MiMeDB: Showing metabocard for dTDP-beta-L-rhamnose (MMDBc0054471)

Microbial

Pharmaceutical

Xenobiotic

Record Information

Version

2.0

Status

Detected and Quantified

Creation Date

2022-06-05 23:14:17 UTC

Update Date

2024-10-13 09:35:38 UTC

Metabolite ID

MMDBc0054471

Metabolite Identification

Common Name

dTDP-beta-L-rhamnose

Description

Deoxythymidine diphosphate-L-rhamnose (dTDP-L-rhamnose) is the precursor of L-rhamnose, a saccharide required for the virulence of some pathogenic bacteria. In gram-negative bacteria such as Salmonella enterica, Vibrio cholerae, or Escherichia coli 075:K5, L-rhamnose is an important residue in the O-antigen of lipopolysaccharides, which are essential for resistance to serum killing and colonization. In gram-positive bacteria such as streptococci, the capsule is a recognized virulence factor. For example, L-rhamnose is known to be present in the capsule of Streptococcus suis, a causative agent of meningitis in humans. In Streptococcus mutans, L-rhamnose containing polysaccharides have been implicated in tooth surface colonization and adherence to kidney, muscle, and heart tissues. In mycobacteria, L-rhamnose is fundamental to the structural integrity of the cell wall since it connects the inner peptidoglycan layer to the arabinogalactan polysaccharides. dTDP-L-rhamnose is synthesized from glucose-1-phosphate and deoxythymidine triphosphate (dTTP) via a pathway involving four distinct enzymes. Whereas common sugars such as glucose, fructose, and mannose are all D-configured, bacteria commonly utilize the L-configured carbohydrates in pharmacologically active compounds and their cell-wall structures. The bacterial cell wall is unique to bacteria; neither the cell wall nor the enzymes and chemical intermediates in its formation have analogues in humans. The enzymes involved in dTDP-L-rhamnose synthesis are potential targets for the design of new therapeutic agents (PMID: 10802738 , 12773151 ).

Structure

MOL SDF PDB SMILES InChI

Synonyms

Not Available

Molecular Formula

C₁₆H₂₆N₂O₁₅P₂

Average Mass

548.3296

Monoisotopic Mass

548.080841196

IUPAC Name

Not Available

Traditional Name

Not Available

CAS Registry Number

Not Available

SMILES

Not Available

InChI Identifier

InChI=1S/C16H26N2O15P2/c1-6-4-18(16(24)17-14(6)23)10-3-8(19)9(31-10)5-29-34(25,26)33-35(27,28)32-15-13(22)12(21)11(20)7(2)30-15/h4,7-13,15,19-22H,3,5H2,1-2H3,(H,25,26)(H,27,28)(H,17,23,24)/t7-,8-,9+,10+,11-,12+,13+,15+/m0/s1

InChI Key

ZOSQFDVXNQFKBY-CGAXJHMRSA-N

Chemical Taxonomy

Functional Ontology

Not Available

Physical Properties

State

Expected Solid

Predicted Properties

Not Available

Spectra

Not Available

Chromatographic Retention Times and Retention Indices

Retention Times

Chromatography Type	Technique	Column	Deposition Date	Retention Time (s)
Liquid Chromatography	HILIC	Waters Acquity UPLC-BEH Amide column (eluted)	2025-10-24	606.3
Liquid Chromatography	HILIC	Accucore 150 Amide HILIC (eluted)	2025-10-24	437.4
Liquid Chromatography	Reversed-phase	Hypersil Gold 1.9 µm C18 (eluted)	2025-10-24	242.8
Liquid Chromatography	Reversed-phase	Agilent Zorbax Eclipse Plus C18 (2.1 mm x 150 mm, 3.5 um) (eluted)	2025-10-24	337.6
Liquid Chromatography	Reversed-phase	XBridge C18 3.5u 2.1x50 mm (eluted)	2025-10-24	306.9
Liquid Chromatography	Reversed-phase	Ascentis Express C18 (eluted)	2025-10-24	200.4
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC HSS T3 C18 (eluted)	2025-10-24	572.5
Liquid Chromatography	HILIC	Merck SeQuant ZIC-HILIC (eluted)	2025-10-24	613.8
Liquid Chromatography	HILIC	Merck SeQuant ZIC-pHILIC (eluted)	2025-10-24	373.3
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC HSS T3 C18 (eluted)	2025-10-24	153.1
Liquid Chromatography	HILIC	Merck SeQuant ZIC-HILIC (eluted)	2025-10-24	270.0
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC HSS T3 C18 (eluted)	2025-10-24	172.2
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC BEH C18 (eluted)	2025-10-24	56.4
Liquid Chromatography	HILIC	Merck SeQuant ZIC-pHILIC column (eluted)	2025-10-24	522.8
Liquid Chromatography	HILIC	Merck SeQuant ZIC-pHILIC column (eluted)	2025-10-24	695.5
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC BEH C18 (eluted)	2025-10-24	57.3
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC BEH C18 (eluted)	2025-10-24	265.0
Liquid Chromatography	Reversed-phase	Kinetex Core-Shell C18 2.6 um, 3.0 x 100 mm, Phenomenex (eluted)	2025-10-24	709.6
Liquid Chromatography	Reversed-phase	Waters Atlantis T3 (2.1 x 150 mm, 5 um) (eluted)	2025-10-24	595.4

Retention Indices

Chromatography Type	Peak Label	SMILES	Stationary Phase	Deposition Date	Retention Index
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_1	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	2291.67
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_2	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	2582.66
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_3	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	2793.27
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_4	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	1929.06
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_5	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	1776.54
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_6	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	919.448
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_7	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	3763.93
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_8	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	1781.63
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_9	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	2264.34
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_10	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	1722.04
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_11	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	2991.38
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_12	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	1321.14
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_13	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	2073.33
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_14	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	535.337
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_15	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	1555.69
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_16	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	1655.77
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_17	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	2939.07
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_18	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	1968.38
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_19	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	946.898
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_20	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	2281.96
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_21	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	2924.25
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_22	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	1475.13
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_23	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	1725.89
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_24	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	1087.98
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_25	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	1862.74
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_26	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	965.931
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_27	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	2045.86
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_28	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	2676.16
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_29	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	2426.29
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_30	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	1582.09
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_31	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	3165.52
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_32	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	1424.27
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_33	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	1546.24
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_34	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	2348.66
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_35	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	1489.44
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_36	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	2315.23
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_37	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	1765.8
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_38	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	696.84
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_39	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	1696.2
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_40	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	2345.22
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_41	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	3240.69
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_42	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	1899.8
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_43	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	2424.1
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_44	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	989.639
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_45	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	2327.44
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_46	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	1262.4
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_47	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	2569.01
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_48	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	2207.17
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_49	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	2175.89
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_50	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	2027.18
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_51	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	2554.66
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_52	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	2255.51
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_53	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	532.557
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_54	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	2204.14
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_55	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	3069.45
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_56	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	2012.49
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_57	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	2007.98
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_58	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	1572.83
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_59	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	1967.14
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_60	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	1635.91
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_61	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	2162.84
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_62	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	2674.3
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_63	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	2697.45
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_64	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	2008.73
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_65	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	1520.02
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_66	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	1141.85
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_67	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	2529.39
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_68	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	1151.3
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_69	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	3036.77
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_70	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	2754.46
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_71	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	2738.84
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_72	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	2607.5
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_73	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	912.842
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_74	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	2601.51
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_75	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	1787.38
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_76	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	1981.5
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_77	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	2972.98
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_78	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	1522.84
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_79	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	1788.64
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_80	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	210.4
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_81	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	2820.25
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_82	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	2518.98
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_83	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	1871.19
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_84	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	1831.7
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_85	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	1540.84
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_86	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	2251.76
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_87	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	1967.23
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_88	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	2153.73
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_89	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	3435.81
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_90	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	1913.3
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_91	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	157.402
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_92	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	2440.26
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_93	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	1252.31
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_94	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard non polar	2025-10-24	3093.72
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_95	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	1818.77
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_96	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	1384.13
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_97	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	2391.19
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_98	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard non polar	2025-10-24	1869.85
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_1	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2933.66
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_2	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	1977.03
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_3	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2565.05
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_4	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2155.15
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_5	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2019.57
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_6	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2399.38
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_7	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	2966.6
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_8	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2172.87
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_9	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	1840.21
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_10	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2145.82
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_11	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	1746.67
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_12	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	1758.88
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_13	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	798.85
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_14	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2789.81
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_15	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2149.2
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_16	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2798.99
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_17	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2366.23
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_18	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	2226.37
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_19	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2411.83
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_20	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2879.8
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_21	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	1961.3
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_22	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	2143.37
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_23	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	1214.48
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_24	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2362.62
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_25	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	891.558
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_26	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2105.31
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_27	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	1039.61
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_28	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	2745.76
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_29	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2633.04
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_30	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2504.77
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_31	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	4548.46
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_32	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2282.75
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_33	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	1649.61
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_34	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2517.68
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_35	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	1554.41
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_36	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	1765.0
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_37	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	1472.97
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_38	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	929.447
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_39	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2553.85
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_40	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	2756.92
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_41	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	1595.95
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_42	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	2157.35
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_43	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	1096.22
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_44	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	1569.92
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_45	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	1719.33
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_46	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2866.16
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_47	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	898.319
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_48	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	1374.1
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_49	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	3163.64
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_50	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	2163.71
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_51	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2347.33
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_52	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	977.498
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_53	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	2917.58
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_54	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2138.31
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_55	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2930.05
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_56	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	2034.08
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_57	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	861.934
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_58	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	2470.72
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_59	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	2147.48
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_60	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2712.06
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_61	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	2702.38
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_62	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	3296.8
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_63	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	2112.94
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_64	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	1091.9
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_65	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2018.99
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_66	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	1266.7
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_67	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	2340.93
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_68	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	1676.33
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_69	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	1300.51
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_70	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	2689.69
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_71	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2721.02
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_72	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	2676.23
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_73	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	1809.31
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_74	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2382.26
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_75	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	1364.61
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_76	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	3165.23
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_77	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2395.17
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_78	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	-146.016
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_79	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	1210.01
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_80	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	1775.21
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_81	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	2736.63
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_82	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	800.369
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_83	CC1=CN([C@H]2C[C@H](O[Si](C)(C)C)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	808.455
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_84	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	1706.57
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_85	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2541.61
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_86	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	823.421
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_87	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2076.46
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_88	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	2825.57
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_89	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	2515.51
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_90	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	846.56
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_91	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	1304.29
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_92	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	2591.06
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_93	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O)[C@H]3O[Si](C)(C)C)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	1016.29
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_94	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O)O[Si](C)(C)C)O2)C(=O)[NH]C1=O	standard polar	2025-10-24	2844.49
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_95	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O)O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	2518.95
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_96	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H]3O)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	1200.86
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_97	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O)[C@@H](O[Si](C)(C)C)[C@H]3O)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	898.878
Gas Chromatography	dTDP-beta-L-rhamnose_TMS_98	CC1=CN([C@H]2C[C@H](O)[C@@H](COP(=O)(O[Si](C)(C)C)OP(=O)(O[C@H]3O[C@@H](C)[C@H](O[Si](C)(C)C)[C@@H](O)[C@H]3O)O[Si](C)(C)C)O2)C(=O)N([Si](C)(C)C)C1=O	standard polar	2025-10-24	665.666

Biological Properties

Cellular Locations

Cytoplasm

Biospecimen Locations

Not Available

Tissue Locations

Not Available

Associated OMIM IDs

114500 (Colorectal cancer)
610247 (Eosinophilic esophagitis)

Human Proteins and Enzymes

Protein ID	Protein Name	Protein Type	Uniprot ID	Species

Human Pathways

Pathways

Name	SMPDB/PathBank

Microbial Pathways

Pathways

Not Available

Metabolic Reactions

Reactions

This table shows at most 20 reactions. For the full list of associated reactions:

See All Associated Reactions

Reaction ID	Precursor	Product	Enzyme	Reaction Type	Data Source	Reference
MMDBr0019344	dTDP-4-dehydro-beta-L-rhamnose	dTDP-beta-L-rhamnose	dTDP-4-dehydrorhamnose reductase	Reduction	PathBank	31602464
MMDBr0025939	dTDP-beta-L-rhamnose	dTDP	Protein-arginine rhamnosyltransferase	Transfer of a rhamnosyl group	RHEA	34755880

Health Effects and Bioactivity

Health Outcome/Bioactivity	Metabolite Response/Effect	Evidence Type	Host and Biospecimen	Data Source	Reference

Microbial Sources

Superkingdom/Kingdom	Phylum	Total species	Hosts and Body Sites
Bacteria/Eubacteria	Proteobacteria	6	Human ; Human subgingival plaque; Human saliva; Human feces; Human feces; pleural fluid plaque; bal
Bacteria	Proteobacteria	1	Human ; Human subgingival plaque; Human saliva; Human feces; Human feces; pleural fluid plaque; bal
Bacteria/Eubacteria	Actinobacteria	4	Human
Bacteria	Actinobacteria	1	Human
Eukaryota/Fungi	Basidiomycota	8	Human feces
Eukaryota/Fungi	Ascomycota	2

Exposure Sources

Other Exposures

Source Type	Data Source	Reference
Drugs - Antimicrobial	U.S. Environmental Protection Agency	CompTox
Cosmetics	U.S. Environmental Protection Agency	CompTox
Domestics	U.S. Environmental Protection Agency	CompTox

Host Biospecimen and Location

Host and Biospecimen	Status	Mean	Std	Min	Max	Units	Age	Sex	Health Condition	Data Source	Reference

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FooDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

Not Available

PDB ID

Not Available

ChEBI ID

Not Available

Food Biomarker Ontology

Not Available

CMMC Knowledgebase

Not Available

General References

Giraud MF, Leonard GA, Field RA, Berlind C, Naismith JH: RmlC, the third enzyme of dTDP-L-rhamnose pathway, is a new class of epimerase. Nat Struct Biol. 2000 May;7(5):398-402. doi: 10.1038/75178. [PubMed:10802738 ]
Dong C, Beis K, Giraud MF, Blankenfeldt W, Allard S, Major LL, Kerr ID, Whitfield C, Naismith JH: A structural perspective on the enzymes that convert dTDP-d-glucose into dTDP-l-rhamnose. Biochem Soc Trans. 2003 Jun;31(Pt 3):532-6. doi: 10.1042/bst0310532. [PubMed:12773151 ]

Showing metabocard for dTDP-beta-L-rhamnose (MMDBc0054471)

MOL for #<Metabolite:0x00007f9adaeb6ac8>

3D MOL for #<Metabolite:0x00007f9adaeb6ac8>

3D SDF for #<Metabolite:0x00007f9adaeb6ac8>

3D-SDF for #<Metabolite:0x00007f9adaeb6ac8>

PDB for #<Metabolite:0x00007f9adaeb6ac8>

3D PDB for #<Metabolite:0x00007f9adaeb6ac8>

SMILES for #<Metabolite:0x00007f9adaeb6ac8>

INCHI for #<Metabolite:0x00007f9adaeb6ac8>

Structure for #<Metabolite:0x00007f9adaeb6ac8>

3D Structure for #<Metabolite:0x00007f9adaeb6ac8>