydropyridine
Hydropyridine
Monosaccharide
Alkyl phosphate
Organic phosphoric acid derivative
Phosphoric acid ester
Vinylogous amide
Tetrahydrofuran
Carboxamide group
1,2-diol
Secondary alcohol
Primary carboxylic acid amide
Organoheterocyclic compound
Azacycle
Enamine
Oxacycle
Carboxylic acid derivative
Carbonyl group
Organic nitrogen compound
Alcohol
Hydrocarbon derivative
Organic oxide
Organonitrogen compound
Organooxygen compound
Organic oxygen compound
Organopnictogen compound
Organic anion
Aliphatic heteromonocyclic compound

Molecular Framework

Aliphatic heteromonocyclic compounds

External Descriptors

a small molecule (NMNH )

Functional Ontology

Not Available

Physical Properties

State

Expected Solid

Predicted Properties

Property	Value	Source
Water Solubility	1.83 g/L	ALOGPS
logP	-0.32	ALOGPS
logP	-2.9	ChemAxon
logS	-2.4	ALOGPS
pKa (Strongest Acidic)	1.22	ChemAxon
pKa (Strongest Basic)	3.7	ChemAxon
Physiological Charge	-2	ChemAxon
Hydrogen Acceptor Count	10	ChemAxon
Hydrogen Donor Count	5	ChemAxon
Polar Surface Area	172.08 Å²	ChemAxon
Rotatable Bond Count	7	ChemAxon
Refractivity	98.68 m³·mol⁻¹	ChemAxon
Polarizability	39.74 Å³	ChemAxon
Number of Rings	3	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	Yes	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	Yes	ChemAxon

Spectra

Spectrum Type	Description	Splash Key	Deposition Date	View
Predicted GC-MS	Predicted GC-MS Spectrum - GC-MS (TMS_4_4) - 70eV, Positive	Not Available	2022-08-08	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 10V, Positive	splash10-0uxr-2092200000-3e5e9ed89d4634952818	2019-02-22	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 20V, Positive	splash10-0udi-5490000000-64cdb7f1346c310f4278	2019-02-22	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 40V, Positive	splash10-0uxr-9460000000-7756e181923124ce7938	2019-02-22	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 10V, Negative	splash10-0imi-7072900000-8c487afe2b1f0ad23088	2019-02-23	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 20V, Negative	splash10-0fb9-9150000000-98b5ddeab68e1c2ba149	2019-02-23	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 40V, Negative	splash10-004i-9100000000-f0eeff9a24fee8132a7c	2019-02-23	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 10V, Positive	splash10-014i-0032900000-e3ccb496083bab162c2d	2021-10-21	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 20V, Positive	splash10-0udi-0292200000-dad9466447a1d355b758	2021-10-21	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 40V, Positive	splash10-0udi-3690000000-c7104a4e07b640bb276f	2021-10-21	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 10V, Negative	splash10-03di-5000900000-c6824de257ee37577cd3	2021-10-21	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 20V, Negative	splash10-004i-9000200000-fa18e0ba1d6c68dca3e6	2021-10-21	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 40V, Negative	splash10-004i-9000000000-59070a00c7090c220975	2021-10-21	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 100 MHz, H₂O, predicted)		2022-08-18	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)		2022-08-18	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 1000 MHz, H₂O, predicted)		2022-08-18	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)		2022-08-18	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 200 MHz, H₂O, predicted)		2022-08-18	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)		2022-08-18	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 300 MHz, H₂O, predicted)		2022-08-18	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)		2022-08-18	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 400 MHz, H₂O, predicted)		2022-08-18	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)		2022-08-18	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 500 MHz, H₂O, predicted)		2022-08-18	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)		2022-08-18	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 600 MHz, H₂O, predicted)		2022-08-18	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)		2022-08-18	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 700 MHz, H₂O, predicted)		2022-08-18	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)		2022-08-18	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 800 MHz, H₂O, predicted)		2022-08-18	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)		2022-08-18	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 900 MHz, H₂O, predicted)		2022-08-18	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)		2022-08-18	View Spectrum

Chromatographic Retention Times and Retention Indices

Retention Times

Chromatography Type	Technique	Column	Deposition Date	Retention Time (s)
Liquid Chromatography	HILIC	Waters Acquity UPLC-BEH Amide column (eluted)	2025-10-24	385.2
Liquid Chromatography	HILIC	Accucore 150 Amide HILIC (eluted)	2025-10-24	361.1
Liquid Chromatography	Reversed-phase	Hypersil Gold 1.9 µm C18 (eluted)	2025-10-24	250.2
Liquid Chromatography	Reversed-phase	Agilent Zorbax Eclipse Plus C18 (2.1 mm x 150 mm, 3.5 um) (eluted)	2025-10-24	288.1
Liquid Chromatography	Reversed-phase	XBridge C18 3.5u 2.1x50 mm (eluted)	2025-10-24	319.4
Liquid Chromatography	Reversed-phase	Ascentis Express C18 (eluted)	2025-10-24	178.4
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC HSS T3 C18 (eluted)	2025-10-24	1140.9
Liquid Chromatography	HILIC	Merck SeQuant ZIC-HILIC (eluted)	2025-10-24	573.3
Liquid Chromatography	HILIC	Merck SeQuant ZIC-pHILIC (eluted)	2025-10-24	376.1
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC HSS T3 C18 (eluted)	2025-10-24	126.4
Liquid Chromatography	HILIC	Merck SeQuant ZIC-HILIC (eluted)	2025-10-24	326.9
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC HSS T3 C18 (eluted)	2025-10-24	142.7
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC BEH C18 (eluted)	2025-10-24	74.5
Liquid Chromatography	HILIC	Merck SeQuant ZIC-pHILIC column (eluted)	2025-10-24	192.8
Liquid Chromatography	HILIC	Merck SeQuant ZIC-pHILIC column (eluted)	2025-10-24	431.6
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC BEH C18 (void)	2025-10-24	46.7
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC BEH C18 (eluted)	2025-10-24	150.4
Liquid Chromatography	Reversed-phase	Kinetex Core-Shell C18 2.6 um, 3.0 x 100 mm, Phenomenex (eluted)	2025-10-24	567.0
Liquid Chromatography	Reversed-phase	Waters Atlantis T3 (2.1 x 150 mm, 5 um) (eluted)	2025-10-24	572.5

Retention Indices

Chromatography Type	Peak Label	SMILES	Stationary Phase	Deposition Date	Retention Index
Gas Chromatography	Isopentenyl-AMP_TMS_1	CC(C)=CCNC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O)[C@@H](O[Si](C)(C)C)[C@H]1O	standard non polar	2025-10-24	1857.76
Gas Chromatography	Isopentenyl-AMP_TMS_2	CC(C)=CCNC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O)[C@@H](O)[C@H]1O[Si](C)(C)C	standard non polar	2025-10-24	1783.76
Gas Chromatography	Isopentenyl-AMP_TMS_3	CC(C)=CCNC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O[Si](C)(C)C)[C@@H](O)[C@H]1O	standard non polar	2025-10-24	2473.52
Gas Chromatography	Isopentenyl-AMP_TMS_4	CC(C)=CCN(C1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O)[C@@H](O)[C@H]1O)[Si](C)(C)C	standard non polar	2025-10-24	1593.72
Gas Chromatography	Isopentenyl-AMP_TMS_5	CC(C)=CCNC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O)[C@@H](O[Si](C)(C)C)[C@H]1O[Si](C)(C)C	standard non polar	2025-10-24	2750.89
Gas Chromatography	Isopentenyl-AMP_TMS_6	CC(C)=CCNC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]1O	standard non polar	2025-10-24	1087.95
Gas Chromatography	Isopentenyl-AMP_TMS_7	CC(C)=CCN(C1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O)[C@@H](O[Si](C)(C)C)[C@H]1O)[Si](C)(C)C	standard non polar	2025-10-24	3316.14
Gas Chromatography	Isopentenyl-AMP_TMS_8	CC(C)=CCNC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O[Si](C)(C)C)[C@@H](O)[C@H]1O[Si](C)(C)C	standard non polar	2025-10-24	3176.86
Gas Chromatography	Isopentenyl-AMP_TMS_9	CC(C)=CCN(C1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O)[C@@H](O)[C@H]1O[Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	2364.18
Gas Chromatography	Isopentenyl-AMP_TMS_10	CC(C)=CCNC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O[Si](C)(C)C)O[Si](C)(C)C)[C@@H](O)[C@H]1O	standard non polar	2025-10-24	2032.75
Gas Chromatography	Isopentenyl-AMP_TMS_11	CC(C)=CCN(C1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O[Si](C)(C)C)[C@@H](O)[C@H]1O)[Si](C)(C)C	standard non polar	2025-10-24	1488.76
Gas Chromatography	Isopentenyl-AMP_TMS_12	CC(C)=CCNC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]1O[Si](C)(C)C	standard non polar	2025-10-24	2064.9
Gas Chromatography	Isopentenyl-AMP_TMS_13	CC(C)=CCN(C1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O)[C@@H](O[Si](C)(C)C)[C@H]1O[Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1593.85
Gas Chromatography	Isopentenyl-AMP_TMS_14	CC(C)=CCNC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O[Si](C)(C)C)O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]1O	standard non polar	2025-10-24	2693.59
Gas Chromatography	Isopentenyl-AMP_TMS_15	CC(C)=CCN(C1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]1O)[Si](C)(C)C	standard non polar	2025-10-24	2939.17
Gas Chromatography	Isopentenyl-AMP_TMS_16	CC(C)=CCNC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O[Si](C)(C)C)O[Si](C)(C)C)[C@@H](O)[C@H]1O[Si](C)(C)C	standard non polar	2025-10-24	2439.99
Gas Chromatography	Isopentenyl-AMP_TMS_17	CC(C)=CCN(C1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O[Si](C)(C)C)[C@@H](O)[C@H]1O[Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1440.67
Gas Chromatography	Isopentenyl-AMP_TMS_18	CC(C)=CCN(C1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O[Si](C)(C)C)O[Si](C)(C)C)[C@@H](O)[C@H]1O)[Si](C)(C)C	standard non polar	2025-10-24	2748.0
Gas Chromatography	Isopentenyl-AMP_TMS_19	CC(C)=CCNC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O[Si](C)(C)C)O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]1O[Si](C)(C)C	standard non polar	2025-10-24	1747.03
Gas Chromatography	Isopentenyl-AMP_TMS_20	CC(C)=CCN(C1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]1O[Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1913.28
Gas Chromatography	Isopentenyl-AMP_TMS_21	CC(C)=CCN(C1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O[Si](C)(C)C)O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]1O)[Si](C)(C)C	standard non polar	2025-10-24	1930.79
Gas Chromatography	Isopentenyl-AMP_TMS_22	CC(C)=CCN(C1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O[Si](C)(C)C)O[Si](C)(C)C)[C@@H](O)[C@H]1O[Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	2126.52
Gas Chromatography	Isopentenyl-AMP_TMS_23	CC(C)=CCN(C1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O[Si](C)(C)C)O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]1O[Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1489.07
Gas Chromatography	Isopentenyl-AMP_TMS_1	CC(C)=CCNC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O)[C@@H](O[Si](C)(C)C)[C@H]1O	standard polar	2025-10-24	2559.79
Gas Chromatography	Isopentenyl-AMP_TMS_2	CC(C)=CCNC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O)[C@@H](O)[C@H]1O[Si](C)(C)C	standard polar	2025-10-24	1714.11
Gas Chromatography	Isopentenyl-AMP_TMS_3	CC(C)=CCNC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O[Si](C)(C)C)[C@@H](O)[C@H]1O	standard polar	2025-10-24	1623.79
Gas Chromatography	Isopentenyl-AMP_TMS_4	CC(C)=CCN(C1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O)[C@@H](O)[C@H]1O)[Si](C)(C)C	standard polar	2025-10-24	2487.91
Gas Chromatography	Isopentenyl-AMP_TMS_5	CC(C)=CCNC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O)[C@@H](O[Si](C)(C)C)[C@H]1O[Si](C)(C)C	standard polar	2025-10-24	1907.13
Gas Chromatography	Isopentenyl-AMP_TMS_6	CC(C)=CCNC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]1O	standard polar	2025-10-24	3241.55
Gas Chromatography	Isopentenyl-AMP_TMS_7	CC(C)=CCN(C1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O)[C@@H](O[Si](C)(C)C)[C@H]1O)[Si](C)(C)C	standard polar	2025-10-24	2222.58
Gas Chromatography	Isopentenyl-AMP_TMS_8	CC(C)=CCNC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O[Si](C)(C)C)[C@@H](O)[C@H]1O[Si](C)(C)C	standard polar	2025-10-24	2359.08
Gas Chromatography	Isopentenyl-AMP_TMS_9	CC(C)=CCN(C1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O)[C@@H](O)[C@H]1O[Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2081.14
Gas Chromatography	Isopentenyl-AMP_TMS_10	CC(C)=CCNC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O[Si](C)(C)C)O[Si](C)(C)C)[C@@H](O)[C@H]1O	standard polar	2025-10-24	1744.2
Gas Chromatography	Isopentenyl-AMP_TMS_11	CC(C)=CCN(C1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O[Si](C)(C)C)[C@@H](O)[C@H]1O)[Si](C)(C)C	standard polar	2025-10-24	2246.69
Gas Chromatography	Isopentenyl-AMP_TMS_12	CC(C)=CCNC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]1O[Si](C)(C)C	standard polar	2025-10-24	2008.32
Gas Chromatography	Isopentenyl-AMP_TMS_13	CC(C)=CCN(C1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O)[C@@H](O[Si](C)(C)C)[C@H]1O[Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	1224.15
Gas Chromatography	Isopentenyl-AMP_TMS_14	CC(C)=CCNC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O[Si](C)(C)C)O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]1O	standard polar	2025-10-24	2577.07
Gas Chromatography	Isopentenyl-AMP_TMS_15	CC(C)=CCN(C1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]1O)[Si](C)(C)C	standard polar	2025-10-24	1885.13
Gas Chromatography	Isopentenyl-AMP_TMS_16	CC(C)=CCNC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O[Si](C)(C)C)O[Si](C)(C)C)[C@@H](O)[C@H]1O[Si](C)(C)C	standard polar	2025-10-24	1546.71
Gas Chromatography	Isopentenyl-AMP_TMS_17	CC(C)=CCN(C1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O[Si](C)(C)C)[C@@H](O)[C@H]1O[Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2612.62
Gas Chromatography	Isopentenyl-AMP_TMS_18	CC(C)=CCN(C1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O[Si](C)(C)C)O[Si](C)(C)C)[C@@H](O)[C@H]1O)[Si](C)(C)C	standard polar	2025-10-24	2391.27
Gas Chromatography	Isopentenyl-AMP_TMS_19	CC(C)=CCNC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O[Si](C)(C)C)O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]1O[Si](C)(C)C	standard polar	2025-10-24	2546.78
Gas Chromatography	Isopentenyl-AMP_TMS_20	CC(C)=CCN(C1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O)O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]1O[Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2147.99
Gas Chromatography	Isopentenyl-AMP_TMS_21	CC(C)=CCN(C1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O[Si](C)(C)C)O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]1O)[Si](C)(C)C	standard polar	2025-10-24	2312.57
Gas Chromatography	Isopentenyl-AMP_TMS_22	CC(C)=CCN(C1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O[Si](C)(C)C)O[Si](C)(C)C)[C@@H](O)[C@H]1O[Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2432.76
Gas Chromatography	Isopentenyl-AMP_TMS_23	CC(C)=CCN(C1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(=O)(O[Si](C)(C)C)O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]1O[Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2107.12

Biological Properties

Cellular Locations

Not Available

Biospecimen Locations

Not Available

Tissue Locations

Not Available

Associated OMIM IDs

114500 (Colorectal cancer)
610247 (Eosinophilic esophagitis)

Human Proteins and Enzymes

Protein ID	Protein Name	Protein Type	Uniprot ID	Species

Human Pathways

Pathways

Name	SMPDB/PathBank

Microbial Pathways

Pathways

Not Available

Metabolic Reactions

Reactions

This table shows at most 20 reactions. For the full list of associated reactions:

See All Associated Reactions

Reaction ID	Precursor	Product	Enzyme	Reaction Type	Data Source	Reference

Health Effects and Bioactivity

Health Outcome/Bioactivity	Metabolite Response/Effect	Evidence Type	Host and Biospecimen	Data Source	Reference

Microbial Sources

Superkingdom/Kingdom	Phylum	Total species	Hosts and Body Sites
Eukaryota/Fungi	Ascomycota	1
Bacteria/Eubacteria	Proteobacteria	12	Human mucosa; Human
Bacteria/Eubacteria	Actinobacteria	3	Human

Exposure Sources

Other Exposures

Source Type	Data Source	Reference

Host Biospecimen and Location

Host and Biospecimen	Status	Mean	Std	Min	Max	Units	Age	Sex	Health Condition	Data Source	Reference

External Links

HMDB ID

HMDB0304433

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FooDB ID

FDB031049

KNApSAcK ID

Not Available

Chemspider ID

90571

KEGG Compound ID

C04713

BioCyc ID

CPD-4205

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

Not Available

PDB ID

Not Available

ChEBI ID

15819

Food Biomarker Ontology

Not Available

CMMC Knowledgebase

Not Available

General References

Bansal P, Morgat A, Axelsen KB, Muthukrishnan V, Coudert E, Aimo L, Hyka-Nouspikel N, Gasteiger E, Kerhornou A, Neto TB, Pozzato M, Blatter MC, Ignatchenko A, Redaschi N, Bridge A: Rhea, the reaction knowledgebase in 2022. Nucleic Acids Res. 2022 Jan 7;50(D1):D693-D700. doi: 10.1093/nar/gkab1016. [PubMed:34755880 ]

Showing metabocard for Isopentenyl-AMP (MMDBc0053381)

MOL for #<Metabolite:0x00007f9ac8a23680>

3D MOL for #<Metabolite:0x00007f9ac8a23680>

3D SDF for #<Metabolite:0x00007f9ac8a23680>

3D-SDF for #<Metabolite:0x00007f9ac8a23680>

PDB for #<Metabolite:0x00007f9ac8a23680>

3D PDB for #<Metabolite:0x00007f9ac8a23680>

SMILES for #<Metabolite:0x00007f9ac8a23680>

INCHI for #<Metabolite:0x00007f9ac8a23680>

Structure for #<Metabolite:0x00007f9ac8a23680>

3D Structure for #<Metabolite:0x00007f9ac8a23680>