MiMeDB: Showing metabocard for glucosyl-(heptosyl)3-Kdo2-lipid A-phosphate (MMDBc0032143)

Microbial

Record Information

Version

1.0

Status

Detected and Quantified

Creation Date

2021-11-18 02:04:08 UTC

Update Date

2022-08-31 18:30:51 UTC

Metabolite ID

MMDBc0032143

Metabolite Identification

Common Name

glucosyl-(heptosyl)3-Kdo2-lipid A-phosphate

Description

Glucosyl-(heptosyl)3-Kdo2-lipid A-phosphate is an intermediate in lipid A-core biosynthesis pathway in E.coli. It is a substrate for the enzyme lipopolysaccharide core heptose (II) kinase which catalyzes the reaction glucosyl-(heptosyl)3-Kdo2-lipid A-phosphate + ATP -> glucosyl-(heptosyl)3-Kdo2-lipid A-bisphosphate + ADP + H+. It is also a product for enzyme lipopolysaccharide core heptosyl transferase III which catalyzes reaction glucosyl-(heptosyl)2-Kdo2-lipid A-phosphate + ADP-L-glycero-beta-D-manno-heptose -> glucosyl-(heptosyl)3-Kdo2-lipid A-phosphate + ADP + H+ (BioCyc compound: CPD0-934).

Structure

MOL SDF PDB SMILES InChI

      
  Mrv1533005261512122D          

209216  0  0  0  0            999 V2000
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187188  1  6  0  0  0
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190191  1  1  0  0  0
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194195  1  1  0  0  0
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161196  1  0  0  0  0
196197  1  1  0  0  0
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198199  1  6  0  0  0
 13200  1  6  0  0  0
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  4203  1  6  0  0  0
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203205  2  0  0  0  0
  2206  1  6  0  0  0
206207  1  6  0  0  0
206208  1  0  0  0  0
208209  1  0  0  0  0
M  CHG  8  26  -1  27  -1 134  -1 135  -1 156  -1 157  -1 201  -1 204  -1
M  END

      
  Mrv1533005261512122D          

209216  0  0  0  0            999 V2000
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208209  1  0  0  0  0
M  CHG  8  26  -1  27  -1 134  -1 135  -1 156  -1 157  -1 201  -1 204  -1
M  END
> <DATABASE_ID>
MMDBc0032143

> <DATABASE_NAME>
MIME

> <SMILES>
[H][C@@]1(O[C@@](C[C@@H](O)[C@H]1O)(O[C@@H]1C[C@@](OC[C@H]2O[C@@H](OC[C@H]3O[C@H](OP([O-])([O-])=O)[C@H](NC(=O)C[C@H](O)CCCCCCCCCCC)[C@@H](OC(=O)C[C@H](O)CCCCCCCCCCC)[C@@H]3O)[C@H](NC(=O)C[C@@H](CCCCCCCCCCC)OC(=O)CCCCCCCCCCC)[C@@H](OC(=O)C[C@@H](CCCCCCCCCCC)OC(=O)CCCCCCCCCCCCC)[C@@H]2OP([O-])([O-])=O)(O[C@]([H])([C@H](O)CO)[C@@H]1O[C@H]1O[C@H]([C@@H](O)CO)[C@@H](OP([O-])([O-])=O)[C@H](O[C@H]2O[C@H]([C@@H](O)COC3O[C@H]([C@@H](O)CO)[C@@H](O)[C@H](O)[C@@H]3O)[C@@H](O)[C@H](OC3O[C@H](CO)[C@@H](O)[C@H](O)[C@H]3O)[C@@H]2O)[C@@H]1O)C([O-])=O)C([O-])=O)[C@H](O)CO

> <INCHI_IDENTIFIER>
InChI=1S/C137H249N2O65P3/c1-7-13-19-25-31-37-38-44-50-56-62-68-100(156)187-86(66-60-54-48-42-35-29-23-17-11-5)72-102(158)192-124-104(139-98(154)71-85(65-59-53-47-41-34-28-22-16-10-4)186-99(155)67-61-55-49-43-36-30-24-18-12-6)128(184-81-95-107(161)123(191-101(157)70-84(146)64-58-52-46-40-33-27-21-15-9-3)103(129(189-95)204-207(180,181)182)138-97(153)69-83(145)63-57-51-45-39-32-26-20-14-8-2)190-96(122(124)202-205(174,175)176)82-185-136(134(170)171)74-93(199-137(135(172)173)73-87(147)105(159)118(200-137)89(149)76-141)121(120(201-136)91(151)78-143)196-133-115(169)126(127(203-206(177,178)179)119(195-133)90(150)77-142)198-132-114(168)125(197-131-112(166)108(162)106(160)94(79-144)188-131)113(167)117(194-132)92(152)80-183-130-111(165)109(163)110(164)116(193-130)88(148)75-140/h83-96,103-133,140-152,159-169H,7-82H2,1-6H3,(H,138,153)(H,139,154)(H,170,171)(H,172,173)(H2,174,175,176)(H2,177,178,179)(H2,180,181,182)/p-8/t83-,84-,85-,86-,87-,88+,89-,90+,91-,92+,93-,94-,95-,96-,103-,104-,105-,106-,107?,108+,109+,110+,111+,112-,113-,114+,115+,116-,117-,118-,119-,120-,121-,122-,123-,124-,125+,126-,127-,128-,129-,130?,131?,132-,133-,136-,137-/m1/s1

> <INCHI_KEY>
QHKUHEQURQLSFA-QCNSDWGJSA-F

> <FORMULA>
C137H241N2O65P3

> <MOLECULAR_WEIGHT>
3049.31

> <EXACT_MASS>
3047.487105701

> <JCHEM_ACCEPTOR_COUNT>
58

> <JCHEM_ATOM_COUNT>
448

> <JCHEM_AVERAGE_POLARIZABILITY>
321.02410718274905

> <JCHEM_BIOAVAILABILITY>
0

> <JCHEM_DONOR_COUNT>
26

> <JCHEM_FORMAL_CHARGE>
-8

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(2R,4R,5R,6R)-2-{[(2R,4R,5R,6R)-2-carboxylato-6-[(1R)-1,2-dihydroxyethyl]-5-{[(2S,3S,4R,5R,6R)-6-[(1S)-1,2-dihydroxyethyl]-4-{[(2R,3S,4S,5R,6R)-6-[(1S)-2-{[(3S,4S,5S,6R)-6-[(1S)-1,2-dihydroxyethyl]-3,4,5-trihydroxyoxan-2-yl]oxy}-1-hydroxyethyl]-3,5-dihydroxy-4-{[(3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}oxan-2-yl]oxy}-3-hydroxy-5-(phosphonatooxy)oxan-2-yl]oxy}-2-{[(2R,3S,4R,5R,6R)-5-[(3R)-3-(dodecanoyloxy)tetradecanamido]-6-{[(2R,3S,4R,5R,6R)-3-hydroxy-5-[(3R)-3-hydroxytetradecanamido]-4-{[(3R)-3-hydroxytetradecanoyl]oxy}-6-(phosphonatooxy)oxan-2-yl]methoxy}-3-(phosphonatooxy)-4-{[(3R)-3-(tetradecanoyloxy)tetradecanoyl]oxy}oxan-2-yl]methoxy}oxan-4-yl]oxy}-6-[(1R)-1,2-dihydroxyethyl]-4,5-dihydroxyoxane-2-carboxylate

> <ALOGPS_LOGP>
2.58

> <JCHEM_LOGP>
11.904648639666664

> <ALOGPS_LOGS>
-3.60

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
8

> <JCHEM_PHYSIOLOGICAL_CHARGE>
-8

> <JCHEM_PKA>
0.8261477200007334

> <JCHEM_PKA_STRONGEST_ACIDIC>
0.30881467462519474

> <JCHEM_POLAR_SURFACE_AREA>
1084.8900000000003

> <JCHEM_REFRACTIVITY>
736.9511000000023

> <JCHEM_ROTATABLE_BOND_COUNT>
115

> <JCHEM_RULE_OF_FIVE>
0

> <ALOGPS_SOLUBILITY>
8.07e-01 g/l

> <JCHEM_TRADITIONAL_IUPAC>
(2R,4R,5R,6R)-2-{[(2R,4R,5R,6R)-2-carboxylato-6-[(1R)-1,2-dihydroxyethyl]-5-{[(2S,3S,4R,5R,6R)-6-[(1S)-1,2-dihydroxyethyl]-4-{[(2R,3S,4S,5R,6R)-6-[(1S)-2-{[(3S,4S,5S,6R)-6-[(1S)-1,2-dihydroxyethyl]-3,4,5-trihydroxyoxan-2-yl]oxy}-1-hydroxyethyl]-3,5-dihydroxy-4-{[(3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}oxan-2-yl]oxy}-3-hydroxy-5-(phosphonatooxy)oxan-2-yl]oxy}-2-{[(2R,3S,4R,5R,6R)-5-[(3R)-3-(dodecanoyloxy)tetradecanamido]-6-{[(2R,3S,4R,5R,6R)-3-hydroxy-5-[(3R)-3-hydroxytetradecanamido]-4-{[(3R)-3-hydroxytetradecanoyl]oxy}-6-(phosphonatooxy)oxan-2-yl]methoxy}-3-(phosphonatooxy)-4-{[(3R)-3-(tetradecanoyloxy)tetradecanoyl]oxy}oxan-2-yl]methoxy}oxan-4-yl]oxy}-6-[(1R)-1,2-dihydroxyethyl]-4,5-dihydroxyoxane-2-carboxylate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 26-MAY-15   NONE
TITLE     NULL                                                        
COMPND    MOLECULE:                                                   
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   26-MAY-15         0                                  
HETATM    1  H   UNK     0      -8.252  -4.741   0.000  0.00  0.00           H+0
HETATM    2  C   UNK     0      -7.438  -6.048   0.000  0.00  0.00           C+0
HETATM    3  O   UNK     0      -6.625  -7.356   0.000  0.00  0.00           O+0
HETATM    4  C   UNK     0      -5.085  -7.305   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0      -4.360  -5.946   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0      -5.174  -4.639   0.000  0.00  0.00           C+0
HETATM    7  O   UNK     0      -4.448  -3.280   0.000  0.00  0.00           O+0
HETATM    8  C   UNK     0      -6.713  -4.690   0.000  0.00  0.00           C+0
HETATM    9  O   UNK     0      -7.527  -3.382   0.000  0.00  0.00           O+0
HETATM   10  O   UNK     0      -4.981  -8.841   0.000  0.00  0.00           O+0
HETATM   11  C   UNK     0      -3.311  -9.191   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0      -2.320  -8.660   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0      -0.937  -9.337   0.000  0.00  0.00           C+0
HETATM   14  O   UNK     0      -0.509  -7.858   0.000  0.00  0.00           O+0
HETATM   15  C   UNK     0      -1.577  -6.748   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0      -1.150  -5.269   0.000  0.00  0.00           C+0
HETATM   17  O   UNK     0      -2.218  -4.159   0.000  0.00  0.00           O+0
HETATM   18  C   UNK     0      -1.791  -2.679   0.000  0.00  0.00           C+0
HETATM   19  O   UNK     0      -2.859  -1.570   0.000  0.00  0.00           O+0
HETATM   20  C   UNK     0      -2.432  -0.090   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0      -3.499   1.019   0.000  0.00  0.00           C+0
HETATM   22  O   UNK     0      -4.994   0.650   0.000  0.00  0.00           O+0
HETATM   23  C   UNK     0      -6.062   1.759   0.000  0.00  0.00           C+0
HETATM   24  O   UNK     0      -7.557   1.389   0.000  0.00  0.00           O+0
HETATM   25  P   UNK     0      -7.984  -0.090   0.000  0.00  0.00           P+0
HETATM   26  O   UNK     0      -6.504  -0.517   0.000  0.00  0.00           O-1
HETATM   27  O   UNK     0      -8.411  -1.570   0.000  0.00  0.00           O-1
HETATM   28  O   UNK     0      -9.464   0.337   0.000  0.00  0.00           O+0
HETATM   29  C   UNK     0      -5.205   3.731   0.000  0.00  0.00           C+0
HETATM   30  N   UNK     0      -6.273   4.841   0.000  0.00  0.00           N+0
HETATM   31  C   UNK     0      -6.705   5.336   0.000  0.00  0.00           C+0
HETATM   32  O   UNK     0      -5.210   5.706   0.000  0.00  0.00           O+0
HETATM   33  C   UNK     0      -7.343   6.938   0.000  0.00  0.00           C+0
HETATM   34  C   UNK     0      -7.346   7.925   0.000  0.00  0.00           C+0
HETATM   35  O   UNK     0      -5.851   8.295   0.000  0.00  0.00           O+0
HETATM   36  C   UNK     0      -7.984   9.527   0.000  0.00  0.00           C+0
HETATM   37  C   UNK     0      -7.557  11.007   0.000  0.00  0.00           C+0
HETATM   38  C   UNK     0      -8.625  12.116   0.000  0.00  0.00           C+0
HETATM   39  C   UNK     0      -8.198  13.596   0.000  0.00  0.00           C+0
HETATM   40  C   UNK     0      -9.265  14.706   0.000  0.00  0.00           C+0
HETATM   41  C   UNK     0      -8.838  16.185   0.000  0.00  0.00           C+0
HETATM   42  C   UNK     0      -9.906  17.295   0.000  0.00  0.00           C+0
HETATM   43  C   UNK     0      -9.479  18.774   0.000  0.00  0.00           C+0
HETATM   44  C   UNK     0     -10.547  19.884   0.000  0.00  0.00           C+0
HETATM   45  C   UNK     0     -10.120  21.364   0.000  0.00  0.00           C+0
HETATM   46  C   UNK     0     -11.187  22.473   0.000  0.00  0.00           C+0
HETATM   47  C   UNK     0      -3.711   4.101   0.000  0.00  0.00           C+0
HETATM   48  O   UNK     0      -3.713   5.088   0.000  0.00  0.00           O+0
HETATM   49  C   UNK     0      -4.781   6.198   0.000  0.00  0.00           C+0
HETATM   50  O   UNK     0      -6.276   5.828   0.000  0.00  0.00           O+0
HETATM   51  C   UNK     0      -4.354   7.678   0.000  0.00  0.00           C+0
HETATM   52  C   UNK     0      -5.421   8.787   0.000  0.00  0.00           C+0
HETATM   53  O   UNK     0      -6.916   8.417   0.000  0.00  0.00           O+0
HETATM   54  C   UNK     0      -4.994  10.267   0.000  0.00  0.00           C+0
HETATM   55  C   UNK     0      -6.062  11.377   0.000  0.00  0.00           C+0
HETATM   56  C   UNK     0      -5.635  12.856   0.000  0.00  0.00           C+0
HETATM   57  C   UNK     0      -6.703  13.966   0.000  0.00  0.00           C+0
HETATM   58  C   UNK     0      -6.276  15.445   0.000  0.00  0.00           C+0
HETATM   59  C   UNK     0      -7.343  16.555   0.000  0.00  0.00           C+0
HETATM   60  C   UNK     0      -6.916  18.035   0.000  0.00  0.00           C+0
HETATM   61  C   UNK     0      -7.984  19.144   0.000  0.00  0.00           C+0
HETATM   62  C   UNK     0      -7.557  20.624   0.000  0.00  0.00           C+0
HETATM   63  C   UNK     0      -8.625  21.734   0.000  0.00  0.00           C+0
HETATM   64  C   UNK     0      -8.198  23.213   0.000  0.00  0.00           C+0
HETATM   65  C   UNK     0      -3.565   2.928   0.000  0.00  0.00           C+0
HETATM   66  O   UNK     0      -2.070   3.298   0.000  0.00  0.00           O+0
HETATM   67  C   UNK     0      -0.296  -2.309   0.000  0.00  0.00           C+0
HETATM   68  N   UNK     0       0.131  -0.830   0.000  0.00  0.00           N+0
HETATM   69  C   UNK     0       2.118  -0.889   0.000  0.00  0.00           C+0
HETATM   70  O   UNK     0       2.264  -2.062   0.000  0.00  0.00           O+0
HETATM   71  C   UNK     0       2.053   1.019   0.000  0.00  0.00           C+0
HETATM   72  C   UNK     0       0.985   2.129   0.000  0.00  0.00           C+0
HETATM   73  C   UNK     0      -0.509   1.759   0.000  0.00  0.00           C+0
HETATM   74  C   UNK     0      -1.577   2.869   0.000  0.00  0.00           C+0
HETATM   75  C   UNK     0      -3.072   2.499   0.000  0.00  0.00           C+0
HETATM   76  C   UNK     0      -4.140   3.609   0.000  0.00  0.00           C+0
HETATM   77  C   UNK     0      -5.635   3.239   0.000  0.00  0.00           C+0
HETATM   78  C   UNK     0      -6.703   4.348   0.000  0.00  0.00           C+0
HETATM   79  C   UNK     0      -8.198   3.979   0.000  0.00  0.00           C+0
HETATM   80  C   UNK     0      -9.265   5.088   0.000  0.00  0.00           C+0
HETATM   81  C   UNK     0     -10.760   4.718   0.000  0.00  0.00           C+0
HETATM   82  C   UNK     0     -11.828   5.828   0.000  0.00  0.00           C+0
HETATM   83  C   UNK     0     -13.323   5.458   0.000  0.00  0.00           C+0
HETATM   84  O   UNK     0       1.412   3.609   0.000  0.00  0.00           O+0
HETATM   85  C   UNK     0       0.345   4.718   0.000  0.00  0.00           C+0
HETATM   86  O   UNK     0      -1.150   4.348   0.000  0.00  0.00           O+0
HETATM   87  C   UNK     0       0.772   6.198   0.000  0.00  0.00           C+0
HETATM   88  C   UNK     0      -0.296   7.308   0.000  0.00  0.00           C+0
HETATM   89  C   UNK     0       0.131   8.787   0.000  0.00  0.00           C+0
HETATM   90  C   UNK     0      -0.937   9.897   0.000  0.00  0.00           C+0
HETATM   91  C   UNK     0      -0.509  11.377   0.000  0.00  0.00           C+0
HETATM   92  C   UNK     0      -1.577  12.486   0.000  0.00  0.00           C+0
HETATM   93  C   UNK     0      -1.150  13.966   0.000  0.00  0.00           C+0
HETATM   94  C   UNK     0      -2.218  15.075   0.000  0.00  0.00           C+0
HETATM   95  C   UNK     0      -1.791  16.555   0.000  0.00  0.00           C+0
HETATM   96  C   UNK     0      -2.859  17.665   0.000  0.00  0.00           C+0
HETATM   97  C   UNK     0      -2.432  19.144   0.000  0.00  0.00           C+0
HETATM   98  C   UNK     0       0.772  -3.419   0.000  0.00  0.00           C+0
HETATM   99  O   UNK     0       2.267  -3.049   0.000  0.00  0.00           O+0
HETATM  100  C   UNK     0       2.694  -1.570   0.000  0.00  0.00           C+0
HETATM  101  O   UNK     0       1.626  -0.460   0.000  0.00  0.00           O+0
HETATM  102  C   UNK     0       4.189  -1.200   0.000  0.00  0.00           C+0
HETATM  103  C   UNK     0       4.616   0.280   0.000  0.00  0.00           C+0
HETATM  104  C   UNK     0       3.548   1.389   0.000  0.00  0.00           C+0
HETATM  105  C   UNK     0       3.975   2.869   0.000  0.00  0.00           C+0
HETATM  106  C   UNK     0       2.907   3.979   0.000  0.00  0.00           C+0
HETATM  107  C   UNK     0       3.334   5.458   0.000  0.00  0.00           C+0
HETATM  108  C   UNK     0       2.267   6.568   0.000  0.00  0.00           C+0
HETATM  109  C   UNK     0       2.694   8.047   0.000  0.00  0.00           C+0
HETATM  110  C   UNK     0       1.626   9.157   0.000  0.00  0.00           C+0
HETATM  111  C   UNK     0       2.053  10.637   0.000  0.00  0.00           C+0
HETATM  112  C   UNK     0       0.985  11.746   0.000  0.00  0.00           C+0
HETATM  113  C   UNK     0       1.412  13.226   0.000  0.00  0.00           C+0
HETATM  114  C   UNK     0       2.907  13.596   0.000  0.00  0.00           C+0
HETATM  115  O   UNK     0       6.111   0.650   0.000  0.00  0.00           O+0
HETATM  116  C   UNK     0       6.538   2.129   0.000  0.00  0.00           C+0
HETATM  117  O   UNK     0       5.470   3.239   0.000  0.00  0.00           O+0
HETATM  118  C   UNK     0       8.033   2.499   0.000  0.00  0.00           C+0
HETATM  119  C   UNK     0       8.460   3.979   0.000  0.00  0.00           C+0
HETATM  120  C   UNK     0       9.955   4.348   0.000  0.00  0.00           C+0
HETATM  121  C   UNK     0      10.382   5.828   0.000  0.00  0.00           C+0
HETATM  122  C   UNK     0      11.877   6.198   0.000  0.00  0.00           C+0
HETATM  123  C   UNK     0      12.304   7.678   0.000  0.00  0.00           C+0
HETATM  124  C   UNK     0      13.799   8.047   0.000  0.00  0.00           C+0
HETATM  125  C   UNK     0      14.226   9.527   0.000  0.00  0.00           C+0
HETATM  126  C   UNK     0      15.721   9.897   0.000  0.00  0.00           C+0
HETATM  127  C   UNK     0      16.148  11.377   0.000  0.00  0.00           C+0
HETATM  128  C   UNK     0      17.643  11.746   0.000  0.00  0.00           C+0
HETATM  129  C   UNK     0      18.070  13.226   0.000  0.00  0.00           C+0
HETATM  130  C   UNK     0      19.565  13.596   0.000  0.00  0.00           C+0
HETATM  131  C   UNK     0       0.345  -4.899   0.000  0.00  0.00           C+0
HETATM  132  O   UNK     0       1.412  -6.008   0.000  0.00  0.00           O+0
HETATM  133  P   UNK     0       2.907  -5.638   0.000  0.00  0.00           P+0
HETATM  134  O   UNK     0       3.277  -7.133   0.000  0.00  0.00           O-1
HETATM  135  O   UNK     0       2.537  -4.144   0.000  0.00  0.00           O-1
HETATM  136  O   UNK     0       4.402  -5.269   0.000  0.00  0.00           O+0
HETATM  137  O   UNK     0      -0.832 -10.874   0.000  0.00  0.00           O+0
HETATM  138  C   UNK     0      -2.110 -11.733   0.000  0.00  0.00           C+0
HETATM  139  H   UNK     0      -3.388 -12.592   0.000  0.00  0.00           H+0
HETATM  140  C   UNK     0      -2.006 -13.269   0.000  0.00  0.00           C+0
HETATM  141  O   UNK     0      -2.535 -14.715   0.000  0.00  0.00           O+0
HETATM  142  C   UNK     0      -0.623 -13.947   0.000  0.00  0.00           C+0
HETATM  143  O   UNK     0       0.656 -13.088   0.000  0.00  0.00           O+0
HETATM  144  C   UNK     0      -3.493 -11.055   0.000  0.00  0.00           C+0
HETATM  145  O   UNK     0      -4.771 -11.914   0.000  0.00  0.00           O+0
HETATM  146  C   UNK     0      -4.667 -13.451   0.000  0.00  0.00           C+0
HETATM  147  O   UNK     0      -3.284 -14.128   0.000  0.00  0.00           O+0
HETATM  148  C   UNK     0      -3.179 -15.665   0.000  0.00  0.00           C+0
HETATM  149  C   UNK     0      -1.796 -16.342   0.000  0.00  0.00           C+0
HETATM  150  O   UNK     0      -1.691 -17.879   0.000  0.00  0.00           O+0
HETATM  151  C   UNK     0      -0.518 -15.483   0.000  0.00  0.00           C+0
HETATM  152  O   UNK     0       0.865 -16.161   0.000  0.00  0.00           O+0
HETATM  153  C   UNK     0      -4.457 -16.523   0.000  0.00  0.00           C+0
HETATM  154  O   UNK     0      -4.353 -18.060   0.000  0.00  0.00           O+0
HETATM  155  P   UNK     0      -5.631 -18.919   0.000  0.00  0.00           P+0
HETATM  156  O   UNK     0      -6.490 -17.641   0.000  0.00  0.00           O-1
HETATM  157  O   UNK     0      -4.772 -20.197   0.000  0.00  0.00           O-1
HETATM  158  O   UNK     0      -6.909 -19.778   0.000  0.00  0.00           O+0
HETATM  159  C   UNK     0      -5.840 -15.846   0.000  0.00  0.00           C+0
HETATM  160  O   UNK     0      -7.119 -16.705   0.000  0.00  0.00           O+0
HETATM  161  C   UNK     0      -8.501 -16.027   0.000  0.00  0.00           C+0
HETATM  162  O   UNK     0      -8.606 -14.491   0.000  0.00  0.00           O+0
HETATM  163  C   UNK     0      -9.989 -13.813   0.000  0.00  0.00           C+0
HETATM  164  C   UNK     0     -10.094 -12.277   0.000  0.00  0.00           C+0
HETATM  165  O   UNK     0      -8.816 -11.418   0.000  0.00  0.00           O+0
HETATM  166  C   UNK     0     -11.477 -11.599   0.000  0.00  0.00           C+0
HETATM  167  O   UNK     0     -11.581 -10.063   0.000  0.00  0.00           O+0
HETATM  168  C   UNK     0     -12.964  -9.385   0.000  0.00  0.00           C+0
HETATM  169  O   UNK     0     -14.242 -10.244   0.000  0.00  0.00           O+0
HETATM  170  C   UNK     0     -15.625  -9.566   0.000  0.00  0.00           C+0
HETATM  171  C   UNK     0     -16.904 -10.426   0.000  0.00  0.00           C+0
HETATM  172  O   UNK     0     -16.799 -11.962   0.000  0.00  0.00           O+0
HETATM  173  C   UNK     0     -18.287  -9.748   0.000  0.00  0.00           C+0
HETATM  174  O   UNK     0     -19.565 -10.607   0.000  0.00  0.00           O+0
HETATM  175  C   UNK     0     -15.730  -8.030   0.000  0.00  0.00           C+0
HETATM  176  O   UNK     0     -17.113  -7.353   0.000  0.00  0.00           O+0
HETATM  177  C   UNK     0     -14.452  -7.171   0.000  0.00  0.00           C+0
HETATM  178  O   UNK     0     -14.557  -5.635   0.000  0.00  0.00           O+0
HETATM  179  C   UNK     0     -13.069  -7.849   0.000  0.00  0.00           C+0
HETATM  180  O   UNK     0     -11.791  -6.990   0.000  0.00  0.00           O+0
HETATM  181  C   UNK     0     -11.267 -14.672   0.000  0.00  0.00           C+0
HETATM  182  O   UNK     0     -12.650 -13.995   0.000  0.00  0.00           O+0
HETATM  183  C   UNK     0     -11.163 -16.208   0.000  0.00  0.00           C+0
HETATM  184  O   UNK     0     -12.441 -17.067   0.000  0.00  0.00           O+0
HETATM  185  C   UNK     0     -12.336 -18.604   0.000  0.00  0.00           C+0
HETATM  186  O   UNK     0     -10.953 -19.281   0.000  0.00  0.00           O+0
HETATM  187  C   UNK     0     -10.849 -20.818   0.000  0.00  0.00           C+0
HETATM  188  C   UNK     0      -9.466 -21.495   0.000  0.00  0.00           C+0
HETATM  189  O   UNK     0      -9.361 -23.032   0.000  0.00  0.00           O+0
HETATM  190  C   UNK     0     -12.127 -21.677   0.000  0.00  0.00           C+0
HETATM  191  O   UNK     0     -12.022 -23.213   0.000  0.00  0.00           O+0
HETATM  192  C   UNK     0     -13.510 -20.999   0.000  0.00  0.00           C+0
HETATM  193  O   UNK     0     -14.788 -21.858   0.000  0.00  0.00           O+0
HETATM  194  C   UNK     0     -13.614 -19.463   0.000  0.00  0.00           C+0
HETATM  195  O   UNK     0     -14.997 -18.785   0.000  0.00  0.00           O+0
HETATM  196  C   UNK     0      -9.780 -16.886   0.000  0.00  0.00           C+0
HETATM  197  O   UNK     0      -9.675 -18.423   0.000  0.00  0.00           O+0
HETATM  198  C   UNK     0      -5.945 -14.309   0.000  0.00  0.00           C+0
HETATM  199  O   UNK     0      -7.328 -13.632   0.000  0.00  0.00           O+0
HETATM  200  C   UNK     0       0.595  -9.501   0.000  0.00  0.00           C+0
HETATM  201  O   UNK     0       1.502  -8.257   0.000  0.00  0.00           O-1
HETATM  202  O   UNK     0       1.218 -10.909   0.000  0.00  0.00           O+0
HETATM  203  C   UNK     0      -3.753  -8.077   0.000  0.00  0.00           C+0
HETATM  204  O   UNK     0      -3.756  -9.617   0.000  0.00  0.00           O-1
HETATM  205  O   UNK     0      -2.418  -7.309   0.000  0.00  0.00           O+0
HETATM  206  C   UNK     0      -8.978  -6.099   0.000  0.00  0.00           C+0
HETATM  207  O   UNK     0      -9.703  -7.458   0.000  0.00  0.00           O+0
HETATM  208  C   UNK     0      -9.791  -4.792   0.000  0.00  0.00           C+0
HETATM  209  O   UNK     0     -11.330  -4.843   0.000  0.00  0.00           O+0
CONECT    1    2                                                            
CONECT    2    1    3    8  206                                             
CONECT    3    2    4                                                       
CONECT    4    3    5   10  203                                             
CONECT    5    4    6                                                       
CONECT    6    5    7    8                                                  
CONECT    7    6                                                            
CONECT    8    6    2    9                                                  
CONECT    9    8                                                            
CONECT   10    4   11                                                       
CONECT   11   10   12  144                                                  
CONECT   12   11   13                                                       
CONECT   13   12   14  137  200                                             
CONECT   14   13   15                                                       
CONECT   15   14   16                                                       
CONECT   16   15   17  131                                                  
CONECT   17   16   18                                                       
CONECT   18   17   19   67                                                  
CONECT   19   18   20                                                       
CONECT   20   19   21                                                       
CONECT   21   20   22   65                                                  
CONECT   22   21   23                                                       
CONECT   23   22   24   29                                                  
CONECT   24   23   25                                                       
CONECT   25   24   26   27   28                                             
CONECT   26   25                                                            
CONECT   27   25                                                            
CONECT   28   25                                                            
CONECT   29   23   30   47                                                  
CONECT   30   29   31                                                       
CONECT   31   30   32   33                                                  
CONECT   32   31                                                            
CONECT   33   31   34                                                       
CONECT   34   33   35   36                                                  
CONECT   35   34                                                            
CONECT   36   34   37                                                       
CONECT   37   36   38                                                       
CONECT   38   37   39                                                       
CONECT   39   38   40                                                       
CONECT   40   39   41                                                       
CONECT   41   40   42                                                       
CONECT   42   41   43                                                       
CONECT   43   42   44                                                       
CONECT   44   43   45                                                       
CONECT   45   44   46                                                       
CONECT   46   45                                                            
CONECT   47   29   48   65                                                  
CONECT   48   47   49                                                       
CONECT   49   48   50   51                                                  
CONECT   50   49                                                            
CONECT   51   49   52                                                       
CONECT   52   51   53   54                                                  
CONECT   53   52                                                            
CONECT   54   52   55                                                       
CONECT   55   54   56                                                       
CONECT   56   55   57                                                       
CONECT   57   56   58                                                       
CONECT   58   57   59                                                       
CONECT   59   58   60                                                       
CONECT   60   59   61                                                       
CONECT   61   60   62                                                       
CONECT   62   61   63                                                       
CONECT   63   62   64                                                       
CONECT   64   63                                                            
CONECT   65   47   21   66                                                  
CONECT   66   65                                                            
CONECT   67   18   68   98                                                  
CONECT   68   67   69                                                       
CONECT   69   68   70   71                                                  
CONECT   70   69                                                            
CONECT   71   69   72                                                       
CONECT   72   71   73   84                                                  
CONECT   73   72   74                                                       
CONECT   74   73   75                                                       
CONECT   75   74   76                                                       
CONECT   76   75   77                                                       
CONECT   77   76   78                                                       
CONECT   78   77   79                                                       
CONECT   79   78   80                                                       
CONECT   80   79   81                                                       
CONECT   81   80   82                                                       
CONECT   82   81   83                                                       
CONECT   83   82                                                            
CONECT   84   72   85                                                       
CONECT   85   84   86   87                                                  
CONECT   86   85                                                            
CONECT   87   85   88                                                       
CONECT   88   87   89                                                       
CONECT   89   88   90                                                       
CONECT   90   89   91                                                       
CONECT   91   90   92                                                       
CONECT   92   91   93                                                       
CONECT   93   92   94                                                       
CONECT   94   93   95                                                       
CONECT   95   94   96                                                       
CONECT   96   95   97                                                       
CONECT   97   96                                                            
CONECT   98   67   99  131                                                  
CONECT   99   98  100                                                       
CONECT  100   99  101  102                                                  
CONECT  101  100                                                            
CONECT  102  100  103                                                       
CONECT  103  102  104  115                                                  
CONECT  104  103  105                                                       
CONECT  105  104  106                                                       
CONECT  106  105  107                                                       
CONECT  107  106  108                                                       
CONECT  108  107  109                                                       
CONECT  109  108  110                                                       
CONECT  110  109  111                                                       
CONECT  111  110  112                                                       
CONECT  112  111  113                                                       
CONECT  113  112  114                                                       
CONECT  114  113                                                            
CONECT  115  103  116                                                       
CONECT  116  115  117  118                                                  
CONECT  117  116                                                            
CONECT  118  116  119                                                       
CONECT  119  118  120                                                       
CONECT  120  119  121                                                       
CONECT  121  120  122                                                       
CONECT  122  121  123                                                       
CONECT  123  122  124                                                       
CONECT  124  123  125                                                       
CONECT  125  124  126                                                       
CONECT  126  125  127                                                       
CONECT  127  126  128                                                       
CONECT  128  127  129                                                       
CONECT  129  128  130                                                       
CONECT  130  129                                                            
CONECT  131   98   16  132                                                  
CONECT  132  131  133                                                       
CONECT  133  132  134  135  136                                             
CONECT  134  133                                                            
CONECT  135  133                                                            
CONECT  136  133                                                            
CONECT  137   13  138                                                       
CONECT  138  137  139  140  144                                             
CONECT  139  138                                                            
CONECT  140  138  141  142                                                  
CONECT  141  140                                                            
CONECT  142  140  143                                                       
CONECT  143  142                                                            
CONECT  144  138   11  145                                                  
CONECT  145  144  146                                                       
CONECT  146  145  147  198                                                  
CONECT  147  146  148                                                       
CONECT  148  147  149  153                                                  
CONECT  149  148  150  151                                                  
CONECT  150  149                                                            
CONECT  151  149  152                                                       
CONECT  152  151                                                            
CONECT  153  148  154  159                                                  
CONECT  154  153  155                                                       
CONECT  155  154  156  157  158                                             
CONECT  156  155                                                            
CONECT  157  155                                                            
CONECT  158  155                                                            
CONECT  159  153  160  198                                                  
CONECT  160  159  161                                                       
CONECT  161  160  162  196                                                  
CONECT  162  161  163                                                       
CONECT  163  162  164  181                                                  
CONECT  164  163  165  166                                                  
CONECT  165  164                                                            
CONECT  166  164  167                                                       
CONECT  167  166  168                                                       
CONECT  168  167  169  179                                                  
CONECT  169  168  170                                                       
CONECT  170  169  171  175                                                  
CONECT  171  170  172  173                                                  
CONECT  172  171                                                            
CONECT  173  171  174                                                       
CONECT  174  173                                                            
CONECT  175  170  176  177                                                  
CONECT  176  175                                                            
CONECT  177  175  178  179                                                  
CONECT  178  177                                                            
CONECT  179  177  168  180                                                  
CONECT  180  179                                                            
CONECT  181  163  182  183                                                  
CONECT  182  181                                                            
CONECT  183  181  184  196                                                  
CONECT  184  183  185                                                       
CONECT  185  184  186  194                                                  
CONECT  186  185  187                                                       
CONECT  187  186  188  190                                                  
CONECT  188  187  189                                                       
CONECT  189  188                                                            
CONECT  190  187  191  192                                                  
CONECT  191  190                                                            
CONECT  192  190  193  194                                                  
CONECT  193  192                                                            
CONECT  194  192  185  195                                                  
CONECT  195  194                                                            
CONECT  196  183  161  197                                                  
CONECT  197  196                                                            
CONECT  198  159  146  199                                                  
CONECT  199  198                                                            
CONECT  200   13  201  202                                                  
CONECT  201  200                                                            
CONECT  202  200                                                            
CONECT  203    4  204  205                                                  
CONECT  204  203                                                            
CONECT  205  203                                                            
CONECT  206    2  207  208                                                  
CONECT  207  206                                                            
CONECT  208  206  209                                                       
CONECT  209  208                                                            
MASTER        0    0    0    0    0    0    0    0  209    0  432    0
END

Synonyms

Value	Source
Glucosyl-(heptosyl)3-kdo2-lipid a-phosphoric acid	Generator

Molecular Formula

C₁₃₇H₂₄₁N₂O₆₅P₃

Average Mass

3049.31

Monoisotopic Mass

3047.487105701

IUPAC Name

(2R,4R,5R,6R)-2-{[(2R,4R,5R,6R)-2-carboxylato-6-[(1R)-1,2-dihydroxyethyl]-5-{[(2S,3S,4R,5R,6R)-6-[(1S)-1,2-dihydroxyethyl]-4-{[(2R,3S,4S,5R,6R)-6-[(1S)-2-{[(3S,4S,5S,6R)-6-[(1S)-1,2-dihydroxyethyl]-3,4,5-trihydroxyoxan-2-yl]oxy}-1-hydroxyethyl]-3,5-dihydroxy-4-{[(3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}oxan-2-yl]oxy}-3-hydroxy-5-(phosphonatooxy)oxan-2-yl]oxy}-2-{[(2R,3S,4R,5R,6R)-5-[(3R)-3-(dodecanoyloxy)tetradecanamido]-6-{[(2R,3S,4R,5R,6R)-3-hydroxy-5-[(3R)-3-hydroxytetradecanamido]-4-{[(3R)-3-hydroxytetradecanoyl]oxy}-6-(phosphonatooxy)oxan-2-yl]methoxy}-3-(phosphonatooxy)-4-{[(3R)-3-(tetradecanoyloxy)tetradecanoyl]oxy}oxan-2-yl]methoxy}oxan-4-yl]oxy}-6-[(1R)-1,2-dihydroxyethyl]-4,5-dihydroxyoxane-2-carboxylate

Traditional Name

CAS Registry Number

Not Available

SMILES

[H][C@@]1(O[C@@](C[C@@H](O)[C@H]1O)(O[C@@H]1C[C@@](OC[C@H]2O[C@@H](OC[C@H]3O[C@H](OP([O-])([O-])=O)[C@H](NC(=O)C[C@H](O)CCCCCCCCCCC)[C@@H](OC(=O)C[C@H](O)CCCCCCCCCCC)[C@@H]3O)[C@H](NC(=O)C[C@@H](CCCCCCCCCCC)OC(=O)CCCCCCCCCCC)[C@@H](OC(=O)C[C@@H](CCCCCCCCCCC)OC(=O)CCCCCCCCCCCCC)[C@@H]2OP([O-])([O-])=O)(O[C@]([H])([C@H](O)CO)[C@@H]1O[C@H]1O[C@H]([C@@H](O)CO)[C@@H](OP([O-])([O-])=O)[C@H](O[C@H]2O[C@H]([C@@H](O)COC3O[C@H]([C@@H](O)CO)[C@@H](O)[C@H](O)[C@@H]3O)[C@@H](O)[C@H](OC3O[C@H](CO)[C@@H](O)[C@H](O)[C@H]3O)[C@@H]2O)[C@@H]1O)C([O-])=O)C([O-])=O)[C@H](O)CO

InChI Identifier

InChI=1S/C137H249N2O65P3/c1-7-13-19-25-31-37-38-44-50-56-62-68-100(156)187-86(66-60-54-48-42-35-29-23-17-11-5)72-102(158)192-124-104(139-98(154)71-85(65-59-53-47-41-34-28-22-16-10-4)186-99(155)67-61-55-49-43-36-30-24-18-12-6)128(184-81-95-107(161)123(191-101(157)70-84(146)64-58-52-46-40-33-27-21-15-9-3)103(129(189-95)204-207(180,181)182)138-97(153)69-83(145)63-57-51-45-39-32-26-20-14-8-2)190-96(122(124)202-205(174,175)176)82-185-136(134(170)171)74-93(199-137(135(172)173)73-87(147)105(159)118(200-137)89(149)76-141)121(120(201-136)91(151)78-143)196-133-115(169)126(127(203-206(177,178)179)119(195-133)90(150)77-142)198-132-114(168)125(197-131-112(166)108(162)106(160)94(79-144)188-131)113(167)117(194-132)92(152)80-183-130-111(165)109(163)110(164)116(193-130)88(148)75-140/h83-96,103-133,140-152,159-169H,7-82H2,1-6H3,(H,138,153)(H,139,154)(H,170,171)(H,172,173)(H2,174,175,176)(H2,177,178,179)(H2,180,181,182)/p-8/t83-,84-,85-,86-,87-,88+,89-,90+,91-,92+,93-,94-,95-,96-,103-,104-,105-,106-,107?,108+,109+,110+,111+,112-,113-,114+,115+,116-,117-,118-,119-,120-,121-,122-,123-,124-,125+,126-,127-,128-,129-,130?,131?,132-,133-,136-,137-/m1/s1

InChI Key

QHKUHEQURQLSFA-QCNSDWGJSA-F

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as saccharolipids. Saccharolipids are compounds in which fatty acids are linked directly to a sugar backbone, forming structures that are compatible with membrane bilayers. In the saccharolipids, a sugar substitutes for the glycerol backbone that is present in glycerolipids and glycerophospholipids. The most familiar saccharolipids contain an acylated glucosamine. In contrast to others glycolipids, the fatty acid is not glycosidically linked to the sugar moiety.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Saccharolipids

Sub Class

Not Available

Direct Parent

Saccharolipids

Alternative Parents

Substituents

Oligosaccharide phosphate
Oligosaccharide
Hexacarboxylic acid or derivatives
Saccharolipid
Hexose phosphate
N-acyl-alpha-hexosamine
Fatty acyl glycoside
C-glucuronide
Alkyl glycoside
O-glycosyl compound
Glycosyl compound
C-glycosyl compound
Ketal
Monoalkyl phosphate
Fatty acid ester
Beta-hydroxy acid
Fatty acyl
Alkyl phosphate
Pyran
Phosphoric acid ester
Oxane
Organic phosphoric acid derivative
Hydroxy acid
Secondary alcohol
Carboxylic acid ester
Oxacycle
Organoheterocyclic compound
Polyol
Carboxylic acid
Carboxylic acid derivative
Carboximidic acid derivative
Carboximidic acid
Acetal
Organic nitrogen compound
Organic oxygen compound
Organopnictogen compound
Organic oxide
Hydrocarbon derivative
Primary alcohol
Organooxygen compound
Organonitrogen compound
Carbonyl group
Alcohol
Organic anion
Aliphatic heteromonocyclic compound

Molecular Framework

Aliphatic heteromonocyclic compounds

External Descriptors

Not Available

Functional Ontology

Not Available

Physical Properties

State

Expected Solid

Predicted Properties

Property	Value	Source
Water Solubility	0.81 g/L	ALOGPS
logP	2.58	ALOGPS
logP	11.9	ChemAxon
logS	-3.6	ALOGPS
pKa (Strongest Acidic)	0.31	ChemAxon
Physiological Charge	-8	ChemAxon
Hydrogen Acceptor Count	58	ChemAxon
Hydrogen Donor Count	26	ChemAxon
Polar Surface Area	1084.89 Å²	ChemAxon
Rotatable Bond Count	115	ChemAxon
Refractivity	736.95 m³·mol⁻¹	ChemAxon
Polarizability	321.02 Å³	ChemAxon
Number of Rings	8	ChemAxon
Bioavailability	No	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	Yes	ChemAxon

Spectra

Not Available

Chromatographic Retention Times and Retention Indices

Retention Times

Chromatography Type	Technique	Column	Deposition Date	Retention Time (s)
Liquid Chromatography	HILIC	Waters Acquity UPLC-BEH Amide column (eluted)	2025-10-23	1277.6
Liquid Chromatography	HILIC	Accucore 150 Amide HILIC (eluted)	2025-10-23	343.8
Liquid Chromatography	Reversed-phase	Hypersil Gold 1.9 µm C18 (eluted)	2025-10-23	2435.0
Liquid Chromatography	Reversed-phase	Agilent Zorbax Eclipse Plus C18 (2.1 mm x 150 mm, 3.5 um) (eluted)	2025-10-23	2286.0
Liquid Chromatography	Reversed-phase	XBridge C18 3.5u 2.1x50 mm (eluted)	2025-10-23	1998.5
Liquid Chromatography	Reversed-phase	Ascentis Express C18 (eluted)	2025-10-23	82.6
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC HSS T3 C18 (retained)	2025-10-23	12411.4
Liquid Chromatography	HILIC	Merck SeQuant ZIC-HILIC (eluted)	2025-10-23	1550.8
Liquid Chromatography	HILIC	Merck SeQuant ZIC-pHILIC (eluted)	2025-10-23	379.2
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC HSS T3 C18 (eluted)	2025-10-23	1347.6
Liquid Chromatography	HILIC	Merck SeQuant ZIC-HILIC (eluted)	2025-10-23	29.9
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC HSS T3 C18 (eluted)	2025-10-23	250.0
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC BEH C18 (eluted)	2025-10-23	673.3
Liquid Chromatography	HILIC	Merck SeQuant ZIC-pHILIC column (eluted)	2025-10-23	18.9
Liquid Chromatography	HILIC	Merck SeQuant ZIC-pHILIC column (void)	2025-10-23	124.9
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC BEH C18 (eluted)	2025-10-23	983.1
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC BEH C18 (void)	2025-10-23	1474.9
Liquid Chromatography	Reversed-phase	Kinetex Core-Shell C18 2.6 um, 3.0 x 100 mm, Phenomenex (eluted)	2025-10-23	5901.6
Liquid Chromatography	Reversed-phase	Waters Atlantis T3 (2.1 x 150 mm, 5 um) (eluted)	2025-10-23	4242.5

Retention Indices

Not Available

Biological Properties

Cellular Locations

Not Available

Biospecimen Locations

Not Available

Tissue Locations

Not Available

Associated OMIM IDs

114500 (Colorectal cancer)
610247 (Eosinophilic esophagitis)

Human Proteins and Enzymes

Protein ID	Protein Name	Protein Type	Uniprot ID	Species

Human Pathways

Pathways

Name	SMPDB/PathBank

Microbial Pathways

Pathways

This table shows at most 5 pathways. For the full list of associated pathways:

See All Associated Bacterial Pathways

Name	SMPDB/PathBank	Species
Lipopolysaccharide Biosynthesis		Escherichia coli UTI89 Escherichia coli 55989 Escherichia coli SE11 Klebsiella pneumoniae Salmonella enterica Citrobacter koseri Proteus mirabilis Shigella boydii Sodalis glossinidius Escherichia albertii Bacteroides fluxus Klebsiella variicola Actinobacillus pleuropneumoniae serovar 3 str. JL03 Citrobacter koseri ATCC BAA-895 Enterobacter cloacae subsp. cloacae ATCC 13047 Escherichia coli O127:H6 str. E2348/69 Escherichia coli ED1a Klebsiella pneumoniae subsp. pneumoniae MGH 78578 Pseudomonas fluorescens Pf0-1 Salmonella enterica subsp. enterica serovar Typhimurium str. LT2 Salmonella enterica subsp. enterica serovar Newport str. SL254 Salmonella enterica subsp. enterica serovar Heidelberg str. SL476 Salmonella enterica subsp. enterica serovar Agona str. SL483 Salmonella enterica subsp. enterica serovar Dublin str. CT02021853 Bacteroides fluxus YIT 12057 Laribacter hongkongensis Cedecea davisae Cedecea davisae DSM 4568 Citrobacter amalonaticus Citrobacter amalonaticus Y19 Escherichia albertii TW07627 Salmonella Salmonella enterica subsp. enterica serovar Typhimurium Tatumella ptyseos Tatumella ptyseos ATCC 33301 Hafnia alvei Hafnia alvei ATCC 51873 Providencia rustigianii DSM 4541 Serratia marcescens subsp. marcescens Db11 Klebsiella aerogenes KCTC 2190 Citrobacter rodentium ICC168 Cronobacter turicensis z3032 Erwinia tasmaniensis Et1/99 Erwinia amylovora CFBP1430 Methylobacillus flagellatus KT Sodalis glossinidius str. 'morsitans' Psychromonas ingrahamii 37 Salmonella enterica subsp. enterica serovar Paratyphi A str. Klebsiella michiganensis KCTC 1686
Lipopolysaccharide Biosynthesis (1-Octadecanoyl-rac-glycerol)		Escherichia coli SMS-3-5 Escherichia coli UTI89 Escherichia coli 55989 Escherichia coli SE11 Klebsiella pneumoniae Pseudomonas fluorescens Pf-5 Salmonella enterica Campylobacter fetus subsp. fetus 82-40 Campylobacter rectus Pseudomonas fluorescens Pseudomonas putida Citrobacter koseri Proteus mirabilis Shigella boydii Campylobacter upsaliensis Helicobacter pullorum Escherichia albertii Klebsiella variicola Actinobacillus pleuropneumoniae serovar 3 str. JL03 Citrobacter koseri ATCC BAA-895 Enterobacter cloacae subsp. cloacae ATCC 13047 Escherichia coli O127:H6 str. E2348/69 Escherichia coli ED1a Klebsiella pneumoniae subsp. pneumoniae MGH 78578 Pseudomonas putida KT2440 Pseudomonas fluorescens Pf0-1 Pseudomonas fluorescens SBW25 Salmonella enterica subsp. enterica serovar Typhimurium str. LT2 Salmonella enterica subsp. enterica serovar Newport str. SL254 Salmonella enterica subsp. enterica serovar Heidelberg str. SL476 Salmonella enterica subsp. enterica serovar Agona str. SL483 Salmonella enterica subsp. enterica serovar Dublin str. CT02021853 Stenotrophomonas maltophilia R551-3 Cetobacterium somerae ATCC BAA-474 Parasutterella excrementihominis YIT 11859 Campylobacter rectus RM3267 Campylobacter upsaliensis JV21 Helicobacter pullorum MIT 98-5489 Aeromonas veronii Cedecea davisae Cedecea davisae DSM 4568 Citrobacter amalonaticus Citrobacter amalonaticus Y19 Escherichia albertii TW07627 Salmonella Salmonella enterica subsp. enterica serovar Typhimurium Tatumella ptyseos Tatumella ptyseos ATCC 33301 Hafnia alvei Hafnia alvei ATCC 51873 Providencia rustigianii DSM 4541 Klebsiella aerogenes KCTC 2190 Azotobacter vinelandii DJ
Lipopolysaccharide Biosynthesis (1,2-Diacyl-sn-glycerol (dihexadec-9-enoyl, n-C16:1))		Escherichia coli SMS-3-5 Escherichia coli UTI89 Escherichia coli 55989 Escherichia coli SE11 Klebsiella pneumoniae Pseudomonas fluorescens Pf-5 Salmonella enterica Campylobacter fetus subsp. fetus 82-40 Campylobacter rectus Pseudomonas fluorescens Pseudomonas putida Citrobacter koseri Proteus mirabilis Shigella boydii Campylobacter upsaliensis Helicobacter pullorum Escherichia albertii Klebsiella variicola Actinobacillus pleuropneumoniae serovar 3 str. JL03 Citrobacter koseri ATCC BAA-895 Enterobacter cloacae subsp. cloacae ATCC 13047 Escherichia coli O127:H6 str. E2348/69 Escherichia coli ED1a Klebsiella pneumoniae subsp. pneumoniae MGH 78578 Pseudomonas putida KT2440 Pseudomonas fluorescens Pf0-1 Pseudomonas fluorescens SBW25 Salmonella enterica subsp. enterica serovar Typhimurium str. LT2 Salmonella enterica subsp. enterica serovar Newport str. SL254 Salmonella enterica subsp. enterica serovar Heidelberg str. SL476 Salmonella enterica subsp. enterica serovar Agona str. SL483 Salmonella enterica subsp. enterica serovar Dublin str. CT02021853 Stenotrophomonas maltophilia R551-3 Cetobacterium somerae ATCC BAA-474 Parasutterella excrementihominis YIT 11859 Campylobacter rectus RM3267 Campylobacter upsaliensis JV21 Helicobacter pullorum MIT 98-5489 Aeromonas veronii Cedecea davisae Cedecea davisae DSM 4568 Citrobacter amalonaticus Citrobacter amalonaticus Y19 Escherichia albertii TW07627 Salmonella Salmonella enterica subsp. enterica serovar Typhimurium Tatumella ptyseos Tatumella ptyseos ATCC 33301 Hafnia alvei Hafnia alvei ATCC 51873 Providencia rustigianii DSM 4541 Klebsiella aerogenes KCTC 2190 Azotobacter vinelandii DJ
Lipopolysaccharide Biosynthesis (1,2-Diacyl-sn-glycerol (dioctadec-11-enoyl, n-C18:1))		Escherichia coli SMS-3-5 Escherichia coli UTI89 Escherichia coli 55989 Escherichia coli SE11 Klebsiella pneumoniae Pseudomonas fluorescens Pf-5 Salmonella enterica Campylobacter fetus subsp. fetus 82-40 Campylobacter rectus Pseudomonas fluorescens Pseudomonas putida Citrobacter koseri Proteus mirabilis Shigella boydii Campylobacter upsaliensis Helicobacter pullorum Escherichia albertii Klebsiella variicola Actinobacillus pleuropneumoniae serovar 3 str. JL03 Citrobacter koseri ATCC BAA-895 Enterobacter cloacae subsp. cloacae ATCC 13047 Escherichia coli O127:H6 str. E2348/69 Escherichia coli ED1a Klebsiella pneumoniae subsp. pneumoniae MGH 78578 Pseudomonas putida KT2440 Pseudomonas fluorescens Pf0-1 Pseudomonas fluorescens SBW25 Salmonella enterica subsp. enterica serovar Typhimurium str. LT2 Salmonella enterica subsp. enterica serovar Newport str. SL254 Salmonella enterica subsp. enterica serovar Heidelberg str. SL476 Salmonella enterica subsp. enterica serovar Agona str. SL483 Salmonella enterica subsp. enterica serovar Dublin str. CT02021853 Stenotrophomonas maltophilia R551-3 Cetobacterium somerae ATCC BAA-474 Parasutterella excrementihominis YIT 11859 Campylobacter rectus RM3267 Campylobacter upsaliensis JV21 Helicobacter pullorum MIT 98-5489 Aeromonas veronii Cedecea davisae Cedecea davisae DSM 4568 Citrobacter amalonaticus Citrobacter amalonaticus Y19 Escherichia albertii TW07627 Salmonella Salmonella enterica subsp. enterica serovar Typhimurium Tatumella ptyseos Tatumella ptyseos ATCC 33301 Hafnia alvei Hafnia alvei ATCC 51873 Providencia rustigianii DSM 4541 Klebsiella aerogenes KCTC 2190 Azotobacter vinelandii DJ
Lipopolysaccharide Biosynthesis (1,2-Diacyl-sn-glycerol (ditetradec-7-enoyl, n-C14:1))		Escherichia coli SMS-3-5 Escherichia coli UTI89 Escherichia coli 55989 Escherichia coli SE11 Klebsiella pneumoniae Pseudomonas fluorescens Pf-5 Salmonella enterica Campylobacter fetus subsp. fetus 82-40 Campylobacter rectus Pseudomonas fluorescens Pseudomonas putida Citrobacter koseri Proteus mirabilis Shigella boydii Campylobacter upsaliensis Helicobacter pullorum Escherichia albertii Klebsiella variicola Actinobacillus pleuropneumoniae serovar 3 str. JL03 Citrobacter koseri ATCC BAA-895 Enterobacter cloacae subsp. cloacae ATCC 13047 Escherichia coli O127:H6 str. E2348/69 Escherichia coli ED1a Klebsiella pneumoniae subsp. pneumoniae MGH 78578 Pseudomonas putida KT2440 Pseudomonas fluorescens Pf0-1 Pseudomonas fluorescens SBW25 Salmonella enterica subsp. enterica serovar Typhimurium str. LT2 Salmonella enterica subsp. enterica serovar Newport str. SL254 Salmonella enterica subsp. enterica serovar Heidelberg str. SL476 Salmonella enterica subsp. enterica serovar Agona str. SL483 Salmonella enterica subsp. enterica serovar Dublin str. CT02021853 Stenotrophomonas maltophilia R551-3 Cetobacterium somerae ATCC BAA-474 Parasutterella excrementihominis YIT 11859 Campylobacter rectus RM3267 Campylobacter upsaliensis JV21 Helicobacter pullorum MIT 98-5489 Aeromonas veronii Cedecea davisae Cedecea davisae DSM 4568 Citrobacter amalonaticus Citrobacter amalonaticus Y19 Escherichia albertii TW07627 Salmonella Salmonella enterica subsp. enterica serovar Typhimurium Tatumella ptyseos Tatumella ptyseos ATCC 33301 Hafnia alvei Hafnia alvei ATCC 51873 Providencia rustigianii DSM 4541 Klebsiella aerogenes KCTC 2190 Azotobacter vinelandii DJ

Metabolic Reactions

Reactions

This table shows at most 20 reactions. For the full list of associated reactions:

See All Associated Reactions

Reaction ID	Precursor	Product	Enzyme	Reaction Type	Data Source	Reference
MMDBr0018392	ADP-L-glycero-beta-D-manno-heptose	glucosyl-(heptosyl)3-Kdo2-lipid A-phosphate	Lipopolysaccharide core heptosyltransferase rfaQ		PathBank	31602464
MMDBr0018393	glucosyl-(heptosyl)3-Kdo2-lipid A-phosphate	glucosyl-(heptosyl)3-Kdo2-lipid A-bisphosphate	Lipopolysaccharide core heptose(II) kinase rfaY	Phosphorylation	PathBank	31602464

Health Effects and Bioactivity

Health Outcome/Bioactivity	Metabolite Response/Effect	Evidence Type	Host and Biospecimen	Data Source	Reference

Microbial Sources

Superkingdom/Kingdom	Phylum	Total species	Hosts and Body Sites	Microbial Links
Bacteria/Eubacteria	Proteobacteria	1	Human ; Human feces; Human feces; pleural fluid plaque; bal	Unknown

Exposure Sources

Other Exposures

Source Type	Data Source	Reference

Host Biospecimen and Location

Host and Biospecimen	Status	Mean	Std	Min	Max	Units	Age	Sex	Health Condition	Data Source	Reference

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FooDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

Not Available

PDB ID

Not Available

ChEBI ID

Not Available

Food Biomarker Ontology

Not Available

CMMC Knowledgebase

Not Available

General References

Wishart DS, Li C, Marcu A, Badran H, Pon A, Budinski Z, Patron J, Lipton D, Cao X, Oler E, Li K, Paccoud M, Hong C, Guo AC, Chan C, Wei W, Ramirez-Gaona M: PathBank: a comprehensive pathway database for model organisms. Nucleic Acids Res. 2020 Jan 8;48(D1):D470-D478. doi: 10.1093/nar/gkz861. [PubMed:31602464 ]

Showing metabocard for glucosyl-(heptosyl)3-Kdo2-lipid A-phosphate (MMDBc0032143)

MOL for #<Metabolite:0x00007f2dfc20dd08>

3D MOL for #<Metabolite:0x00007f2dfc20dd08>

3D SDF for #<Metabolite:0x00007f2dfc20dd08>

3D-SDF for #<Metabolite:0x00007f2dfc20dd08>

PDB for #<Metabolite:0x00007f2dfc20dd08>

3D PDB for #<Metabolite:0x00007f2dfc20dd08>

SMILES for #<Metabolite:0x00007f2dfc20dd08>

INCHI for #<Metabolite:0x00007f2dfc20dd08>

Structure for #<Metabolite:0x00007f2dfc20dd08>

3D Structure for #<Metabolite:0x00007f2dfc20dd08>