MiMeDB: Showing metabocard for 3',3'-cGAMP (MMDBc0054254)

Record Information

Version

2.0

Status

Detected and Quantified

Creation Date

2022-06-05 23:01:42 UTC

Update Date

2025-01-16 10:56:33 UTC

Metabolite ID

MMDBc0054254

Metabolite Identification

Common Name

3',3'-cGAMP

Description

This compound belongs to the family of Purine Ribonucleoside Monophosphates. These are nucleotides consisting of a purine base linked to a ribose to which one monophosphate group is attached.

Structure

MOL SDF PDB SMILES InChI

Synonyms

Not Available

Molecular Formula

C₂₀H₂₄N₁₀O₁₃P₂

Average Mass

674.4113

Monoisotopic Mass

674.099953928

IUPAC Name

Not Available

Traditional Name

Not Available

CAS Registry Number

Not Available

SMILES

Not Available

InChI Identifier

InChI=1S/C20H24N10O13P2/c21-14-8-15(24-3-23-14)29(4-25-8)18-10(31)12-6(40-18)1-38-45(36,37)43-13-7(2-39-44(34,35)42-12)41-19(11(13)32)30-5-26-9-16(30)27-20(22)28-17(9)33/h3-7,10-13,18-19,31-32H,1-2H2,(H,34,35)(H,36,37)(H2,21,23,24)(H3,22,27,28,33)/t6-,7-,10-,11-,12-,13-,18-,19-/m1/s1

InChI Key

RFCBNSCSPXMEBK-INFSMZHSSA-N

Chemical Taxonomy

Functional Ontology

Not Available

Physical Properties

State

Not Available

Predicted Properties

Not Available

Spectra

Not Available

Chromatographic Retention Times and Retention Indices

Retention Times

Chromatography Type	Technique	Column	Deposition Date	Retention Time (s)
Liquid Chromatography	HILIC	Waters Acquity UPLC-BEH Amide column (eluted)	2025-10-24	700.1
Liquid Chromatography	HILIC	Accucore 150 Amide HILIC (eluted)	2025-10-24	548.0
Liquid Chromatography	Reversed-phase	Hypersil Gold 1.9 µm C18 (void)	2025-10-24	125.2
Liquid Chromatography	Reversed-phase	Agilent Zorbax Eclipse Plus C18 (2.1 mm x 150 mm, 3.5 um) (eluted)	2025-10-24	315.1
Liquid Chromatography	Reversed-phase	XBridge C18 3.5u 2.1x50 mm (eluted)	2025-10-24	412.2
Liquid Chromatography	Reversed-phase	Ascentis Express C18 (eluted)	2025-10-24	229.4
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC HSS T3 C18 (eluted)	2025-10-24	842.0
Liquid Chromatography	HILIC	Merck SeQuant ZIC-HILIC (eluted)	2025-10-24	1058.0
Liquid Chromatography	HILIC	Merck SeQuant ZIC-pHILIC (eluted)	2025-10-24	914.3
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC HSS T3 C18 (eluted)	2025-10-24	144.1
Liquid Chromatography	HILIC	Merck SeQuant ZIC-HILIC (eluted)	2025-10-24	485.5
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC HSS T3 C18 (eluted)	2025-10-24	168.2
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC BEH C18 (eluted)	2025-10-24	50.1
Liquid Chromatography	HILIC	Merck SeQuant ZIC-pHILIC column (eluted)	2025-10-24	578.6
Liquid Chromatography	HILIC	Merck SeQuant ZIC-pHILIC column (eluted)	2025-10-24	702.2
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC BEH C18 (eluted)	2025-10-24	75.7
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC BEH C18 (eluted)	2025-10-24	254.8
Liquid Chromatography	Reversed-phase	Kinetex Core-Shell C18 2.6 um, 3.0 x 100 mm, Phenomenex (eluted)	2025-10-24	743.9
Liquid Chromatography	Reversed-phase	Waters Atlantis T3 (2.1 x 150 mm, 5 um) (eluted)	2025-10-24	633.2

Retention Indices

Chromatography Type	Peak Label	SMILES	Stationary Phase	Deposition Date	Retention Index
Gas Chromatography	3',3'-cGAMP_TMS_1	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O)OC[C@H]3O[C@@H](N4C=NC5=C4[NH]C(=N)N=C5O)[C@H](O)[C@@H]3OP(=O)(O)OC[C@H]2O[C@H]1N1C=NC2=C(N)N=CN=C21	standard non polar	2025-10-24	1869.15
Gas Chromatography	3',3'-cGAMP_TMS_2	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O)OC[C@H]3O[C@@H](N4C=NC5=C(N)N=CN=C54)[C@H](O)[C@@H]3OP(=O)(O)OC[C@H]2O[C@H]1N1C=NC2=C1[NH]C(=N)N=C2O	standard non polar	2025-10-24	1859.65
Gas Chromatography	3',3'-cGAMP_TMS_3	C[Si](C)(C)OC1=NC(=N)[NH]C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O	standard non polar	2025-10-24	1760.78
Gas Chromatography	3',3'-cGAMP_TMS_4	C[Si](C)(C)OP1(=O)OC[C@H]2O[C@@H](N3C=NC4=C(N)N=CN=C43)[C@H](O)[C@@H]2OP(=O)(O)OC[C@H]2O[C@@H](N3C=NC4=C3[NH]C(=N)N=C4O)[C@H](O)[C@@H]2O1	standard non polar	2025-10-24	1260.47
Gas Chromatography	3',3'-cGAMP_TMS_5	C[Si](C)(C)OP1(=O)OC[C@H]2O[C@@H](N3C=NC4=C3[NH]C(=N)N=C4O)[C@H](O)[C@@H]2OP(=O)(O)OC[C@H]2O[C@@H](N3C=NC4=C(N)N=CN=C43)[C@H](O)[C@@H]2O1	standard non polar	2025-10-24	861.099
Gas Chromatography	3',3'-cGAMP_TMS_6	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O)[C@@H]3O	standard non polar	2025-10-24	1564.91
Gas Chromatography	3',3'-cGAMP_TMS_7	C[Si](C)(C)N1C(=N)N=C(O)C2=C1N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O)C=N2	standard non polar	2025-10-24	1965.13
Gas Chromatography	3',3'-cGAMP_TMS_8	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O)C=N2	standard non polar	2025-10-24	1769.69
Gas Chromatography	3',3'-cGAMP_TMS_9	C[Si](C)(C)OC1=NC(=N)[NH]C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O[Si](C)(C)C	standard non polar	2025-10-24	2743.28
Gas Chromatography	3',3'-cGAMP_TMS_10	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O)OC[C@H]3O[C@@H](N4C=NC5=C4[NH]C(=N)N=C5O)[C@H](O[Si](C)(C)C)[C@@H]3OP(=O)(O)OC[C@H]2O[C@H]1N1C=NC2=C(N)N=CN=C21	standard non polar	2025-10-24	1140.7
Gas Chromatography	3',3'-cGAMP_TMS_11	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O[Si](C)(C)C)OC[C@H]3O[C@@H](N4C=NC5=C4[NH]C(=N)N=C5O)[C@H](O)[C@@H]3OP(=O)(O)OC[C@H]2O[C@H]1N1C=NC2=C(N)N=CN=C21	standard non polar	2025-10-24	1828.15
Gas Chromatography	3',3'-cGAMP_TMS_12	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O)OC[C@H]3O[C@@H](N4C=NC5=C4[NH]C(=N)N=C5O)[C@H](O)[C@@H]3OP(=O)(O[Si](C)(C)C)OC[C@H]2O[C@H]1N1C=NC2=C(N)N=CN=C21	standard non polar	2025-10-24	1737.67
Gas Chromatography	3',3'-cGAMP_TMS_13	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O)[C@@H]3O	standard non polar	2025-10-24	3180.59
Gas Chromatography	3',3'-cGAMP_TMS_14	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O[Si](C)(C)C)C=N2	standard non polar	2025-10-24	766.389
Gas Chromatography	3',3'-cGAMP_TMS_15	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O)OC[C@H]3O[C@@H](N4C=NC5=C4N([Si](C)(C)C)C(=N)N=C5O)[C@H](O)[C@@H]3OP(=O)(O)OC[C@H]2O[C@H]1N1C=NC2=C(N)N=CN=C21	standard non polar	2025-10-24	1691.21
Gas Chromatography	3',3'-cGAMP_TMS_16	C[Si](C)(C)OC1=NC(=N)[NH]C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O	standard non polar	2025-10-24	1665.72
Gas Chromatography	3',3'-cGAMP_TMS_17	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O[Si](C)(C)C)OC[C@H]3O[C@@H](N4C=NC5=C(N)N=CN=C54)[C@H](O)[C@@H]3OP(=O)(O)OC[C@H]2O[C@H]1N1C=NC2=C1[NH]C(=N)N=C2O	standard non polar	2025-10-24	3764.83
Gas Chromatography	3',3'-cGAMP_TMS_18	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O)OC[C@H]3O[C@@H](N4C=NC5=C(N)N=CN=C54)[C@H](O)[C@@H]3OP(=O)(O[Si](C)(C)C)OC[C@H]2O[C@H]1N1C=NC2=C1[NH]C(=N)N=C2O	standard non polar	2025-10-24	2082.68
Gas Chromatography	3',3'-cGAMP_TMS_19	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O)[C@@H]3O[Si](C)(C)C	standard non polar	2025-10-24	1784.28
Gas Chromatography	3',3'-cGAMP_TMS_20	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O)C=N2	standard non polar	2025-10-24	1643.91
Gas Chromatography	3',3'-cGAMP_TMS_21	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O)OC[C@H]3O[C@@H](N4C=NC5=C(N)N=CN=C54)[C@H](O)[C@@H]3OP(=O)(O)OC[C@H]2O[C@H]1N1C=NC2=C1N([Si](C)(C)C)C(=N)N=C2O	standard non polar	2025-10-24	2398.82
Gas Chromatography	3',3'-cGAMP_TMS_22	C[Si](C)(C)OC1=NC(=N)[NH]C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O[Si](C)(C)C)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O	standard non polar	2025-10-24	2350.43
Gas Chromatography	3',3'-cGAMP_TMS_23	C[Si](C)(C)OC1=NC(=N)[NH]C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O	standard non polar	2025-10-24	2062.69
Gas Chromatography	3',3'-cGAMP_TMS_24	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O[Si](C)(C)C)[C@@H]3O	standard non polar	2025-10-24	2119.67
Gas Chromatography	3',3'-cGAMP_TMS_25	C[Si](C)(C)N=C1N=C(O[Si](C)(C)C)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O)C=N2	standard non polar	2025-10-24	726.052
Gas Chromatography	3',3'-cGAMP_TMS_26	C[Si](C)(C)OC1=NC(=N)N([Si](C)(C)C)C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O	standard non polar	2025-10-24	1734.18
Gas Chromatography	3',3'-cGAMP_TMS_27	C[Si](C)(C)OP1(=O)OC[C@H]2O[C@@H](N3C=NC4=C3[NH]C(=N)N=C4O)[C@H](O)[C@@H]2OP(=O)(O[Si](C)(C)C)OC[C@H]2O[C@@H](N3C=NC4=C(N)N=CN=C43)[C@H](O)[C@@H]2O1	standard non polar	2025-10-24	1505.85
Gas Chromatography	3',3'-cGAMP_TMS_28	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O[Si](C)(C)C)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O)[C@@H]3O	standard non polar	2025-10-24	2401.1
Gas Chromatography	3',3'-cGAMP_TMS_29	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O)C=N2	standard non polar	2025-10-24	2161.2
Gas Chromatography	3',3'-cGAMP_TMS_30	C[Si](C)(C)OP1(=O)OC[C@H]2O[C@@H](N3C=NC4=C(N)N=CN=C43)[C@H](O)[C@@H]2OP(=O)(O)OC[C@H]2O[C@@H](N3C=NC4=C3N([Si](C)(C)C)C(=N)N=C4O)[C@H](O)[C@@H]2O1	standard non polar	2025-10-24	2316.17
Gas Chromatography	3',3'-cGAMP_TMS_31	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O)[C@@H]3O	standard non polar	2025-10-24	1653.13
Gas Chromatography	3',3'-cGAMP_TMS_32	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O[Si](C)(C)C)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O)C=N2	standard non polar	2025-10-24	2475.81
Gas Chromatography	3',3'-cGAMP_TMS_33	C[Si](C)(C)OP1(=O)OC[C@H]2O[C@@H](N3C=NC4=C3N([Si](C)(C)C)C(=N)N=C4O)[C@H](O)[C@@H]2OP(=O)(O)OC[C@H]2O[C@@H](N3C=NC4=C(N)N=CN=C43)[C@H](O)[C@@H]2O1	standard non polar	2025-10-24	2305.57
Gas Chromatography	3',3'-cGAMP_TMS_34	C[Si](C)(C)N(C1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O)[C@@H]3O)[Si](C)(C)C	standard non polar	2025-10-24	1700.73
Gas Chromatography	3',3'-cGAMP_TMS_35	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N[Si](C)(C)C)N=CN=C31)[C@@H]4O)C=N2	standard non polar	2025-10-24	2603.58
Gas Chromatography	3',3'-cGAMP_TMS_36	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1N([Si](C)(C)C)C(=N)N=C2O)[C@@H]3O	standard non polar	2025-10-24	-661.418
Gas Chromatography	3',3'-cGAMP_TMS_37	C[Si](C)(C)N=C1N=C(O)C2=C(N([C@@H]3O[C@@H]4COP(=O)(O)O[C@@H]5[C@@H](COP(=O)(O)O[C@H]4[C@H]3O)O[C@@H](N3C=NC4=C(N)N=CN=C43)[C@@H]5O)C=N2)N1[Si](C)(C)C	standard non polar	2025-10-24	1997.11
Gas Chromatography	3',3'-cGAMP_TMS_38	C[Si](C)(C)OC1=NC(=N)[NH]C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O[Si](C)(C)C	standard non polar	2025-10-24	1266.54
Gas Chromatography	3',3'-cGAMP_TMS_39	C[Si](C)(C)OC1=NC(=N)[NH]C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O[Si](C)(C)C)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O[Si](C)(C)C	standard non polar	2025-10-24	3413.18
Gas Chromatography	3',3'-cGAMP_TMS_40	C[Si](C)(C)OC1=NC(=N)[NH]C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O[Si](C)(C)C	standard non polar	2025-10-24	2282.05
Gas Chromatography	3',3'-cGAMP_TMS_41	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O[Si](C)(C)C)[C@@H]3O	standard non polar	2025-10-24	1286.69
Gas Chromatography	3',3'-cGAMP_TMS_42	C[Si](C)(C)N=C1N=C(O[Si](C)(C)C)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O[Si](C)(C)C)C=N2	standard non polar	2025-10-24	2120.24
Gas Chromatography	3',3'-cGAMP_TMS_43	C[Si](C)(C)OC1=NC(=N)N([Si](C)(C)C)C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O[Si](C)(C)C	standard non polar	2025-10-24	1533.68
Gas Chromatography	3',3'-cGAMP_TMS_44	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O[Si](C)(C)C)OC[C@H]3O[C@@H](N4C=NC5=C4[NH]C(=N)N=C5O)[C@H](O[Si](C)(C)C)[C@@H]3OP(=O)(O)OC[C@H]2O[C@H]1N1C=NC2=C(N)N=CN=C21	standard non polar	2025-10-24	3725.02
Gas Chromatography	3',3'-cGAMP_TMS_45	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O)OC[C@H]3O[C@@H](N4C=NC5=C4[NH]C(=N)N=C5O)[C@H](O[Si](C)(C)C)[C@@H]3OP(=O)(O[Si](C)(C)C)OC[C@H]2O[C@H]1N1C=NC2=C(N)N=CN=C21	standard non polar	2025-10-24	1834.04
Gas Chromatography	3',3'-cGAMP_TMS_46	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O)[C@@H]3O[Si](C)(C)C	standard non polar	2025-10-24	2627.82
Gas Chromatography	3',3'-cGAMP_TMS_47	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O[Si](C)(C)C)C=N2	standard non polar	2025-10-24	883.339
Gas Chromatography	3',3'-cGAMP_TMS_48	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O)OC[C@H]3O[C@@H](N4C=NC5=C4N([Si](C)(C)C)C(=N)N=C5O)[C@H](O[Si](C)(C)C)[C@@H]3OP(=O)(O)OC[C@H]2O[C@H]1N1C=NC2=C(N)N=CN=C21	standard non polar	2025-10-24	1220.7
Gas Chromatography	3',3'-cGAMP_TMS_49	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O[Si](C)(C)C)OC[C@H]3O[C@@H](N4C=NC5=C4[NH]C(=N)N=C5O)[C@H](O)[C@@H]3OP(=O)(O[Si](C)(C)C)OC[C@H]2O[C@H]1N1C=NC2=C(N)N=CN=C21	standard non polar	2025-10-24	3288.93
Gas Chromatography	3',3'-cGAMP_TMS_50	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]2[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O)[C@@H]3O	standard non polar	2025-10-24	1120.62
Gas Chromatography	3',3'-cGAMP_TMS_51	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O[Si](C)(C)C)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O[Si](C)(C)C)C=N2	standard non polar	2025-10-24	1948.9
Gas Chromatography	3',3'-cGAMP_TMS_52	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O[Si](C)(C)C)OC[C@H]3O[C@@H](N4C=NC5=C4N([Si](C)(C)C)C(=N)N=C5O)[C@H](O)[C@@H]3OP(=O)(O)OC[C@H]2O[C@H]1N1C=NC2=C(N)N=CN=C21	standard non polar	2025-10-24	2108.79
Gas Chromatography	3',3'-cGAMP_TMS_53	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O[Si](C)(C)C)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O)[C@@H]3O	standard non polar	2025-10-24	1916.75
Gas Chromatography	3',3'-cGAMP_TMS_54	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O[Si](C)(C)C)C=N2	standard non polar	2025-10-24	1224.42
Gas Chromatography	3',3'-cGAMP_TMS_55	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O)OC[C@H]3O[C@@H](N4C=NC5=C4N([Si](C)(C)C)C(=N)N=C5O)[C@H](O)[C@@H]3OP(=O)(O[Si](C)(C)C)OC[C@H]2O[C@H]1N1C=NC2=C(N)N=CN=C21	standard non polar	2025-10-24	2513.11
Gas Chromatography	3',3'-cGAMP_TMS_56	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O)OC[C@H]3O[C@@H](N4C=NC5=C4[NH]C(=N)N=C5O)[C@H](O)[C@@H]3OP(=O)(O)OC[C@H]2O[C@H]1N1C=NC2=C(N([Si](C)(C)C)[Si](C)(C)C)N=CN=C21	standard non polar	2025-10-24	2182.72
Gas Chromatography	3',3'-cGAMP_TMS_57	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N[Si](C)(C)C)N=CN=C31)[C@@H]4O[Si](C)(C)C)C=N2	standard non polar	2025-10-24	2086.38
Gas Chromatography	3',3'-cGAMP_TMS_58	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC2=C1N([Si](C)(C)C)C(=N)N=C2O)[C@@H]3O	standard non polar	2025-10-24	2294.71
Gas Chromatography	3',3'-cGAMP_TMS_59	C[Si](C)(C)N=C1N=C(O)C2=C(N([C@@H]3O[C@@H]4COP(=O)(O)O[C@@H]5[C@@H](COP(=O)(O)O[C@H]4[C@H]3O)O[C@@H](N3C=NC4=C(N)N=CN=C43)[C@@H]5O[Si](C)(C)C)C=N2)N1[Si](C)(C)C	standard non polar	2025-10-24	283.1
Gas Chromatography	3',3'-cGAMP_TMS_60	C[Si](C)(C)OC1=NC(=N)[NH]C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O[Si](C)(C)C)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O	standard non polar	2025-10-24	4015.19
Gas Chromatography	3',3'-cGAMP_TMS_61	C[Si](C)(C)OC1=NC(=N)[NH]C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]2[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O	standard non polar	2025-10-24	564.316
Gas Chromatography	3',3'-cGAMP_TMS_62	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O[Si](C)(C)C)[C@@H]3O[Si](C)(C)C	standard non polar	2025-10-24	2523.1
Gas Chromatography	3',3'-cGAMP_TMS_63	C[Si](C)(C)N=C1N=C(O[Si](C)(C)C)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O)C=N2	standard non polar	2025-10-24	1081.98
Gas Chromatography	3',3'-cGAMP_TMS_64	C[Si](C)(C)OC1=NC(=N)N([Si](C)(C)C)C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O	standard non polar	2025-10-24	1043.83
Gas Chromatography	3',3'-cGAMP_TMS_65	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O[Si](C)(C)C)OC[C@H]3O[C@@H](N4C=NC5=C(N)N=CN=C54)[C@H](O)[C@@H]3OP(=O)(O[Si](C)(C)C)OC[C@H]2O[C@H]1N1C=NC2=C1[NH]C(=N)N=C2O	standard non polar	2025-10-24	3048.28
Gas Chromatography	3',3'-cGAMP_TMS_66	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O[Si](C)(C)C)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O)[C@@H]3O[Si](C)(C)C	standard non polar	2025-10-24	3921.76
Gas Chromatography	3',3'-cGAMP_TMS_67	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]3[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O)C=N2	standard non polar	2025-10-24	1735.38
Gas Chromatography	3',3'-cGAMP_TMS_68	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O[Si](C)(C)C)OC[C@H]3O[C@@H](N4C=NC5=C(N)N=CN=C54)[C@H](O)[C@@H]3OP(=O)(O)OC[C@H]2O[C@H]1N1C=NC2=C1N([Si](C)(C)C)C(=N)N=C2O	standard non polar	2025-10-24	1749.63
Gas Chromatography	3',3'-cGAMP_TMS_69	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O)[C@@H]3O[Si](C)(C)C	standard non polar	2025-10-24	3407.34
Gas Chromatography	3',3'-cGAMP_TMS_70	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O[Si](C)(C)C)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O)C=N2	standard non polar	2025-10-24	1871.48
Gas Chromatography	3',3'-cGAMP_TMS_71	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O)OC[C@H]3O[C@@H](N4C=NC5=C(N)N=CN=C54)[C@H](O)[C@@H]3OP(=O)(O[Si](C)(C)C)OC[C@H]2O[C@H]1N1C=NC2=C1N([Si](C)(C)C)C(=N)N=C2O	standard non polar	2025-10-24	2734.77
Gas Chromatography	3',3'-cGAMP_TMS_72	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O)OC[C@H]3O[C@@H](N4C=NC5=C(N([Si](C)(C)C)[Si](C)(C)C)N=CN=C54)[C@H](O)[C@@H]3OP(=O)(O)OC[C@H]2O[C@H]1N1C=NC2=C1[NH]C(=N)N=C2O	standard non polar	2025-10-24	1647.39
Gas Chromatography	3',3'-cGAMP_TMS_73	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC3=C(N[Si](C)(C)C)N=CN=C31)[C@@H]4O)C=N2	standard non polar	2025-10-24	2864.89
Gas Chromatography	3',3'-cGAMP_TMS_74	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1N([Si](C)(C)C)C(=N)N=C2O)[C@@H]3O[Si](C)(C)C	standard non polar	2025-10-24	2123.13
Gas Chromatography	3',3'-cGAMP_TMS_75	C[Si](C)(C)N=C1N=C(O)C2=C(N([C@@H]3O[C@@H]4COP(=O)(O)O[C@@H]5[C@@H](COP(=O)(O)O[C@H]4[C@H]3O[Si](C)(C)C)O[C@@H](N3C=NC4=C(N)N=CN=C43)[C@@H]5O)C=N2)N1[Si](C)(C)C	standard non polar	2025-10-24	2848.74
Gas Chromatography	3',3'-cGAMP_TMS_76	C[Si](C)(C)OC1=NC(=N)[NH]C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O[Si](C)(C)C)O[C@@H]3[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O	standard non polar	2025-10-24	1734.49
Gas Chromatography	3',3'-cGAMP_TMS_77	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O[Si](C)(C)C)[C@@H]3O	standard non polar	2025-10-24	306.361
Gas Chromatography	3',3'-cGAMP_TMS_78	C[Si](C)(C)N=C1N=C(O[Si](C)(C)C)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O[Si](C)(C)C)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O)C=N2	standard non polar	2025-10-24	1766.18
Gas Chromatography	3',3'-cGAMP_TMS_79	C[Si](C)(C)OC1=NC(=N)N([Si](C)(C)C)C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O[Si](C)(C)C)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O	standard non polar	2025-10-24	1061.91
Gas Chromatography	3',3'-cGAMP_TMS_80	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O[Si](C)(C)C)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O[Si](C)(C)C)[C@@H]3O	standard non polar	2025-10-24	2074.73
Gas Chromatography	3',3'-cGAMP_TMS_81	C[Si](C)(C)N=C1N=C(O[Si](C)(C)C)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O)C=N2	standard non polar	2025-10-24	3478.16
Gas Chromatography	3',3'-cGAMP_TMS_82	C[Si](C)(C)OC1=NC(=N)N([Si](C)(C)C)C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O	standard non polar	2025-10-24	694.858
Gas Chromatography	3',3'-cGAMP_TMS_83	C[Si](C)(C)OC1=NC(=N)[NH]C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C(N([Si](C)(C)C)[Si](C)(C)C)N=CN=C21)[C@@H]3O	standard non polar	2025-10-24	2308.75
Gas Chromatography	3',3'-cGAMP_TMS_84	C[Si](C)(C)N=C1N=C(O[Si](C)(C)C)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N[Si](C)(C)C)N=CN=C31)[C@@H]4O)C=N2	standard non polar	2025-10-24	2297.59
Gas Chromatography	3',3'-cGAMP_TMS_85	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1N([Si](C)(C)C)C(=N)N=C2O[Si](C)(C)C)[C@@H]3O	standard non polar	2025-10-24	1555.25
Gas Chromatography	3',3'-cGAMP_TMS_86	C[Si](C)(C)N=C1N=C(O[Si](C)(C)C)C2=C(N([C@@H]3O[C@@H]4COP(=O)(O)O[C@@H]5[C@@H](COP(=O)(O)O[C@H]4[C@H]3O)O[C@@H](N3C=NC4=C(N)N=CN=C43)[C@@H]5O)C=N2)N1[Si](C)(C)C	standard non polar	2025-10-24	429.226
Gas Chromatography	3',3'-cGAMP_TMS_87	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O[Si](C)(C)C)O[C@@H]3[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O)[C@@H]3O	standard non polar	2025-10-24	2822.51
Gas Chromatography	3',3'-cGAMP_TMS_88	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O[Si](C)(C)C)O[C@@H]4[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O)C=N2	standard non polar	2025-10-24	1625.21
Gas Chromatography	3',3'-cGAMP_TMS_89	C[Si](C)(C)OP1(=O)OC[C@H]2O[C@@H](N3C=NC4=C3N([Si](C)(C)C)C(=N)N=C4O)[C@H](O)[C@@H]2OP(=O)(O[Si](C)(C)C)OC[C@H]2O[C@@H](N3C=NC4=C(N)N=CN=C43)[C@H](O)[C@@H]2O1	standard non polar	2025-10-24	1050.17
Gas Chromatography	3',3'-cGAMP_TMS_90	C[Si](C)(C)OP1(=O)OC[C@H]2O[C@@H](N3C=NC4=C(N([Si](C)(C)C)[Si](C)(C)C)N=CN=C43)[C@H](O)[C@@H]2OP(=O)(O)OC[C@H]2O[C@@H](N3C=NC4=C3[NH]C(=N)N=C4O)[C@H](O)[C@@H]2O1	standard non polar	2025-10-24	2218.95
Gas Chromatography	3',3'-cGAMP_TMS_91	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N[Si](C)(C)C)N=CN=C31)[C@@H]4O)C=N2	standard non polar	2025-10-24	3388.92
Gas Chromatography	3',3'-cGAMP_TMS_92	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O[Si](C)(C)C)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1N([Si](C)(C)C)C(=N)N=C2O)[C@@H]3O	standard non polar	2025-10-24	1195.6
Gas Chromatography	3',3'-cGAMP_TMS_93	C[Si](C)(C)N=C1N=C(O)C2=C(N([C@@H]3O[C@@H]4COP(=O)(O)O[C@@H]5[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]4[C@H]3O)O[C@@H](N3C=NC4=C(N)N=CN=C43)[C@@H]5O)C=N2)N1[Si](C)(C)C	standard non polar	2025-10-24	1326.69
Gas Chromatography	3',3'-cGAMP_TMS_94	C[Si](C)(C)OP1(=O)OC[C@H]2O[C@@H](N3C=NC4=C3[NH]C(=N)N=C4O)[C@H](O)[C@@H]2OP(=O)(O)OC[C@H]2O[C@@H](N3C=NC4=C(N([Si](C)(C)C)[Si](C)(C)C)N=CN=C43)[C@H](O)[C@@H]2O1	standard non polar	2025-10-24	685.843
Gas Chromatography	3',3'-cGAMP_TMS_95	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O[Si](C)(C)C)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N[Si](C)(C)C)N=CN=C31)[C@@H]4O)C=N2	standard non polar	2025-10-24	287.631
Gas Chromatography	3',3'-cGAMP_TMS_96	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1N([Si](C)(C)C)C(=N)N=C2O)[C@@H]3O	standard non polar	2025-10-24	1853.82
Gas Chromatography	3',3'-cGAMP_TMS_97	C[Si](C)(C)N=C1N=C(O)C2=C(N([C@@H]3O[C@@H]4COP(=O)(O[Si](C)(C)C)O[C@@H]5[C@@H](COP(=O)(O)O[C@H]4[C@H]3O)O[C@@H](N3C=NC4=C(N)N=CN=C43)[C@@H]5O)C=N2)N1[Si](C)(C)C	standard non polar	2025-10-24	2718.1
Gas Chromatography	3',3'-cGAMP_TMS_98	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N([Si](C)(C)C)[Si](C)(C)C)N=CN=C31)[C@@H]4O)C=N2	standard non polar	2025-10-24	758.385
Gas Chromatography	3',3'-cGAMP_TMS_99	C[Si](C)(C)N(C1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1N([Si](C)(C)C)C(=N)N=C2O)[C@@H]3O)[Si](C)(C)C	standard non polar	2025-10-24	1351.38
Gas Chromatography	3',3'-cGAMP_TMS_100	C[Si](C)(C)N=C1N=C(O)C2=C(N([C@@H]3O[C@@H]4COP(=O)(O)O[C@@H]5[C@@H](COP(=O)(O)O[C@H]4[C@H]3O)O[C@@H](N3C=NC4=C(N[Si](C)(C)C)N=CN=C43)[C@@H]5O)C=N2)N1[Si](C)(C)C	standard non polar	2025-10-24	1529.3
Gas Chromatography	3',3'-cGAMP_TMS_1	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O)OC[C@H]3O[C@@H](N4C=NC5=C4[NH]C(=N)N=C5O)[C@H](O)[C@@H]3OP(=O)(O)OC[C@H]2O[C@H]1N1C=NC2=C(N)N=CN=C21	standard polar	2025-10-24	2763.51
Gas Chromatography	3',3'-cGAMP_TMS_2	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O)OC[C@H]3O[C@@H](N4C=NC5=C(N)N=CN=C54)[C@H](O)[C@@H]3OP(=O)(O)OC[C@H]2O[C@H]1N1C=NC2=C1[NH]C(=N)N=C2O	standard polar	2025-10-24	2123.19
Gas Chromatography	3',3'-cGAMP_TMS_3	C[Si](C)(C)OC1=NC(=N)[NH]C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O	standard polar	2025-10-24	1081.04
Gas Chromatography	3',3'-cGAMP_TMS_4	C[Si](C)(C)OP1(=O)OC[C@H]2O[C@@H](N3C=NC4=C(N)N=CN=C43)[C@H](O)[C@@H]2OP(=O)(O)OC[C@H]2O[C@@H](N3C=NC4=C3[NH]C(=N)N=C4O)[C@H](O)[C@@H]2O1	standard polar	2025-10-24	2735.32
Gas Chromatography	3',3'-cGAMP_TMS_5	C[Si](C)(C)OP1(=O)OC[C@H]2O[C@@H](N3C=NC4=C3[NH]C(=N)N=C4O)[C@H](O)[C@@H]2OP(=O)(O)OC[C@H]2O[C@@H](N3C=NC4=C(N)N=CN=C43)[C@H](O)[C@@H]2O1	standard polar	2025-10-24	2530.45
Gas Chromatography	3',3'-cGAMP_TMS_6	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O)[C@@H]3O	standard polar	2025-10-24	589.927
Gas Chromatography	3',3'-cGAMP_TMS_7	C[Si](C)(C)N1C(=N)N=C(O)C2=C1N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O)C=N2	standard polar	2025-10-24	1311.92
Gas Chromatography	3',3'-cGAMP_TMS_8	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O)C=N2	standard polar	2025-10-24	2594.24
Gas Chromatography	3',3'-cGAMP_TMS_9	C[Si](C)(C)OC1=NC(=N)[NH]C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O[Si](C)(C)C	standard polar	2025-10-24	2054.51
Gas Chromatography	3',3'-cGAMP_TMS_10	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O)OC[C@H]3O[C@@H](N4C=NC5=C4[NH]C(=N)N=C5O)[C@H](O[Si](C)(C)C)[C@@H]3OP(=O)(O)OC[C@H]2O[C@H]1N1C=NC2=C(N)N=CN=C21	standard polar	2025-10-24	1288.26
Gas Chromatography	3',3'-cGAMP_TMS_11	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O[Si](C)(C)C)OC[C@H]3O[C@@H](N4C=NC5=C4[NH]C(=N)N=C5O)[C@H](O)[C@@H]3OP(=O)(O)OC[C@H]2O[C@H]1N1C=NC2=C(N)N=CN=C21	standard polar	2025-10-24	3042.77
Gas Chromatography	3',3'-cGAMP_TMS_12	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O)OC[C@H]3O[C@@H](N4C=NC5=C4[NH]C(=N)N=C5O)[C@H](O)[C@@H]3OP(=O)(O[Si](C)(C)C)OC[C@H]2O[C@H]1N1C=NC2=C(N)N=CN=C21	standard polar	2025-10-24	3313.19
Gas Chromatography	3',3'-cGAMP_TMS_13	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O)[C@@H]3O	standard polar	2025-10-24	-25.6004
Gas Chromatography	3',3'-cGAMP_TMS_14	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O[Si](C)(C)C)C=N2	standard polar	2025-10-24	1261.98
Gas Chromatography	3',3'-cGAMP_TMS_15	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O)OC[C@H]3O[C@@H](N4C=NC5=C4N([Si](C)(C)C)C(=N)N=C5O)[C@H](O)[C@@H]3OP(=O)(O)OC[C@H]2O[C@H]1N1C=NC2=C(N)N=CN=C21	standard polar	2025-10-24	3363.9
Gas Chromatography	3',3'-cGAMP_TMS_16	C[Si](C)(C)OC1=NC(=N)[NH]C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O	standard polar	2025-10-24	2426.2
Gas Chromatography	3',3'-cGAMP_TMS_17	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O[Si](C)(C)C)OC[C@H]3O[C@@H](N4C=NC5=C(N)N=CN=C54)[C@H](O)[C@@H]3OP(=O)(O)OC[C@H]2O[C@H]1N1C=NC2=C1[NH]C(=N)N=C2O	standard polar	2025-10-24	784.227
Gas Chromatography	3',3'-cGAMP_TMS_18	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O)OC[C@H]3O[C@@H](N4C=NC5=C(N)N=CN=C54)[C@H](O)[C@@H]3OP(=O)(O[Si](C)(C)C)OC[C@H]2O[C@H]1N1C=NC2=C1[NH]C(=N)N=C2O	standard polar	2025-10-24	2614.82
Gas Chromatography	3',3'-cGAMP_TMS_19	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O)[C@@H]3O[Si](C)(C)C	standard polar	2025-10-24	2916.2
Gas Chromatography	3',3'-cGAMP_TMS_20	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O)C=N2	standard polar	2025-10-24	2466.72
Gas Chromatography	3',3'-cGAMP_TMS_21	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O)OC[C@H]3O[C@@H](N4C=NC5=C(N)N=CN=C54)[C@H](O)[C@@H]3OP(=O)(O)OC[C@H]2O[C@H]1N1C=NC2=C1N([Si](C)(C)C)C(=N)N=C2O	standard polar	2025-10-24	2842.04
Gas Chromatography	3',3'-cGAMP_TMS_22	C[Si](C)(C)OC1=NC(=N)[NH]C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O[Si](C)(C)C)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O	standard polar	2025-10-24	2164.21
Gas Chromatography	3',3'-cGAMP_TMS_23	C[Si](C)(C)OC1=NC(=N)[NH]C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O	standard polar	2025-10-24	1869.41
Gas Chromatography	3',3'-cGAMP_TMS_24	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O[Si](C)(C)C)[C@@H]3O	standard polar	2025-10-24	2641.14
Gas Chromatography	3',3'-cGAMP_TMS_25	C[Si](C)(C)N=C1N=C(O[Si](C)(C)C)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O)C=N2	standard polar	2025-10-24	1536.0
Gas Chromatography	3',3'-cGAMP_TMS_26	C[Si](C)(C)OC1=NC(=N)N([Si](C)(C)C)C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O	standard polar	2025-10-24	3194.83
Gas Chromatography	3',3'-cGAMP_TMS_27	C[Si](C)(C)OP1(=O)OC[C@H]2O[C@@H](N3C=NC4=C3[NH]C(=N)N=C4O)[C@H](O)[C@@H]2OP(=O)(O[Si](C)(C)C)OC[C@H]2O[C@@H](N3C=NC4=C(N)N=CN=C43)[C@H](O)[C@@H]2O1	standard polar	2025-10-24	2535.48
Gas Chromatography	3',3'-cGAMP_TMS_28	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O[Si](C)(C)C)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O)[C@@H]3O	standard polar	2025-10-24	967.806
Gas Chromatography	3',3'-cGAMP_TMS_29	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O)C=N2	standard polar	2025-10-24	1362.02
Gas Chromatography	3',3'-cGAMP_TMS_30	C[Si](C)(C)OP1(=O)OC[C@H]2O[C@@H](N3C=NC4=C(N)N=CN=C43)[C@H](O)[C@@H]2OP(=O)(O)OC[C@H]2O[C@@H](N3C=NC4=C3N([Si](C)(C)C)C(=N)N=C4O)[C@H](O)[C@@H]2O1	standard polar	2025-10-24	2762.17
Gas Chromatography	3',3'-cGAMP_TMS_31	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O)[C@@H]3O	standard polar	2025-10-24	1694.45
Gas Chromatography	3',3'-cGAMP_TMS_32	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O[Si](C)(C)C)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O)C=N2	standard polar	2025-10-24	2308.23
Gas Chromatography	3',3'-cGAMP_TMS_33	C[Si](C)(C)OP1(=O)OC[C@H]2O[C@@H](N3C=NC4=C3N([Si](C)(C)C)C(=N)N=C4O)[C@H](O)[C@@H]2OP(=O)(O)OC[C@H]2O[C@@H](N3C=NC4=C(N)N=CN=C43)[C@H](O)[C@@H]2O1	standard polar	2025-10-24	2026.16
Gas Chromatography	3',3'-cGAMP_TMS_34	C[Si](C)(C)N(C1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O)[C@@H]3O)[Si](C)(C)C	standard polar	2025-10-24	2057.71
Gas Chromatography	3',3'-cGAMP_TMS_35	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N[Si](C)(C)C)N=CN=C31)[C@@H]4O)C=N2	standard polar	2025-10-24	1426.53
Gas Chromatography	3',3'-cGAMP_TMS_36	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1N([Si](C)(C)C)C(=N)N=C2O)[C@@H]3O	standard polar	2025-10-24	1206.23
Gas Chromatography	3',3'-cGAMP_TMS_37	C[Si](C)(C)N=C1N=C(O)C2=C(N([C@@H]3O[C@@H]4COP(=O)(O)O[C@@H]5[C@@H](COP(=O)(O)O[C@H]4[C@H]3O)O[C@@H](N3C=NC4=C(N)N=CN=C43)[C@@H]5O)C=N2)N1[Si](C)(C)C	standard polar	2025-10-24	1419.11
Gas Chromatography	3',3'-cGAMP_TMS_38	C[Si](C)(C)OC1=NC(=N)[NH]C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O[Si](C)(C)C	standard polar	2025-10-24	3546.11
Gas Chromatography	3',3'-cGAMP_TMS_39	C[Si](C)(C)OC1=NC(=N)[NH]C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O[Si](C)(C)C)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O[Si](C)(C)C	standard polar	2025-10-24	887.211
Gas Chromatography	3',3'-cGAMP_TMS_40	C[Si](C)(C)OC1=NC(=N)[NH]C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O[Si](C)(C)C	standard polar	2025-10-24	2075.83
Gas Chromatography	3',3'-cGAMP_TMS_41	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O[Si](C)(C)C)[C@@H]3O	standard polar	2025-10-24	1607.08
Gas Chromatography	3',3'-cGAMP_TMS_42	C[Si](C)(C)N=C1N=C(O[Si](C)(C)C)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O[Si](C)(C)C)C=N2	standard polar	2025-10-24	4066.55
Gas Chromatography	3',3'-cGAMP_TMS_43	C[Si](C)(C)OC1=NC(=N)N([Si](C)(C)C)C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O[Si](C)(C)C	standard polar	2025-10-24	1864.98
Gas Chromatography	3',3'-cGAMP_TMS_44	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O[Si](C)(C)C)OC[C@H]3O[C@@H](N4C=NC5=C4[NH]C(=N)N=C5O)[C@H](O[Si](C)(C)C)[C@@H]3OP(=O)(O)OC[C@H]2O[C@H]1N1C=NC2=C(N)N=CN=C21	standard polar	2025-10-24	1463.34
Gas Chromatography	3',3'-cGAMP_TMS_45	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O)OC[C@H]3O[C@@H](N4C=NC5=C4[NH]C(=N)N=C5O)[C@H](O[Si](C)(C)C)[C@@H]3OP(=O)(O[Si](C)(C)C)OC[C@H]2O[C@H]1N1C=NC2=C(N)N=CN=C21	standard polar	2025-10-24	2497.13
Gas Chromatography	3',3'-cGAMP_TMS_46	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O)[C@@H]3O[Si](C)(C)C	standard polar	2025-10-24	1613.24
Gas Chromatography	3',3'-cGAMP_TMS_47	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O[Si](C)(C)C)C=N2	standard polar	2025-10-24	2092.23
Gas Chromatography	3',3'-cGAMP_TMS_48	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O)OC[C@H]3O[C@@H](N4C=NC5=C4N([Si](C)(C)C)C(=N)N=C5O)[C@H](O[Si](C)(C)C)[C@@H]3OP(=O)(O)OC[C@H]2O[C@H]1N1C=NC2=C(N)N=CN=C21	standard polar	2025-10-24	1498.17
Gas Chromatography	3',3'-cGAMP_TMS_49	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O[Si](C)(C)C)OC[C@H]3O[C@@H](N4C=NC5=C4[NH]C(=N)N=C5O)[C@H](O)[C@@H]3OP(=O)(O[Si](C)(C)C)OC[C@H]2O[C@H]1N1C=NC2=C(N)N=CN=C21	standard polar	2025-10-24	1656.6
Gas Chromatography	3',3'-cGAMP_TMS_50	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]2[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O)[C@@H]3O	standard polar	2025-10-24	713.377
Gas Chromatography	3',3'-cGAMP_TMS_51	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O[Si](C)(C)C)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O[Si](C)(C)C)C=N2	standard polar	2025-10-24	3385.62
Gas Chromatography	3',3'-cGAMP_TMS_52	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O[Si](C)(C)C)OC[C@H]3O[C@@H](N4C=NC5=C4N([Si](C)(C)C)C(=N)N=C5O)[C@H](O)[C@@H]3OP(=O)(O)OC[C@H]2O[C@H]1N1C=NC2=C(N)N=CN=C21	standard polar	2025-10-24	2587.12
Gas Chromatography	3',3'-cGAMP_TMS_53	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O[Si](C)(C)C)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O)[C@@H]3O	standard polar	2025-10-24	1576.1
Gas Chromatography	3',3'-cGAMP_TMS_54	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O[Si](C)(C)C)C=N2	standard polar	2025-10-24	3153.8
Gas Chromatography	3',3'-cGAMP_TMS_55	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O)OC[C@H]3O[C@@H](N4C=NC5=C4N([Si](C)(C)C)C(=N)N=C5O)[C@H](O)[C@@H]3OP(=O)(O[Si](C)(C)C)OC[C@H]2O[C@H]1N1C=NC2=C(N)N=CN=C21	standard polar	2025-10-24	4230.94
Gas Chromatography	3',3'-cGAMP_TMS_56	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O)OC[C@H]3O[C@@H](N4C=NC5=C4[NH]C(=N)N=C5O)[C@H](O)[C@@H]3OP(=O)(O)OC[C@H]2O[C@H]1N1C=NC2=C(N([Si](C)(C)C)[Si](C)(C)C)N=CN=C21	standard polar	2025-10-24	2915.85
Gas Chromatography	3',3'-cGAMP_TMS_57	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N[Si](C)(C)C)N=CN=C31)[C@@H]4O[Si](C)(C)C)C=N2	standard polar	2025-10-24	2247.36
Gas Chromatography	3',3'-cGAMP_TMS_58	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC2=C1N([Si](C)(C)C)C(=N)N=C2O)[C@@H]3O	standard polar	2025-10-24	-68.8982
Gas Chromatography	3',3'-cGAMP_TMS_59	C[Si](C)(C)N=C1N=C(O)C2=C(N([C@@H]3O[C@@H]4COP(=O)(O)O[C@@H]5[C@@H](COP(=O)(O)O[C@H]4[C@H]3O)O[C@@H](N3C=NC4=C(N)N=CN=C43)[C@@H]5O[Si](C)(C)C)C=N2)N1[Si](C)(C)C	standard polar	2025-10-24	1666.91
Gas Chromatography	3',3'-cGAMP_TMS_60	C[Si](C)(C)OC1=NC(=N)[NH]C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O[Si](C)(C)C)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O	standard polar	2025-10-24	1299.27
Gas Chromatography	3',3'-cGAMP_TMS_61	C[Si](C)(C)OC1=NC(=N)[NH]C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]2[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O	standard polar	2025-10-24	2869.56
Gas Chromatography	3',3'-cGAMP_TMS_62	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O[Si](C)(C)C)[C@@H]3O[Si](C)(C)C	standard polar	2025-10-24	4519.02
Gas Chromatography	3',3'-cGAMP_TMS_63	C[Si](C)(C)N=C1N=C(O[Si](C)(C)C)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O)C=N2	standard polar	2025-10-24	1414.25
Gas Chromatography	3',3'-cGAMP_TMS_64	C[Si](C)(C)OC1=NC(=N)N([Si](C)(C)C)C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O	standard polar	2025-10-24	2655.23
Gas Chromatography	3',3'-cGAMP_TMS_65	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O[Si](C)(C)C)OC[C@H]3O[C@@H](N4C=NC5=C(N)N=CN=C54)[C@H](O)[C@@H]3OP(=O)(O[Si](C)(C)C)OC[C@H]2O[C@H]1N1C=NC2=C1[NH]C(=N)N=C2O	standard polar	2025-10-24	2388.43
Gas Chromatography	3',3'-cGAMP_TMS_66	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O[Si](C)(C)C)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O)[C@@H]3O[Si](C)(C)C	standard polar	2025-10-24	2983.44
Gas Chromatography	3',3'-cGAMP_TMS_67	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]3[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O)C=N2	standard polar	2025-10-24	2664.62
Gas Chromatography	3',3'-cGAMP_TMS_68	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O[Si](C)(C)C)OC[C@H]3O[C@@H](N4C=NC5=C(N)N=CN=C54)[C@H](O)[C@@H]3OP(=O)(O)OC[C@H]2O[C@H]1N1C=NC2=C1N([Si](C)(C)C)C(=N)N=C2O	standard polar	2025-10-24	2096.57
Gas Chromatography	3',3'-cGAMP_TMS_69	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O)[C@@H]3O[Si](C)(C)C	standard polar	2025-10-24	3257.16
Gas Chromatography	3',3'-cGAMP_TMS_70	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O[Si](C)(C)C)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O)C=N2	standard polar	2025-10-24	1210.48
Gas Chromatography	3',3'-cGAMP_TMS_71	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O)OC[C@H]3O[C@@H](N4C=NC5=C(N)N=CN=C54)[C@H](O)[C@@H]3OP(=O)(O[Si](C)(C)C)OC[C@H]2O[C@H]1N1C=NC2=C1N([Si](C)(C)C)C(=N)N=C2O	standard polar	2025-10-24	2582.71
Gas Chromatography	3',3'-cGAMP_TMS_72	C[Si](C)(C)O[C@@H]1[C@@H]2OP(=O)(O)OC[C@H]3O[C@@H](N4C=NC5=C(N([Si](C)(C)C)[Si](C)(C)C)N=CN=C54)[C@H](O)[C@@H]3OP(=O)(O)OC[C@H]2O[C@H]1N1C=NC2=C1[NH]C(=N)N=C2O	standard polar	2025-10-24	1277.13
Gas Chromatography	3',3'-cGAMP_TMS_73	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O[Si](C)(C)C)O[C@@H](N1C=NC3=C(N[Si](C)(C)C)N=CN=C31)[C@@H]4O)C=N2	standard polar	2025-10-24	2007.08
Gas Chromatography	3',3'-cGAMP_TMS_74	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1N([Si](C)(C)C)C(=N)N=C2O)[C@@H]3O[Si](C)(C)C	standard polar	2025-10-24	1960.45
Gas Chromatography	3',3'-cGAMP_TMS_75	C[Si](C)(C)N=C1N=C(O)C2=C(N([C@@H]3O[C@@H]4COP(=O)(O)O[C@@H]5[C@@H](COP(=O)(O)O[C@H]4[C@H]3O[Si](C)(C)C)O[C@@H](N3C=NC4=C(N)N=CN=C43)[C@@H]5O)C=N2)N1[Si](C)(C)C	standard polar	2025-10-24	1647.92
Gas Chromatography	3',3'-cGAMP_TMS_76	C[Si](C)(C)OC1=NC(=N)[NH]C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O[Si](C)(C)C)O[C@@H]3[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O	standard polar	2025-10-24	2663.66
Gas Chromatography	3',3'-cGAMP_TMS_77	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O[Si](C)(C)C)[C@@H]3O	standard polar	2025-10-24	1015.19
Gas Chromatography	3',3'-cGAMP_TMS_78	C[Si](C)(C)N=C1N=C(O[Si](C)(C)C)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O[Si](C)(C)C)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O)C=N2	standard polar	2025-10-24	1832.89
Gas Chromatography	3',3'-cGAMP_TMS_79	C[Si](C)(C)OC1=NC(=N)N([Si](C)(C)C)C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O[Si](C)(C)C)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O	standard polar	2025-10-24	1879.86
Gas Chromatography	3',3'-cGAMP_TMS_80	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O[Si](C)(C)C)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O[Si](C)(C)C)[C@@H]3O	standard polar	2025-10-24	1697.62
Gas Chromatography	3',3'-cGAMP_TMS_81	C[Si](C)(C)N=C1N=C(O[Si](C)(C)C)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O)C=N2	standard polar	2025-10-24	2491.31
Gas Chromatography	3',3'-cGAMP_TMS_82	C[Si](C)(C)OC1=NC(=N)N([Si](C)(C)C)C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C(N)N=CN=C21)[C@@H]3O	standard polar	2025-10-24	2399.01
Gas Chromatography	3',3'-cGAMP_TMS_83	C[Si](C)(C)OC1=NC(=N)[NH]C2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C(N([Si](C)(C)C)[Si](C)(C)C)N=CN=C21)[C@@H]3O	standard polar	2025-10-24	2398.15
Gas Chromatography	3',3'-cGAMP_TMS_84	C[Si](C)(C)N=C1N=C(O[Si](C)(C)C)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N[Si](C)(C)C)N=CN=C31)[C@@H]4O)C=N2	standard polar	2025-10-24	2753.8
Gas Chromatography	3',3'-cGAMP_TMS_85	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1N([Si](C)(C)C)C(=N)N=C2O[Si](C)(C)C)[C@@H]3O	standard polar	2025-10-24	3999.7
Gas Chromatography	3',3'-cGAMP_TMS_86	C[Si](C)(C)N=C1N=C(O[Si](C)(C)C)C2=C(N([C@@H]3O[C@@H]4COP(=O)(O)O[C@@H]5[C@@H](COP(=O)(O)O[C@H]4[C@H]3O)O[C@@H](N3C=NC4=C(N)N=CN=C43)[C@@H]5O)C=N2)N1[Si](C)(C)C	standard polar	2025-10-24	3484.64
Gas Chromatography	3',3'-cGAMP_TMS_87	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O[Si](C)(C)C)O[C@@H]3[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1[NH]C(=N)N=C2O)[C@@H]3O	standard polar	2025-10-24	2057.1
Gas Chromatography	3',3'-cGAMP_TMS_88	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O[Si](C)(C)C)O[C@@H]4[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N)N=CN=C31)[C@@H]4O)C=N2	standard polar	2025-10-24	2492.48
Gas Chromatography	3',3'-cGAMP_TMS_89	C[Si](C)(C)OP1(=O)OC[C@H]2O[C@@H](N3C=NC4=C3N([Si](C)(C)C)C(=N)N=C4O)[C@H](O)[C@@H]2OP(=O)(O[Si](C)(C)C)OC[C@H]2O[C@@H](N3C=NC4=C(N)N=CN=C43)[C@H](O)[C@@H]2O1	standard polar	2025-10-24	2842.06
Gas Chromatography	3',3'-cGAMP_TMS_90	C[Si](C)(C)OP1(=O)OC[C@H]2O[C@@H](N3C=NC4=C(N([Si](C)(C)C)[Si](C)(C)C)N=CN=C43)[C@H](O)[C@@H]2OP(=O)(O)OC[C@H]2O[C@@H](N3C=NC4=C3[NH]C(=N)N=C4O)[C@H](O)[C@@H]2O1	standard polar	2025-10-24	2084.32
Gas Chromatography	3',3'-cGAMP_TMS_91	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N[Si](C)(C)C)N=CN=C31)[C@@H]4O)C=N2	standard polar	2025-10-24	2176.83
Gas Chromatography	3',3'-cGAMP_TMS_92	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O[Si](C)(C)C)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1N([Si](C)(C)C)C(=N)N=C2O)[C@@H]3O	standard polar	2025-10-24	1234.24
Gas Chromatography	3',3'-cGAMP_TMS_93	C[Si](C)(C)N=C1N=C(O)C2=C(N([C@@H]3O[C@@H]4COP(=O)(O)O[C@@H]5[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]4[C@H]3O)O[C@@H](N3C=NC4=C(N)N=CN=C43)[C@@H]5O)C=N2)N1[Si](C)(C)C	standard polar	2025-10-24	1398.92
Gas Chromatography	3',3'-cGAMP_TMS_94	C[Si](C)(C)OP1(=O)OC[C@H]2O[C@@H](N3C=NC4=C3[NH]C(=N)N=C4O)[C@H](O)[C@@H]2OP(=O)(O)OC[C@H]2O[C@@H](N3C=NC4=C(N([Si](C)(C)C)[Si](C)(C)C)N=CN=C43)[C@H](O)[C@@H]2O1	standard polar	2025-10-24	1975.38
Gas Chromatography	3',3'-cGAMP_TMS_95	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O[Si](C)(C)C)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N[Si](C)(C)C)N=CN=C31)[C@@H]4O)C=N2	standard polar	2025-10-24	1845.69
Gas Chromatography	3',3'-cGAMP_TMS_96	C[Si](C)(C)NC1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O[Si](C)(C)C)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1N([Si](C)(C)C)C(=N)N=C2O)[C@@H]3O	standard polar	2025-10-24	1831.56
Gas Chromatography	3',3'-cGAMP_TMS_97	C[Si](C)(C)N=C1N=C(O)C2=C(N([C@@H]3O[C@@H]4COP(=O)(O[Si](C)(C)C)O[C@@H]5[C@@H](COP(=O)(O)O[C@H]4[C@H]3O)O[C@@H](N3C=NC4=C(N)N=CN=C43)[C@@H]5O)C=N2)N1[Si](C)(C)C	standard polar	2025-10-24	2115.73
Gas Chromatography	3',3'-cGAMP_TMS_98	C[Si](C)(C)N=C1N=C(O)C2=C([NH]1)N([C@@H]1O[C@@H]3COP(=O)(O)O[C@@H]4[C@@H](COP(=O)(O)O[C@H]3[C@H]1O)O[C@@H](N1C=NC3=C(N([Si](C)(C)C)[Si](C)(C)C)N=CN=C31)[C@@H]4O)C=N2	standard polar	2025-10-24	703.738
Gas Chromatography	3',3'-cGAMP_TMS_99	C[Si](C)(C)N(C1=NC=NC2=C1N=CN2[C@@H]1O[C@@H]2COP(=O)(O)O[C@@H]3[C@@H](COP(=O)(O)O[C@H]2[C@H]1O)O[C@@H](N1C=NC2=C1N([Si](C)(C)C)C(=N)N=C2O)[C@@H]3O)[Si](C)(C)C	standard polar	2025-10-24	1093.78
Gas Chromatography	3',3'-cGAMP_TMS_100	C[Si](C)(C)N=C1N=C(O)C2=C(N([C@@H]3O[C@@H]4COP(=O)(O)O[C@@H]5[C@@H](COP(=O)(O)O[C@H]4[C@H]3O)O[C@@H](N3C=NC4=C(N[Si](C)(C)C)N=CN=C43)[C@@H]5O)C=N2)N1[Si](C)(C)C	standard polar	2025-10-24	2591.0

Biological Properties

Cellular Locations

Not Available

Biospecimen Locations

Not Available

Tissue Locations

Not Available

Associated OMIM IDs

114500 (Colorectal cancer)
610247 (Eosinophilic esophagitis)

Human Proteins and Enzymes

Protein ID	Protein Name	Protein Type	Uniprot ID	Species
MMDBp0196709	Cyclic GMP-AMP synthase	Unknown	Q8N884

Human Pathways

Pathways

Name	SMPDB/PathBank

Microbial Pathways

Pathways

Not Available

Metabolic Reactions

Reactions

This table shows at most 20 reactions. For the full list of associated reactions:

See All Associated Reactions

Reaction ID	Precursor	Product	Enzyme	Reaction Type	Data Source	Reference

Health Effects and Bioactivity

Health Outcome/Bioactivity	Metabolite Response/Effect	Evidence Type	Host and Biospecimen	Data Source	Reference

Microbial Sources

Superkingdom/Kingdom	Phylum	Total species	Hosts and Body Sites	Microbial Links
Bacteria/Eubacteria	Bacteroidetes	1	Human
Bacteria/Eubacteria	Proteobacteria	2	Human ; Human feces; Human feces; pleural fluid plaque; bal

Exposure Sources

Other Exposures

Source Type	Data Source	Reference

Host Biospecimen and Location

Host and Biospecimen	Status	Mean	Std	Min	Max	Units	Age	Sex	Health Condition	Data Source	Reference

External Links

Not Available

General References

Magrane M: UniProt Knowledgebase: a hub of integrated protein data. Database (Oxford). 2011 Mar 29;2011:bar009. doi: 10.1093/database/bar009. Print 2011. [PubMed:21447597 ]

Showing metabocard for 3',3'-cGAMP (MMDBc0054254)

MOL for #<Metabolite:0x00007f9ad0f6fb40>

3D MOL for #<Metabolite:0x00007f9ad0f6fb40>

3D SDF for #<Metabolite:0x00007f9ad0f6fb40>

3D-SDF for #<Metabolite:0x00007f9ad0f6fb40>

PDB for #<Metabolite:0x00007f9ad0f6fb40>

3D PDB for #<Metabolite:0x00007f9ad0f6fb40>

SMILES for #<Metabolite:0x00007f9ad0f6fb40>

INCHI for #<Metabolite:0x00007f9ad0f6fb40>

Structure for #<Metabolite:0x00007f9ad0f6fb40>

3D Structure for #<Metabolite:0x00007f9ad0f6fb40>